Cr3+掺杂浓度对YAGG:Ce3+,Cr3+发光陶瓷余辉性能的影响

doi:10.15541/jim20240497

无机材料学报 ›› 2025, Vol. 40 ›› Issue (9): 1037-1044.DOI: 10.15541/jim20240497

• 研究快报 • 上一篇

Cr³⁺掺杂浓度对YAGG:Ce³⁺,Cr³⁺发光陶瓷余辉性能的影响

李廷松¹^,²(), 王文丽¹^,³, 刘强³, 王雁斌¹^,², 周真真¹^,², 胡辰¹^,², 李江¹^,²()

1.中国科学院上海硅酸盐研究所, 透明陶瓷研究中心, 上海 201899
2.中国科学院大学材料科学与光电工程中心, 北京 100049
3.江苏大学材料科学与工程学院, 镇江 212013

收稿日期:2024-11-28 修回日期:2024-12-25 出版日期:2025-09-20 网络出版日期:2025-01-24
通讯作者: 李江, 研究员. E-mail: lijiang@mail.sic.ac.cn
作者简介:李廷松(1998-), 男, 硕士研究生. E-mail: litingsong@mail.sic.ac.cn

Influence of Cr³⁺ Doping Concentration on the Persistent Performance of YAGG:Ce³⁺,Cr³⁺ Luminescent Ceramics

LI Tingsong¹^,²(), WANG Wenli¹^,³, LIU Qiang³, WANG Yanbin¹^,², ZHOU Zhenzhen¹^,², HU Chen¹^,², LI Jiang¹^,²()

1. Transparent Ceramics Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
3. School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, China

Received:2024-11-28 Revised:2024-12-25 Published:2025-09-20 Online:2025-01-24
Contact: LI Jiang, professor. E-mail:lijiang@mail.sic.ac.cn
About author:LI Tingsong (1998-), male, Master candidate. E-mail: litingsong@mail.sic.ac.cn
Supported by:
National Key R&D Program of China(2023YFB3506600)

摘要/Abstract

摘要：

Y₃Al₂Ga₃O₁₂:Ce³⁺,Cr³⁺(YAGG:Ce³⁺,Cr³⁺)作为长余辉发光材料, 具有初始发光强度高和余辉时间长的优点, 在长余辉发光材料应用中具有广阔的前景。目前, YAGG:Ce³⁺,Cr³⁺粉体具有良好的余辉性能, 但陶瓷的余辉性能还有待进一步优化。本工作通过固相反应及空气预烧结、热等静压烧结(HIP)后处理和空气退火制备了不同Cr³⁺掺杂浓度的(Y_0.998Ce_0.002)₃(Al_1-_xCr_x)₂Ga₃O₁₂陶瓷, 研究了Cr³⁺掺杂浓度对陶瓷的微观结构、光学性能和余辉性能的影响。结果表明, 随着Cr³⁺掺杂浓度从0.025%增加到0.2%(原子百分数), 预烧结陶瓷或HIP后处理陶瓷的微观结构没有明显变化, 但陶瓷的直线透过率逐渐增加, 余辉性能逐渐下降。其中, 掺杂了0.025% Cr³⁺的YAGG:Ce³⁺,Cr³⁺陶瓷经过空气预烧结结合HIP后处理和空气退火后, 具有超过6055 mcd/m²的最强初始发光强度和1030 min的最长余辉时间。本工作通过优化Cr³⁺掺杂浓度和制备工艺, 使得YAGG:Ce³⁺,Cr³⁺陶瓷的长余辉发光(PersL)性能得到明显提升。

关键词: YAGG:Ce³⁺,Cr³⁺陶瓷, Cr³⁺掺杂浓度, 长余辉发光, 热等静压烧结, 空气退火

Abstract:

