Energy Storage and Strain Property of (Bi0.5Na0.5)0.935Ba0.065TiO3-xBiScO3 Ceramics

doi:10.15541/jim20180198

Abstract

Abstract:

(1-x)(Bi_0.5Na_0.5)_0.935Ba_0.065TiO₃-xBiScO₃ (BNBT-xBS) lead-free ceramics were fabricated by conventional ceramic sintering process and modified by BiScO₃. Effects of BiScO₃content on microstructure, energy storage, field-induced strain and dielectric properties of BNBT-xBS ceramics were investigated. The results indicated that the structure of BNBT-xBS ceramics without impurity phase transferred from the co-existence phase of rhombohedral and tetragonal phase to pseudo-cubic phase. Average grain size of BNBT-xBS ceramics grew slightly with increment of doping content. The long-range ferroelectric order of BNBT-xBS ceramics was destroyed by BiScO₃, which resulted in weak polarization. Meanwhile, the phase transition of BNBT-xBS ceramics was observed from a typical ferroelectric phase to relaxor phase. BiScO₃ dopants improved energy storage and strain performance of ceramics as well, whose maximum energy storage density and high strain were 0.46 J/cm³ and 0.25% at 70 kV/cm. The dielectric constant decreased with doping content increasing. Relaxor ferroelectric characteristics were also verified by temperature-dependence dielectric spectra. The resistance of BNBT-xBS ceramics illustrated a negative temperature coefficient and excellent electrical insulativity below 450℃.

Key words: BNBT-xBS, energy storage, strain, lead-free, ceramics

CLC Number:

TQ174

LIU Guo-Bao, WANG Hua, XIE Hang, PANG Si-Jian, ZHOU Chang-Rong, XU Ji-Wen. Energy Storage and Strain Property of (Bi_0.5Na_0.5)_0.935Ba_0.065TiO₃-xBiScO₃ Ceramics[J]. Journal of Inorganic Materials, 2018, 33(12): 1330-1336.

Figures/Tables 7

Fig. 1 XRD patterns of BNBT-xBS ceramics at the range of (a) 2θ=20°-70°; (b) 2θ=39°-41°; (c) 2θ= 45°-47°

Fig. 2 Surface morphologies of BNBT-xBS ceramics at(a) x=0; (b) x=0.025; (c) x=0.050; (d) x=0.075, and (e) x=0.100

Fig. 3 Grain size distribution of BNBT-xBS ceramics at (a) x=0; (b) x=0.025; (c) x=0.050; (d) x=0.075, and (e) x=0.100

Fig. 4 (a) P-E hysteresis loops of BNBT-xBS ceramics, (b) energy storage density (Wrec) and efficiency (η) of BNBT-xBS ceramics vs. BS content

Fig. 5 Bipolar strain curves of BNBT-xBS ceramics

Fig. 6 Temperature dependence of relative permittivity (εr) and loss tangent (tanδ) of BNBT-xBS ceramics(a) x=0; (b) x=0.025; (c) x=0.050; (d) x=0.075; (e) x=0.100

Fig. 7 (a) Complex impedance plots and (b) temperature dependence - Z’’- f of BNBT-0.05BS ceramic

