Journal of Inorganic Materials

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Recent Progress in Bimetallic Oxide-Based Electromagnetic Wave Absorbing Materials

SUN Lei1, XIE Xiu-bo1,2, DU Wei1,3, HOU Chuan-xin1,2   

  1. 1. School of Environmental and Material Engineering, Yantai University, Yantai 264005, China;
    2. Yantai Key Laboratory of Advanced Nuclear Fuel Cycle and Nuclear Equipment Electromagnetic Environment Safety, Yantai University, Yantai 264005;
    3. Shandong University of Aeronautics, Binzhou 256600, China
  • Received:2026-06-03 Revised:2026-08-26
  • Contact: DU Wei, Professor. E-mail: duwei@ytu.edu.cn; HOU Chuanxin, Professor. E-mail: chuanxin210@ytu.edu.cn
  • About author:SUN Lei (2001-), female, Master candidate. E-mail: 4516996sl@s.ytu.edu.cn
  • Supported by:
    Shandong Provincial Natural Science Foundation (ZR2025QB33); National Natural Science Foundation of China (52572325, 52472131); Excellent Youth Innovation Team Project for Higher Education Institutions of Shandong Province (2023KJ238); Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai (AMGM2024F27).

Abstract: To address electromagnetic wave pollution, developing high-performance electromagnetic wave absorbing (EMWA) materials has become an urgent priority. Bimetallic oxides have emerged as a research hot spot in this field due to their tunable electromagnetic properties and excellent environmental stability. In recent years, considerable attention has been paid to the influence of multidimensional structural design. In this work, the progress in bimetallic oxide-based EMWA materials over the past decade was summarized, systematically elucidating the evolutionary patterns—from zero-dimensional nanoparticles and one-dimensional nanowires/tubes to two-dimensional nanosheets and three-dimensional hierarchical structures. Moreover, the unique advantages of different dimensions in optimizing impedance matching and enhancing loss mechanisms were analyzed. A comprehensive comparison showed that interfacial polarization can be enhanced by zero-dimensional materials through core-shell and hollow designs with high specific surface area, abundant surface atoms, and unsaturated bonds. One-dimensional materials utilized shape anisotropy and conductive networks to achieve strong absorption at low filling ratios. Two-dimensional materials relied on large-area heterogeneous interfaces to demonstrate excellent performance at ultra-thin matching thicknesses. Three-dimensional materials, with continuous networks and adjustable porosity, can simultaneously construct continuous conductive pathways and interconnected pores, optimizing the conductive network while extending the electromagnetic wave propagation path, achieving maximized energy dissipation. Studies have demonstrated that dimensional control significantly enhances material wave absorptive properties. Finally, the paper summarizes current challenges and outlines future research directions, aiming to provide valuable guidance for designing next-generation high-performance EMWA materials.

Key words: bimetallic oxide, dimensional engineering, electromagnetic wave absorption, impedance matching, review

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