新型光伏储电原位集成电池研究进展

doi:10.15541/jim20190342

无机材料学报 ›› 2020, Vol. 35 ›› Issue (6): 623-632.DOI: 10.15541/jim20190342 CSTR: 32189.14.10.15541/jim20190342

所属专题： 2020年能源材料论文精选(三) :太阳能电池、热电材料及其他；【虚拟专辑】太阳能电池(2020~2021)

• 综述 • 下一篇

新型光伏储电原位集成电池研究进展

于守武¹,赵泽文^1,²,赵晋津²,肖淑娟¹,师岩³,高存法³,苏晓²,胡宇翔⁴,赵智胜⁵,王婕²,王连洲⁴()

^1. 华北理工大学材料科学与工程学院, 唐山 063009
^2. 石家庄铁道大学材料科学与工程学院, 石家庄 050043
^3. 南京航空航天大学机械结构强度与振动国家重点实验室, 南京 210016
^4. 昆士兰大学化工学院, 纳米材料研究中心, 澳大利亚生物工程与纳米科技研究所, 布里斯班 QLD 4072, 澳大利亚
^5. 燕山大学亚稳材料制备技术与科学国家重点实验室, 秦皇岛 066004

收稿日期:2019-07-10 修回日期:2019-09-01 出版日期:2020-06-20 网络出版日期:2019-09-18
作者简介:于守武(1979-), 男, 博士, 副教授. E-mail: yushouwu@ncst.edu.cn;<br/>YU Shouwu (1979-), male, PhD, associate professor. E-mail: yushouwu@ncst.edu.cn
基金资助:
河北省自然科学基金杰出青年项目(A2019210204);国家自然科学基金(11772207);河北省青年拔尖人才支持计划;深圳孔雀团队计划项目(KQTD20170810160424889);机械结构力学及控制国家重点实验室(南京航空航天大学)开放课题(MCMS-E-0519G04);亚稳材料制备技术与科学国家重点实验室(燕山大学)开放基金(201919)

Research Progress in Novel In-situ Integrative Photovoltaic-storage Tandem Cells

YU Shouwu¹,ZHAO Zewen^1,²,ZHAO Jinjin²,XIAO Shujuan¹,SHI Yan³,GAO Cunfa³,SU Xiao²,HU Yuxiang⁴,ZHAO Zhisheng⁵,WANG Jie²,WANG Lianzhou⁴()

^1. College of Materials Science and Engineering, North China University of Science and Technology, Tangshan 063009, China
^2. School of Materials Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang 050043, China
^3. State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
^4. Australian Institute for Bioengineering and Nanotechnology, Nanomaterials Centre, School of Chemical Engineering, The University of Queensland, Brisbane QLD 4072, Australia
^5. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China

Received:2019-07-10 Revised:2019-09-01 Published:2020-06-20 Online:2019-09-18
Supported by:
Natural Science Foundation of Hebei Province for Distinguished Young Scholar(A2019210204);National Natural Science Foundation of China(11772207);Youth Top-notch Talents Supporting Plan of Hebei Province;Shenzhen Peacock Team Program(KQTD20170810160424889);State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics(MCMS-E-0519G04);The Open Fund of State Key Laboratory of Metastable Materials Science and Technology(201919)

摘要/Abstract

摘要：

随着光伏智能电子产品日益融入到日常生活, 人们不仅对高性能光伏发电设备的需求增加, 同时对智能化、可持续和快速充电/放电能源集成设备的需求也急剧增加, 将能量产生部件和能量存储部件结合成独立设备已经成为一种极具有吸引力和挑战性的前沿技术。原位逐层制备光电转换功能薄膜与储电功能薄膜并组装, 获得光伏储电原位集成电池的技术, 既减少了太阳光波动对能量输出的影响, 又可以实现光伏自供电、弱光缓冲和可穿戴等功能, 因此具有良好的发展前景。本文综述了硅基光伏储电原位集成电池、敏化光伏储电原位集成电池、钙钛矿光伏储电原位集成电池的最新研究成果, 介绍了此类新型电池性能的评价方法, 分析了其工作原理、构造特点和性能参数, 并对此新兴研究领域的发展趋势进行了展望。