Y₃Al₂Ga₃O₁₂:Ce³⁺,Cr³⁺ (YAGG:Ce³⁺,Cr³⁺), as a persistent luminescent material, has advantages of high initial luminescence intensity and long persistent time, which is promising in persistent luminescent material applications. At present, YAGG:Ce³⁺,Cr³⁺ powders exhibit good persistent performance, but their persistent performance of ceramics still needs to be further improved to meet the new requirements. In this work, (Y_0.998Ce_0.002)₃(Al_1-_xCr_x)₂Ga₃O₁₂ ceramics with different Cr³⁺ doping concentrations were prepared by solid-state reaction, including air pre-sintering, hot isostatic pressing (HIP) post-treatment and air annealing, to investigate the effects of Cr³⁺ doping concentration on the microstructure, optical properties and persistent performance of the ceramics. The results showed that as the doping concentration of Cr³⁺ increased from 0.025% to 0.2% (in atom), no significant effect of Cr³⁺ concentration on the morphology of pre-sintered ceramics or HIP post-treatment ceramics was observed, but the in-line transmittance gradually increased while the persistent performance gradually decreased. Among them, YAGG:Ce³⁺,Cr³⁺ ceramics doped with 0.025% Cr³⁺ showed the strongest initial luminescence intensity exceeding 6055 mcd/m² and a persistent time of 1030 min after air pre-sintering combined with HIP post-treatment and air annealing. By optimizing the Cr³⁺ doping concentration and the fabrication process, the persistent luminescence (PersL) performance of the YAGG:Ce³⁺,Cr³⁺ ceramics was obviously improved.

Key words: YAGG:Ce³⁺,Cr³⁺ ceramic, Cr³⁺ doping concentration, persistent luminescence, hot isostatic pressing, air annealing

中图分类号:

TQ174

李廷松, 王文丽, 刘强, 王雁斌, 周真真, 胡辰, 李江. Cr³⁺掺杂浓度对YAGG:Ce³⁺,Cr³⁺发光陶瓷余辉性能的影响[J]. 无机材料学报, 2025, 40(9): 1037-1044.

LI Tingsong, WANG Wenli, LIU Qiang, WANG Yanbin, ZHOU Zhenzhen, HU Chen, LI Jiang. Influence of Cr³⁺ Doping Concentration on the Persistent Performance of YAGG:Ce³⁺,Cr³⁺ Luminescent Ceramics[J]. Journal of Inorganic Materials, 2025, 40(9): 1037-1044.

图/表 7

Fig. 1 XRD patterns of pre-sintered combined with HIP post- treated YAGG:Ce3+,Cr3+ PersL ceramics with different concentrations of Cr3+

Fig. 2 FESEM images of pre-sintered YAGG:Ce3+,Cr3+ PersL ceramics with different concentrations of Cr3+ (a) 0.025%; (b) 0.05%; (c) 0.1%; (d) 0.2%

Fig. 3 FESEM images of HIP post-treated YAGG:Ce3+,Cr3+ PersL ceramics with different concentrations of Cr3+ (a) 0.025%; (b) 0.05%; (c) 0.1%; (d) 0.2%

Fig. 4 Photographs and in-line transmittance of pre-sintered combined with HIP post-treated YAGG:Ce3+,Cr3+ PersL ceramics with different concentrations of Cr3+ (2.1 mm in thickness) (a) Photographs of ceramics (from left to right containing 0.025%, 0.05%, 0.1%, and 0.2% Cr, respectively); (b) In-line transmittance of ceramics

Fig. 5 PL spectra of pre-sintered combined with HIP post-treated YAGG:Ce3+,Cr3+ PersL ceramics (a) PL spectra of ceramics with different Cr3+ doping concentrations at room temperature; (b) Temperature-dependent PL spectra of ceramics with Cr3+ concentration of 0.025%

