Journal of Inorganic Materials ›› 2025, Vol. 40 ›› Issue (10): 1079-1096.DOI: 10.15541/jim20240525
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TIAN Tian1(), FANG Chenkai1, ZHANG Jie1, WANG Weiwei2, WU Tingfeng1, XU Jiayue1(
)
Received:
2024-12-18
Revised:
2025-01-02
Published:
2025-03-19
Online:
2025-03-19
Contact:
XU Jiayue, professor. E-mail: xujiayue@sit.edu.cnAbout author:
TIAN Tian (1985-), male, professor. E-mail: tiant@sit.edu.cn
Supported by:
CLC Number:
TIAN Tian, FANG Chenkai, ZHANG Jie, WANG Weiwei, WU Tingfeng, XU Jiayue. Research Progress on Photorefraction of Lithium Niobate Crystal Doped with High Valence Ion[J]. Journal of Inorganic Materials, 2025, 40(10): 1079-1096.
Fig. 3 Comparison between the local lattice distortions of VLi, NbLi and the bulk LiNbO3 calculated by spin-polarized HSE06[69] (a) Lattice of ${\text{V}}_{\text{Li}}^{4+}$; (b) Lattice of ${\text{Nb}}_{\text{Li}}^{4+}$; (c) Lattice of ${\text{V}}_{\text{Li}}^{3+}$; (d) Lattice of ${\text{Nb}}_{\text{Li}}^{3+}$; (e) Lattice of ${\text{V}}_{\text{Li}}^{2+}$; (f) Lattice of ${\text{Nb}}_{\text{Li}}^{2+}$; (g) Lattice of bulk lithium niobate. Red balls refer to O, green balls refer to V, grey balls refer to Nb, and white balls refer to Li
Fig. 4 Photorefractive properties of CLN and LN:V, Mg crystals measured at the wavelength of 532 and 488 nm[70] (a) Diffraction efficiency; (b) Response time
Fig. 5 OH− absorption spectra and light energy transfer curves for two-beam coupling of CLN, LN:V and LN:Mg, V crystals[70] (a) OH− absorption spectra; (b) Light energy transfer curves
Fig. 6 Angular scans for Nb- and W-RBS along the <$01\overline{1}0$>, <$02\overline{2}1$>, <$11\overline{2}0$> axial directions, and computer simulation of the occupancy of Nb and W ions in the direction of <$02\overline{2}1$>[73-74] (a) Angular scans; (b) Occupancy simulation
Fig. 7 Time dependence of diffraction efficiency of CLN:W crystals measured at the wavelength of 532 nm[76] (a) CLN:W0.5in; (b) CLN:W2.0in; (c) CLN:W0.5out; (d) CLN:W2.0out; (e) CLN:W3.0in
Fig. 8 Time dependence of diffraction efficiency of CLN:W crystals measured at the wavelength of 488 nm[76] (a) CLN:W0.5in; (b) CLN:W2.0in; (c) CLN:W0.5out; (d) CLN:W2.0out; (e) CLN:W3.0in
Fig. 13 Photorefractive properties of LN:Mo, Mg and LN:Mo, Zr with different concentrations from UV to the visible bands[80] (a) Diffraction efficiency; (b) Response time; (c) Refractive index change; (d) Sensitivity
Crystal | Doping element/% | Diffraction efficiency/% | Response time/s | Ref. | |||||
---|---|---|---|---|---|---|---|---|---|
Mo2O3 | MgO | ZnO | In2O3 | ZrO2 | HfO2 | ||||
LN:Mo | 0.5 | - | - | - | - | - | 28.50 | 5.50 | [ |
LN:Mo, Mg | 0.5 | 6.5 | - | - | - | - | 60.00 | 0.35 | [ |
LN:Mo, Zn | 0.5 | - | 7.2 | - | - | - | 17.72 | 0.65 | [ |
LN:Mo, In | 0.5 | - | - | 3 | - | - | 28.90 | 0.76 | [ |
LN:Mo, Zr | 0.5 | - | - | - | 2.5 | - | 20.80 | 15.00 | [ |
LN:Mo, Hf | 0.5 | - | - | - | - | 3.5 | 46.07 | 0.90 | [ |
Table 1 Photorefractive properties of Mo ions and photorefraction resistant ions co-doped LN crystals[77,80 -83]
Crystal | Doping element/% | Diffraction efficiency/% | Response time/s | Ref. | |||||
---|---|---|---|---|---|---|---|---|---|
Mo2O3 | MgO | ZnO | In2O3 | ZrO2 | HfO2 | ||||
LN:Mo | 0.5 | - | - | - | - | - | 28.50 | 5.50 | [ |
LN:Mo, Mg | 0.5 | 6.5 | - | - | - | - | 60.00 | 0.35 | [ |
LN:Mo, Zn | 0.5 | - | 7.2 | - | - | - | 17.72 | 0.65 | [ |
LN:Mo, In | 0.5 | - | - | 3 | - | - | 28.90 | 0.76 | [ |
LN:Mo, Zr | 0.5 | - | - | - | 2.5 | - | 20.80 | 15.00 | [ |
LN:Mo, Hf | 0.5 | - | - | - | - | 3.5 | 46.07 | 0.90 | [ |
Fig. 16 Photorefractive properties of LN:U with different concentrations in the visible band[94] (a) Diffraction efficiency; (b) Refractive index change; (c) Response time; (d) Sensitivity
Fig. 17 Photorefractive parameters of CLN, LN:U0.6, LN:U0.6, In2.0, and LN:Fe0.3[95] (a) Diffraction efficiency; (b) Response time; (c) Refractive index change; (d) Sensitivity
Fig. 18 Photorefractive properties of LN:U, Mg with different concentrations[96] (a) Diffraction efficiency and sensitivity; (b) Response time and refractive index modulation
Fig. 19 Transmission spectra of LN:Tb under UV irradiation and temporal evolution of 313 nm induced absorption[104] (a) Transmission spectra; (b) Induced absorbance
Fig. 20 Photorefractive properties of LN:Bi with different concentrations[106] (a) Diffraction efficiency and refractive index change; (b) Response time and sensitivity
Fig. 21 Photorefractive properties of LN:Bi, CLN, and LN:Bi, Mg with different Mg concentrations[107] (a) Diffraction efficiency and refractive index change; (b) Response time and sensitivity
Fig. 22 Holographic images during display (at 60 Hz)[109] (a) Rhythmic gymnastics; (b) Karate kumite; (c) Diving; (d) Baseball; (e) Olympic rings; (f) Basketball; (g) Athletics; (h) Shooting; (i) Surfing
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