关键词: 硅基太阳能电池, 敏化太阳能电池, 钙钛矿太阳能电池, 能量储存, 光伏储能, 原位集成, 综述

Abstract:

As smart electronic products are increasingly applied in our daily life, there is not only an increasing demand for high-performance photovoltaic power generation devices, but also strong need for in-situ energy storage functions in these devices. The integration of energy generating components and energy storage components into one device has become an attractive challenging technology. The basic idea is that by integration design and engineering the assembly of the photoelectric conversion layer and the energy storage layer into one in-situ energy conversion and storage system could not only offer multiple functions, such as self-powered ability, weak light buffer and portability, but reduce sunlight fluctuation effect on energy output. This review summarizes the research progress in novel in-situ integrative photovoltaic-storage tandem cells, classified by silicon solar cell, sensitized solar cell and perovskite solar cell. Evaluation of methodology, operational principle, construction feature, and performance parameter are also discussed and critically reviewed, and the further development of in-situ integrative photovoltaic-storage tandem cell is also prospected.

Key words: silicon solar cell, sensitized solar cell, perovskite solar cell, energy storage, photovoltaic-storage, in-situ integration, review

中图分类号:

TQ174

于守武, 赵泽文, 赵晋津, 肖淑娟, 师岩, 高存法, 苏晓, 胡宇翔, 赵智胜, 王婕, 王连洲. 新型光伏储电原位集成电池研究进展[J]. 无机材料学报, 2020, 35(6): 623-632.

YU Shouwu, ZHAO Zewen, ZHAO Jinjin, XIAO Shujuan, SHI Yan, GAO Cunfa, SU Xiao, HU Yuxiang, ZHAO Zhisheng, WANG Jie, WANG Lianzhou. Research Progress in Novel In-situ Integrative Photovoltaic-storage Tandem Cells[J]. Journal of Inorganic Materials, 2020, 35(6): 623-632.

图/表 7

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Solar cell type	Device construction	η_overall*/%	η_solar*/%	η_storage*/%	Ref.
	PEDOT:PSS/n-Si/Ti/PE/(PVA/H₃PO₄)/PE/Ti	10.50	13.39	78.42	[29]
SiSC-SPC	Glass/c-Si/Insulation layer/Graphene oxides/ Electrolyte/Substrate	9.72	15.69	62.00	[30]
	PEDOT:PSS/Si/Au/Graphene/Separator/Graphene/PET	2.92	12.37	23.61	[19]
SiSC-LIB	c-Si/Al/SiO₂/Al/Li₄Ti₅O₁₂/Soild electrolyte/LiCoO₂/ Al/Li₄Ti₅O₁₂/Solid electrolyte/LiCoO₂/Al	7.61	15.80	48.16	[31]

Solar cell type	Device construction	η_overall*/%	η_solar*/%	η_storage*/%	Ref.
	PEDOT:PSS/n-Si/Ti/PE/(PVA/H₃PO₄)/PE/Ti	10.50	13.39	78.42	[29]
SiSC-SPC	Glass/c-Si/Insulation layer/Graphene oxides/ Electrolyte/Substrate	9.72	15.69	62.00	[30]
	PEDOT:PSS/Si/Au/Graphene/Separator/Graphene/PET	2.92	12.37	23.61	[19]
SiSC-LIB	c-Si/Al/SiO₂/Al/Li₄Ti₅O₁₂/Soild electrolyte/LiCoO₂/ Al/Li₄Ti₅O₁₂/Solid electrolyte/LiCoO₂/Al	7.61	15.80	48.16	[31]