Fig. 6 Luminous photographs, initial luminescence intensity and duration of pre-sintered, HIP post-treated and air annealed YAGG:Ce3+,Cr3+ PersL ceramics with different concentrations of Cr3+ (excitation: 365 nm, 24 W, 5 min) (a) Luminous photographs of pre-sintered ceramics; (b) Luminous photographs of HIP post-treated ceramics; (c) Luminous photographs of air annealed ceramics; (d) Initial luminescence intensity of ceramics; (e) Duration of ceramics

Fig. 7 Energy band diagram of YAGG:Ce3+,Cr3+ PersL ceramics

参考文献 46

[1]	POELMAN D, VAN DER HEGGEN D, DU J, et al. Persistent phosphors for the future: fit for the right application. Journal of Applied Physics, 2020, 128(24): 240903.
[2]	XU J, TANABE S. Persistent luminescence instead of phosphorescence: history, mechanism, and perspective. Journal of Luminescence, 2019, 205: 581.
[3]	LI Y, GECEVICIUSA M, QIU J R. Long persistent phosphors- from fundamentals to applications. Chemical Society Reviews, 2016, 45(8): 2090.
[4]	MATSUZAWA T, AOKI Y, TAKEUCHI N, et al. A new long phosphorescent phosphor with high brightness, SrAl₂O₄:Eu²⁺,Dy³⁺. Journal of the Electrochemical Society, 2019, 143(8): 2670.
[5]	CHERNOV V, SALAS-CASTILLO P, DÍAZ-TORRES L A, et al. Thermoluminescence and infrared stimulated luminescence in long persistent monoclinic SrAl₂O₄:Eu²⁺,Dy³⁺ and SrAl₂O₄:Eu²⁺,Nd³⁺ phosphors. Optical Materials, 2019, 92: 46.
[6]	SMET P F, BOTTERMAN J, VAN DEN EECKHOUT K, et al. Persistent luminescence in nitride and oxynitride phosphors: a review. Optical Materials, 2014, 36(11): 1913.
[7]	XUE H L, YANG M P, SUN J J, et al. Study on the flux for SrAl₂O₄:Eu²⁺, Dy³⁺ phosphor preparation used in fluorescent fiber. Ceramics International, 2024, 50(1): 1137.
[8]	HÖLSÄ J. Persistent luminescence beats the afterglow: 400 years of persistent luminescence. Journal of the Electrochemical Society, 2009, 18(4): 42.
[9]	ZENG Q Q, WU Y Z, CHENG H Y, et al. Calcium doped self- activated zinc germanate long afterglow materials: multicolor afterglow and application in dynamic anti-counterfeiting. Journal of Inorganic Materials, 2023, 38(8): 901.
[10]	CAI Y Y, LIU S B, ZHAO L, et al. Delayed stress memory by CaAl₂O₄:Eu²⁺ mechanoluminescent phosphor with defect engineering regulation. Journal of Advanced Ceramics, 2022, 11(8): 1319.
[11]	ZHOU S H, LOU B B, MA C G, et al. First-principles study on persistent luminescence mechanism of LiYGeO₄:Eu³⁺. Journal of Rare Earths, 2023, 41(10): 1519.
[12]	LI Q L, LI N X, LI Y C, et al. Research progress of radio- photoluminescence materials and their applications. Journal of Inorganic Materials, 2023, 38(7): 731.
[13]	ZHAO J T, LEI L, YE R G, et al. Sunlight activated ultra-stable long persistent luminescence glass ceramic for outdoor information display. Journal of Advanced Ceramics, 2022, 11(6): 974.
[14]	VAN DEN EECKHOUT K, POELMAN D, SMET P F. Persistent luminescence in non-Eu²⁺-doped compounds: a review. Materials, 2013, 6(7): 2789.