References 32

[1]	WANG C H .Electrical and physical properties of lead-free (Na0.5K0.5)NbO3-Bi0.5(Na0.90K0.10)0.5TiO3 ceramics. Key Engineering Materials, 2014, 602-603(9): 791-794.
[2]	ZHANG Z Y, YANG D L, ZHANG W,et al. Current status and prospects of (Bi0.5Na0.5)TiO3-based lead-free piezoelectric ceramics. Journal of Materials Science and Engineering, 2006, 24(5): 796-800.
[3]	TAKENAKA T, MARUYAMA K I, SAKATA K.(Bi1/2Na1/2)TiO3-BaTiO3 system for lead-free piezoelectric ceramics.Japanese Journal of Applied Physics, 1991, 30(9B): 2236-2239.
[4]	HAO J J, LI L T, WANG X H,et al. Progress in research on lead-free piezoelectric ceramic. Journal of The Chinese Ceramic Society, 2004, 32(2): 189-195.
[5]	LIDJICI H, LAGOUN B, BERRAHAL M,et al. XRD, Raman and electrical studies on the (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3 lead free ceramics. Journal of Alloys and Compounds, 2015, 618: 643-648.
[6]	LI L, HAO J, XU Z,et al. Electric field-induced large strain of (Bi1/2Na1/2)0.935Ba0.065TiO3-CaYAlO4 lead-free ceramics. Materials Letters, 2017, 209: 408-412.
[7]	XU Q, XIE J, HE Z,et al. Energy-storage properties of Bi0.5Na0.5TiO3-BaTiO3-KNbO3 ceramics fabricated by wet-chemical method. Journal of the European Ceramic Society, 2017, 37(1): 99-106.
[8]	OGIHARA H, RANDALL C A, TROLIER-MCKINSTRY S.High-energy density capacitors utilizing 0.7BaTiO3-0.3BiScO3 ceramics.Journal of the American Ceramic Society, 2009, 92(8): 1719-1724.
[9]	OGIHARA H, RANDALL C A, TROLIER-MCKINSTRY S.Weakly coupled relaxor behavior of BaTiO3-BiScO3 ceramics.Journal of the American Ceramic Society, 2009, 92(1): 110-118.
[10]	CAO W P, LI W L, FENG Y,et al. Defect dipole induced large recoverable strain and high energy-storage density in lead-free Na0.5Bi0.5TiO3-based systems. Applied Physics Letters, 2016, 108(20): 3687-3694.
[11]	CAO W P, LI W L, DAI X F,et al. Large electrocaloric response and high energy-storage properties over a broad temperature range in lead-free NBT-ST ceramics. Journal of the European Ceramic Society, 2016, 36(3): 593-600.
[12]	KRAUSS W, SCHUTZ D, MAUTNER F A,et al. Piezoelectric properties and phase transition temperatures of the solid solution of (1-x)(Bi0.5Na0.5)TiO3-xSrTiO3. Journal of the European Ceramic Society, 2010, 30(8): 1827-1832.
[13]	ZHANG S T, KOUNGA A B, AULBACH E. Giant strain in lead-free piezoceramics Bi0.5Na0.5TiO3-BaTiO3-K0.5Na0.5NbO3 system. Applied Physics Letters, 2007, 91(11): 112906-1-3.
[14]	GUO Y P, GU M Y, LUO H S, et al. Composition-induced antiferroelectric phase and giant strain in lead-free (Nay, Biz)Ti1-xO3(1-x)-xBaTiO3 ceramics. Physical Review B, 2011, 83(83): 3002-3005.
[15]	LIU X, DU H, LIU X,et al. Energy storage properties of BiTi0.5Zn0.5O3-Bi0.5Na0.5TiO3-BaTiO3 relaxor ferroelectrics. Ceramics International, 2016, 42(15): 17876-17879.
[16]	DONG X L. Doped Pb(Zr,Sn,Ti)O3 slim-loop ferroelectric ceramics for high-power pulse capacitors application.Ferroelectric, 2008, 363(1): 56-63.
[17]	HAO J, YE C, SHEN B, et al. Enhanced electrostricitive properties Enhanced electrostricitive properties and thermal endurance of textured (Bi0.5Na0.5)TiO3-BaTiO3- (K0.5Na0.5)NbO3 ceramics. Journal of Applied Physics, 2013, 114(5): 054101-1-5.