Solar cell type	Device construction	η_overall*/%	η_solar*/%	η_storage*/%	Ref.
DSSC-SPC	FTO/TiO₂@dye/LiI/Carbon layer/Porous separator/C/Pt	-	-	59.00	[12]
	FTO/TiO₂@N719/I^-/I₃^-/Pt/Carbon/Separator/Electrolyte/C/Pt	-	-	42.00	[37]
	TCO/TiO₂@N719/I^-/I₃^- gel/MWCNT /PVA-H₃PO₄/MWCNT	5.12	6.10	84.00	[39]
	FTO/TiO₂@N719/ I^-/I₃^- /Zn NWs@PVDF @Au@Pt/FTO	3.70	-	-	[40]
	Glass/FTO/TiO₂@dye/ I^-/I₃^-/Si/Ionic polymer/Si wafer	2.10	2.63	80.00	[41]
	FTO/TiO₂-D365dye/P3HT/Ag/RuO_x(OH)_y/Nafion membrane/ RuO_x(OH)_y/FTO	0.80	0.91	88.00	[42]
	Ti/TiO₂@N719/ I^-/I₃^-/Pt/Parafilm/C/PVDF/ SS	1.46	2.03	71.56	[43]
	CNT fiber@CNTs/ Ti wire/TiO₂@N719/I^-/I₃^-/CNT fiber	1.50	6.10	84.00	[44]
	Ti wire/TiO₂@N719/Eutectic melts/CNTs-Ti wire/ TiO₂ /PVA-H₃PO₄/CNT	2.07	2.73	75.70	[45]
	Ti/TiO₂@N719/I^-/I₃^-/MWCNT/Separator/MWCNT/PVA-H₃PO₄/MWCNT	1.83	6.47	28.30	[11]
	Ti Fiber@TiO₂@dye/ I^-/I₃^-/Stainless steel(ss)@PANi-SS@Space wire/H₂SO₄/ss@PANi	2.12	4.56	46.00	[18]
	Ti/TiO₂@N719/I^-/I₃^-/Carbon fiber(CF)/EVA/Cu-CF@RuO₂?xH₂O/H₃PO₄/PVA/CF@RuO₂?xH₂O/EVA/Cu/PDMS	-	5.64	-	[46]
QDSSC-SPC	Glass/FTO/TiO₂@CdS/CdSe/S^2-/S/Cfiber@Cu₂S/C/Electrolyte/C		1.8		[48]
DSSC-LIB	Pt/Electrolyte/TNTs@N719/Ti/TNTs/Membrane/LiCoO₂/Al	0.82	-	-	[49]
	PEN/ITO/TiO₂@N719/I^-/I₃^-/Pt/PEDOT/LiClO₄/PEDOT/Pt	-	4.37	-	[50]
	FTO/TiO₂@N3/I^-/I₃^-/Pt/PProDOT-Et₂/LiClO₄/PProDOT-Et₂/Pt	0.60	0.75	80.00	[51]
	FTO/Pt/ I^-/I₃^-/TiO₂nanotube (ATO)@N749/Ti/ ATO/Separator/Li₂SO₄/ATO/Ti/FTO	1.64	3.18	51.60	[52]
	FTO/TiO₂@bis-EDOT dye/PEDOT/C/LiClO₄/electrolyte/ppy/FTO	0.10	-	-	[53]