[15]	ZHENG H R, LIU L, LI Y A, et al. X-ray excited Mn²⁺-doped persistent luminescence materials with biological window emission for in vivo bioimaging. Journal of Rare Earths, 2024, 42(1): 28.
[16]	YIN X G, ZHONG H Y, LIU L, et al. X-ray-activated Bi³⁺/Pr³⁺ co-doped LiYGeO₄ phosphor with UV and NIR dual-emissive persistent luminescence. Journal of Rare Earths, 2024, 42(5): 955.
[17]	DONG S M, WANG J Y, NI D W. Structural ceramics-the cornerstone of human civilization. Journal of Inorganic Materials, 2024, 39(6): 569.
[18]	ZHUANG Y X, KATAYAMA Y, UEDA J, et al. A brief review on red to near-infrared persistent luminescence in transition-metal- activated phosphors. Optical Materials, 2014, 36(11): 1907.
[19]	KADENGE V, KIPROTICH S, KAWIRA M, et al. Effect of Dy³⁺ concentrationson the structural and optical properties of SrAl₂O₄:Eu²⁺,Dy³⁺ NPs. Trends in Sciences, 2024, 21: 1.
[20]	YANG L, GAI S L, DING H, et al. Recent progress in inorganic afterglow materials: mechanisms, persistent luminescent properties, modulating methods, and bioimaging applications. Advanced Optical Materials, 2023, 11(11): 2202382.
[21]	LIANG L L, CHEN J Y, SHAO K, et al. Controlling persistent luminescence in nanocrystalline phosphors. Nature Materials, 2023, 22: 289.
[22]	ZHUANG Y X, UEDA J, TANABE S. Photochromism and white long-lasting persistent luminescence in Bi³⁺-doped ZnGa₂O₄ ceramics. Optical Materials Express, 2012, 2(10): 1378.
[23]	ZHUANG Y X, UEDA J, TANABE S. Enhancement of red persistent luminescence in Cr³⁺-doped ZnGa₂O₄ phosphors by Bi₂O₃ codoping. Applied Physics Express, 2013, 6(5): 052602.
[24]	DAI Z F, MAO X Y, LIU Q, et al. Effect of dopant concentration on the optical characteristics of Cr³⁺:ZnGa₂O₄ transparent ceramics exhibiting persistent luminescence. Optical Materials, 2022, 125: 112127.
[25]	DAI Z F, BOIKO V, GRZESZKIEWICZ K, et al. Effect of annealing treatment on the persistent luminescence of Y₃Al₂Ga₃O₁₂:Ce³⁺, Cr³⁺,Pr³⁺ ceramics. Optical Materials, 2020, 105: 109888.
[26]	LIU Q, WANG W L, DAI Z F, et al. Fabrication and long persistent luminescence of Ce³⁺-Cr³⁺ co-doped yttrium aluminum gallium garnet transparent ceramics. Journal of Rare Earths, 2022, 40(11): 1699.
[27]	YANG Y M, LI Z Y, ZHANG J Y, et al. X-ray-activated long persistent phosphors featuring strong UVC afterglow emissions. Light: Science & Applications, 2018, 7: 88.
[28]	LI T S, LIU Q, ZHU D Y, et al. Fabrication and characterizations of Eu²⁺-Dy³⁺ co-doped SrAl₂O₄ ceramics with persistent luminescence. Journal of the American Ceramic Society, 2023, 106(10): 5877.
[29]	UEDA J, DORENBOS P, BOS A J J, et al. Control of electron transfer between Ce³⁺ and Cr³⁺ in the Y₃Al_5-_xGa_xO₁₂ host via conduction band engineering. Journal of Materials Chemistry C, 2015, 3(22): 5642.
[30]	XU J, MURATA D, UEDA J, et al. Toward rechargeable persistent luminescence for the first and third biological windows via persistent energy transfer and electron trap redistribution. Inorganic chemistry, 2018, 57(9): 5194.