[18]	HUSSAIN A, RAHMAN J U, ZAMAN A,et al. Field-induced strain and polarization response in lead-free Bi1/2(Na0.80K0.20)1/2TiO3-SrZrO3 ceramics. Materials Chemistry and Physics, 2014, 143(3): 1282-1288.
[19]	HAO J, SHEN B, ZHAI J, et al. Phase transitional behavior Phase transitional behavior and electric field-induced large strain in alkali niobate-modified Bi0.5(Na0.80K0.20)0.5TiO3 lead-free piezoceramics. Journal of Applied Physics,2014, 115(3): 034101-1-8.
[20]	WANG K, HUSSAIN A, JO W,et al. Temperature-dependent properties of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-SrTiO3 lead-free piezoceramics. Journal of the American Ceramic Society, 2012, 95(7): 2241-2247.
[21]	PALEI P, SONIA, KUMAR P.Dielectric, ferroelectric and piezoelectric properties of (1-x)[K0.5Na0.5NbO3]-x[LiSbO3] ceramics. Journal of Physics and Chemistry of Solids, 2012, 73(7): 827-833.
[22]	CHAUHAN A, PATEL S, VAISH R,et al. Anti-ferroelectric ceramics for high energy density capacitors. Materials, 2015, 8(12): 8009-8031.
[23]	LI Y, CAO W, LI Q, et al .Electric field induced metastable ferroelectric phase Electric field induced metastable ferroelectric phase and its behavior in (Pb, La)(Zr,Sn,Ti)O3 antiferroelectric single crystal near morphotropic phase boundary. Applied Physics Letters, 2014, 104(5): 052912-1-4.
[24]	XU Y, YAN Y, YOUNG S E,et al. Influence of perpendicular compressive stress on the phase transition behavior in (Pb,La,Ba,)(Zr,Sn,Ti)O3 antiferroelectric ceramics. Ceramics International, 2016, 42(1): 721-726.
[25]	NEURGAONKAR R R, OLIVER J R, CORY W K,et al. Structural and dielectric properties of the phase Pb1-2xKxM3+xNb2O6, M = La or Bi. Materials Research Bulletin, 1983, 18(6): 735-741.
[26]	NEURGAONKAR R R, NELSON J G, OLIVER J R,et al. Ferroelectric and structural properties of the tungsten bronze system K2Ln3+Nb5O15, Ln = La to Lu. Materials Research Bulletin, 1990, 25(8): 959-970.
[27]	WU Y, FORBESS M J, SERAJI S,et al. Oxygen-vacancy-related dielectric relaxation in SrBi2Ta1.8V0.2O9 ferroelectrics. Journal of Applied Physics, 2001, 89(10): 5647-5652.
[28]	ZHANG H, XU P, PATTERSON E,et al. Preparation and enhanced electrical properties of grain-oriented (Bi1/2Na1/2)TiO3- based lead-free incipient piezoceramics. Journal of the European Ceramic Society, 2015, 35(9): 2501-2512.
[29]	ZANG J, LI M, SINCLAIR D C,et al. Impedance spectroscopy of (Bi1/2Na1/2)TiO3-BaTiO3 ceramics modified with (K0.5Na0.5)NbO3. Journal of the American Ceramic Society, 2014, 97(5): 1523-1529.
[30]	JO W, SCHAAB S, SAPPER E, ,et al. On the phase identity and its thermal evolution of lead free (Bi1/2Na1/2)TiO3-6mol% BaTiO3. Journal of Applied Physics, 2011, 110(7): 074106-1-9.
[31]	JIANG C, ZHOU X, ZHOU K,et al. Grain oriented Na0.5Bi0.5TiO3-BaTiO3, ceramics with giant strain response derived from single-crystalline Na0.5Bi0.5TiO3-BaTiO3 templates. Journal of the European Ceramic Society, 2016, 36(6): 1377-1383.
[32]	CHENG J R, SHI G Y, QI Y F,et al. Impedance spectroscopy study of high temperature BiFeO3-PbTiO3 based ceramics. Journal of Shanghai University(Natural Science Edition), 2011, 17(4): 213-218.

Energy Storage and Strain Property of (Bi_0.5Na_0.5)_0.935Ba_0.065TiO₃-xBiScO₃ Ceramics

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