Solar cell type	Device construction	η_overall*/%	η_solar*/%	η_storage*/%	Ref.
DSSC-SPC	FTO/TiO₂@dye/LiI/Carbon layer/Porous separator/C/Pt	-	-	59.00	[12]
	FTO/TiO₂@N719/I^-/I₃^-/Pt/Carbon/Separator/Electrolyte/C/Pt	-	-	42.00	[37]
	TCO/TiO₂@N719/I^-/I₃^- gel/MWCNT /PVA-H₃PO₄/MWCNT	5.12	6.10	84.00	[39]
	FTO/TiO₂@N719/ I^-/I₃^- /Zn NWs@PVDF @Au@Pt/FTO	3.70	-	-	[40]
	Glass/FTO/TiO₂@dye/ I^-/I₃^-/Si/Ionic polymer/Si wafer	2.10	2.63	80.00	[41]
	FTO/TiO₂-D365dye/P3HT/Ag/RuO_x(OH)_y/Nafion membrane/ RuO_x(OH)_y/FTO	0.80	0.91	88.00	[42]
	Ti/TiO₂@N719/ I^-/I₃^-/Pt/Parafilm/C/PVDF/ SS	1.46	2.03	71.56	[43]
	CNT fiber@CNTs/ Ti wire/TiO₂@N719/I^-/I₃^-/CNT fiber	1.50	6.10	84.00	[44]
	Ti wire/TiO₂@N719/Eutectic melts/CNTs-Ti wire/ TiO₂ /PVA-H₃PO₄/CNT	2.07	2.73	75.70	[45]
	Ti/TiO₂@N719/I^-/I₃^-/MWCNT/Separator/MWCNT/PVA-H₃PO₄/MWCNT	1.83	6.47	28.30	[11]
	Ti Fiber@TiO₂@dye/ I^-/I₃^-/Stainless steel(ss)@PANi-SS@Space wire/H₂SO₄/ss@PANi	2.12	4.56	46.00	[18]
	Ti/TiO₂@N719/I^-/I₃^-/Carbon fiber(CF)/EVA/Cu-CF@RuO₂?xH₂O/H₃PO₄/PVA/CF@RuO₂?xH₂O/EVA/Cu/PDMS	-	5.64	-	[46]
QDSSC-SPC	Glass/FTO/TiO₂@CdS/CdSe/S^2-/S/Cfiber@Cu₂S/C/Electrolyte/C		1.8		[48]
DSSC-LIB	Pt/Electrolyte/TNTs@N719/Ti/TNTs/Membrane/LiCoO₂/Al	0.82	-	-	[49]
	PEN/ITO/TiO₂@N719/I^-/I₃^-/Pt/PEDOT/LiClO₄/PEDOT/Pt	-	4.37	-	[50]
	FTO/TiO₂@N3/I^-/I₃^-/Pt/PProDOT-Et₂/LiClO₄/PProDOT-Et₂/Pt	0.60	0.75	80.00	[51]
	FTO/Pt/ I^-/I₃^-/TiO₂nanotube (ATO)@N749/Ti/ ATO/Separator/Li₂SO₄/ATO/Ti/FTO	1.64	3.18	51.60	[52]
	FTO/TiO₂@bis-EDOT dye/PEDOT/C/LiClO₄/electrolyte/ppy/FTO	0.10	-	-	[53]

Device construction	η_overall*/%	η_solar*/%	η_storage*/%	Ref.
FTO/c-TiO₂/m-TiO₂/CH₃NH₃PbI₃/Carbon/Gel electrolyte/Carbon	7.10	9.60	73.96	[72]
FTO/TiO₂/Perovskite/Carbon/MnO₂/Membrane SSE/Carbon	5.26	7.79	67.50	[13]
ITO/pss/PTAA/Perovskite/PCBM/PEI/Ag/GRO/PVA/Separator/PVA/GRO	10.97	13.66	80.31	[73]
FTO/TiO₂/CH₃NH₃PbI₃/MWCNT/PMMA/PVA/PANI@acSACNT/PMMA/SACNT	1.92	2.71	70.90	[74]
PET/ITO/PEDOT:PSS/CH₃NH₃PbI₃/PCBM/CuOHNT/AgNW/AuPd/MnO₂/KOH/PVA/MnO₂/AuPd/AgNW/CuOHNT	6.97	10.41	67.00	[75]

新型光伏储电原位集成电池研究进展

Research Progress in Novel In-situ Integrative Photovoltaic-storage Tandem Cells

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