[31]	DAI Z F, BOIKO V, GRZESZKIEWICZ K, et al. Effect of annealing temperature on persistent luminescence of Y₃Al₂Ga₃O₁₂:Cr³⁺ co-doped with Ce³⁺ and Pr³⁺. Optical Materials, 2021, 111: 110522.
[32]	DAI Z, BOIKO V, MARKOWSKA M, et al. Optical studies of Y₃(Al,Ga)₅O₁₂:Ce³⁺,Cr³⁺,Nd³⁺ nano-phosphors obtained by the Pechini method. Journal of Rare Earths, 2019, 37(11): 1132.
[33]	XIA Z G, MEIJERINK A. Ce³⁺-doped garnet phosphors: composition modification, luminescence properties and applications. Chemical Society Reviews, 2017, 46(1): 275.
[34]	WEI Z Y, MENG G H, CHEN L, et al. Progress in ceramic materials and structure design toward advanced thermal barrier coatings. Journal of Advanced Ceramics, 2022, 11(7): 985.
[35]	UEDA J, KUROISHI K, TANABE S. Yellow persistent luminescence in Ce³⁺-Cr³⁺-codoped gadolinium aluminum gallium garnet transparent ceramics after blue-light excitation. Applied Physics Express, 2014, 7(6): 062201.
[36]	MÉVEL C, CARREAUD J, DELAIZIR G, et al. First ZnGa₂O₄ transparent ceramics. Journal of the European Ceramic Society, 2021, 41(9): 4934.
[37]	KARACAOGLU E, ÖZTÜRK E, UYANER M, et al. Atomic layer deposition (ALD) of nanoscale coatings on SrAl₂O₄-based phosphor powders to prevent aqueous degradation. Journal of the American Ceramic Society, 2020, 103(6): 3706.
[38]	XU J, UEDA J, TANABE S. Novel persistent phosphors of lanthanide-chromium co-doped yttrium aluminum gallium garnet: design concept with vacuum referred binding energy diagram. Journal of Materials Chemistry C, 2016, 4(20): 4380.
[39]	BOIKO V, DAI Z F, MARKOWSKA M, et al. Particle size-related limitations of persistent phosphors based on the doped Y₃Al₂Ga₃O₁₂ system. Scientific Reports, 2021, 11: 141.
[40]	KATAYAMA Y, VIANA B, GOURIER D, et al. Photostimulation induced persistent luminescence in Y₃Al₂Ga₃O₁₂:Cr³⁺. Optical Materials Express, 2016, 6(4): 1405.
[41]	BOIKO V, ZELER J, MARKOWSKA M, et al. Persistent luminescence from Y₃Al₂Ga₃O₁₂ doped with Ce³⁺ and Cr³⁺ after X-ray and blue light irradiation. Journal of Rare Earths, 2019, 37(11): 1200.
[42]	XU J, UEDA J, KUROISHI K, et al. Fabrication of Ce³⁺-Cr³⁺ co-doped yttrium aluminium gallium garnet transparent ceramic phosphors with super long persistent luminescence. Scripta Materialia, 2015, 102: 47.
[43]	CHEN R, LAWLESS J L, PAGONIS V. A model for explaining the concentration quenching of thermoluminescence. Radiation Measurements, 2011, 46(12): 1380.
[44]	CHEN B, WANG F. Combating concentration quenching in upconversion nanoparticles. Accounts of Chemical Research, 2020, 53(2): 358. DOI PMID
[45]	WANG Z J, MEIJERINK A. Concentration quenching in upconversion nanocrystals. Journal of Physical Chemistry C, 2018, 122(45): 26298. DOI PMID
[46]	PAN Z W, LU Y Y, LIU F. Sunlight-activated long-persistent luminescence in the near-infrared from Cr³⁺-doped zinc gallogermanates. Nature Materials, 2011, 11: 58.

Cr³⁺掺杂浓度对YAGG:Ce³⁺,Cr³⁺发光陶瓷余辉性能的影响

Influence of Cr³⁺ Doping Concentration on the Persistent Performance of YAGG:Ce³⁺,Cr³⁺ Luminescent Ceramics

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