活性填料在先驱体转化制备陶瓷材料中的应用

无机材料学报

活性填料在先驱体转化制备陶瓷材料中的应用

谢征芳; 陈朝辉; 李永清; 周长江

国防科技大学航天与材料工程学院, 长沙 410073

收稿日期:1999-04-19 修回日期:1999-06-01 出版日期:2000-04-20 网络出版日期:2000-04-20

Applications of Active Filler in the Preparation of Preceramic Polymer Derived Ceramics

XIE Zheng-Fang; CHEN Zhao-Hui; LI Yong-Qing; ZHOU Chang-Jiang

College of Aerospace & Material Engineering; National University of Defense Technology; Changsha 410073; China

Received:1999-04-19 Revised:1999-06-01 Published:2000-04-20 Online:2000-04-20

摘要/Abstract

摘要： 综述了用先驱体法制备陶瓷材料的特点，针对先驱体法气孔率高及收缩率大的不足，提出了三个解决办法，其中着重讨论了活性填料的选择原则及其在先驱体裂解制备陶瓷中的特点、应用及国内外研究现状．

关键词: 有机先驱体, 活性填料, 陶瓷

Abstract: The characteristics and development of ceramics prepared by preceramic polymer pyrolysis were reviewed. The disadvantages of such method, high porosity and large shrinkage of ceramics obtained, and the means to overcome these disadvrantages were included. Adding active fillers as one of the means was described in detail, and to select the fillers four principles were proposed. The development at home and abroad of the active fillers controlled polymer pyrolysis was also reviewed.

Key words: preceramic polymer, active filler, ceramics

中图分类号:

TB323

谢征芳,陈朝辉,李永清,周长江. 活性填料在先驱体转化制备陶瓷材料中的应用[J]. 无机材料学报.

XIE Zheng-Fang,CHEN Zhao-Hui,LI Yong-Qing,ZHOU Chang-Jiang. Applications of Active Filler in the Preparation of Preceramic Polymer Derived Ceramics[J]. Journal of Inorganic Materials.

参考文献

[1] Yajima S, et al. Nature, 1976, 261: 525--528.
[2] 谢征芳，陈朝辉，肖加余等. 高分子材料科学与工程(录用待刊).
[3] Dietmar S. AD-A 258, 327.
[4] Haug T, Knable H, Ehrmann U. Processing, Properties and Structueal Development of Polymer-derived Fiber-reinforced SiC. In: Organosilicon Chemistry: from molecular to materials. VCH. Verlagsgesellechaft
mbH, D-69451, Weinheim, 1994: 303-317, edited by Auner N.
[5] Dietmar S, Nathan B, David P, et al. J. Am. Ceram. Soc., 1991, 74 (10): 2687--89.
[6] Peter G, Seibold M. J. Mater. Sci., 1992, 27: 1053--60.
[7] Peter G. J. Am. Ceram. Soc., 1995, 78 (4): 835--48.
[8] 郭景坤(GUO Jing-Kun). 无机材料学报(Journal of Inorganic Materials), 1995, 10 (1): 27--31.
[9] 董绍明，江东亮，谭寿洪等(DONG Shao-Ming, { et al). 无机?材料学报(Journal of Inorganic Materials), 1999, 14 (1): 61--65.
[10] Robert C W. 69th Handbook of Chemistry and Physics. Florida: CRC Press Inc., 1988--1989.
[11] 李世普. 特种陶瓷工艺学. 武汉：武汉工业大学出版社, 1993.
[12] Peter G, Michael S, Tobias E. Mater. Research Soc. Symposium Proceedings, 1992, 274: 155--166.
[13] Michael S, Peter G. J. European Ceram. Soc., 1993, 11: 105--113.
[14] Peter G. cfi/Ber DKG, 1994, 71 (6): 304--309.
[15] Tobias E, Michael S, Otto J, et al. J. Am. Ceram. Soc., 1993, 76 (1): 207--213.
[16] Sung H Y, Richard E R, Stephen C D. J. Am. Cream. Soc., 1995, 78 (7): 1818--1824.
[17] Dietmar S, Heinrich L, Christine A S, et al. J. Inorganic and Organometallic Polymers, 1992, 2 (1): 59--77.
[18] Dietmar S. Applications of Transition Metal Compounds in the Preparation of useful Silicon-Containing Ceramics. In: Organosilicon Chemistry: from Molecular to Materials. VCH. Verlagsgesellechaft mbH, D-69451, Weinheim, 1994. 269--274, edited by Auner N.
[19] Daniel S, Tobias E, Peter G. J. Am. Cream. Soc., 1997, 80 (7): 1831--1840.
[20] 周游，江东亮，谭寿洪等. 中国有色金属学报，1995, 5 (2): 709--711.
[21] Zhou Y, Jiang D L, Guo J K. In: Proceedings of the 5th International Symposium on Ceramic Materials and Components for Engineering. 1994, Shanghai, China.
[22] Hu H F, Su B, Chen Z H. Proceedings of ICAM’96.
[23] 周长江. 活性填料在聚碳硅烷裂解制备陶瓷基复合材料中的应用研?究. 硕士学位论文. 国防科技大学, 1998.
[24] 陈朝辉，谢征芳，周长江. 材料研究学报(录用待刊).