Thermal Property of Y4.67(SiO4)3O Ceramic Sintered from Hydrothermally Synthesized Spindle-like Y4.67(SiO4)3O Apatite Crystallites

doi:10.15541/jim20170495

Abstract

Abstract:

Spindle-like Y_4.67(SiO₄)₃O apatite crystallites composed of numerous nanoparticles with a mean diameter of about 50 nm were synthesized via a facile hydrothermal method at 503 K for 12 h. To the best of our knowedge, the thermal properties of the spindle-like Y_4.67(SiO₄)₃O apatite crystallites was firstly reported. Their phase composition, microstructure, formation mechanism were investigated. Results show that hydrothermal temperature greatly influences the crystal phase composition and the crystal morphology. In addition, the obtained Y_4.67(SiO₄)₃O ceramics possess low thermal conductivity and a relatively high thermal expansion coefficient, which make them a promising candidate material for environmental/thermal barrier coatings.

Key words: ceramics, Y_4.67(SiO₄)₃O apatite crystallites, thermal properties

CLC Number:

TQ174

WANG Qing-Gang, HUANG Jian-Feng, ZHOU Lei, WU Wan-Chen, CAO Li-Yun. Thermal Property of Y_4.67(SiO₄)₃O Ceramic Sintered from Hydrothermally Synthesized Spindle-like Y_4.67(SiO₄)₃O Apatite Crystallites[J]. Journal of Inorganic Materials, 2018, 33(6): 688-692.

Figures/Tables 4

Fig. 1 XRD patterns of Y4.67(SiO4)3O at different temperatures after reaction for 12 h

Fig. 2 SEM images of the products synthesized at different temperatures(a) 483 K; (b) 493 K; (c) 503 K; (d) EDS analysis spectrum of the Y4.67(SiO4)3O; (e) Schematic diagram of the growth process of the spindle-like Y4.67(SiO4)3O apatite crystallites

Fig. 3 TEM images of Y4.67(SiO4)3O. (a) Typical TEM image; (b) Magnified image of (a); (c) High-resolution TEM image of a part of the sample; (d) Selected area electronic diffraction (SAED) pattern of (c)

Fig. 4 Thermal properties of the sample. (a) TG-DSC curves of the Y4.67(SiO4)3O powders prepared at 503 K for 12 h; (b) XRD patterns of the sample (I) before and (II) after sintering in air for 5 h at 1673 K; (c) Microstructure of the surface of Y4.67(SiO4)3O after sintering in air for 5 h at 1673 K; (d) Thermal conductivity of Y4.67(SiO4)3O ceramics; (e) Thermal expansion coefficients of Y4.67(SiO4)3O ceramics

References 17

[1]	KLEMM HAGEN, TAUT CHRISTINE, WOTTING GERHARD.Long-term stability of nonoxide ceramics in an oxidative environment at 1500℃.Journal of the European Ceramic Society, 2003, 23(4): 619-627.
[2]	XU YUE, HU XUN-XUN, XU FANG-FANG,et al. Rare earth silicate environmental barrier coatings: present status and prospective. Ceramics International, 2017, 43(8): 5847-5855.
[3]	MORE KARREN L, TORTORELLI PETER F, WALKER LARRY R,et al. High temperature stability of SiC-based composites in high-water-vapor-pressure environments. Journal of the American Ceramic Society, 2003, 86(8): 1272-1281.
[4]	STOLZENBURG F, KENESEI P, ALMER J,et al. The influence of calcium-magnesium-aluminosilicate deposits on internal stresses in Yb2Si2O7 multilayer environmental barrier coatings. Acta Materialia, 2016, 105: 189-198.
[5]	WANG CHAO, CHEN MENG, WANG HONG-JIE,et al. Fabrication and thermal shock resistance of multilayer γ-Y2Si2O7 environmental barrier coating on porous Si3N4 ceramic. Journal of the European Ceramic Society, 2016, 36(3): 689-695.
[6]	AL NASIRI N, PATRA N, JAYASEELAN D D,et al. Water vapour corrosion of rare earth monosilicates for environmental barrier coating application. Ceramics International, 2017, 43(10): 7393-7400.
[7]	WANG YI-GUANG, WU YA-HUI, CHENG LAI-FEI,et al. Hot corrosion behavior of barium aluminosilicate-coated C/SiC composites at 900℃. Journal of the American Ceramic Society, 2009, 93(1): 204-208.
[8]	SEIFERT HANS J, WAGNER SIGRID, FABRICHNAYA OLGA,et al. Yttrium silicate coatings on chemical vapor deposition- SiC-precoated C/C-SiC: thermodynamic assessment and high- temperature investigation. Journal of the American Ceramic Society, 2005, 88(2): 424-430.
[9]	LEE KANG N, FOX DENNIS S, BANSAL NAROTTAM P.Rare earth silicate environmental barrier coatings for SiC/SiC composites and Si3N4 ceramics.Journal of the European Ceramic Society, 2005, 25(10): 1081-1088.
[10]	MA QING-SONG, CAI LI-HUI.Fabrication of Y2Si2O7 coating and its oxidation protection for C/SiC composites.Transactions of Nonferrous Metals Society of China, 2017, 27(2): 390-396.
[11]	SUN ZI-QI, LI MEI-SHUANG, ZHOU YAN-CHUN.Recent progress on synthesis, multi-scale structure, and properties of Y-Si-O oxides.International Materials Reviews, 2014, 59(7): 357-383.
[12]	SUN ZI-QI, ZHOU YAN-CHUN, WANG JING-YANG,et al. Thermal properties and thermal shock resistance of γ-Y2Si2O7. Journal of the American Ceramic Society, 2008, 91(8): 2623-2629.
[13]	SUN ZI-QI, LI MEI-SHUANG, ZHOU YAN-CHUN.Thermal properties of single-phase Y2SiO5.Journal of the European Ceramic Society, 2009, 29(4): 551-557.
[14]	XU ZHEN-HUA, HE LI-MIN, MU REN-DE,et al.(Y0.05La0.95)2, 2014, 116(2): 182-184.
[15]	MAO CHANG-JIE, PAN HONG-CHENG, WU XING-CAI,et al. Sonochemical route for self-assembled V2O5 bundles with spindle- like morphology and their novel application in serum albumin sensing. Journal of Physical Chemistry B, 2006, 110(30): 14709-14713.
[16]	WU RUI-FEN, PAN WEI, REN XIAO-RUI,et al. An extremely low thermal conduction ceramic: Re9.33(SiO4)6O2 silicate oxyapatite. Acta Materialia, 2012, 60: 5536-5544.
[17]	KEY THOMAS S, PRESLEY KAYLA F, HAY RANDALL S,et al. Total thermal expansion coefficients of the yttrium silicate apatite phase Y4.69(SiO4)3O. Journal of the American Ceramic, 2014, 97(1): 28-31.

Thermal Property of Y_4.67(SiO₄)₃O Ceramic Sintered from Hydrothermally Synthesized Spindle-like Y_4.67(SiO₄)₃O Apatite Crystallites

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 17

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LIU Yanyan, XIE Xi, LIU Zengqian, ZHANG Zhefeng. Metal Matrix Composites Reinforced by MAX Phase Ceramics: Fabrication, Properties and Bioinspired Designs [J]. Journal of Inorganic Materials, 2024, 39(2): 145-152.
[2]	CHEN Mengjie, WANG Qianqian, WU Chengtie, HUANG Jian. Predicting the Degradability of Bioceramics through a DFT-based Descriptor [J]. Journal of Inorganic Materials, 2024, 39(10): 1175-1181.
[3]	ZHENG Jiaqian, LU Xiao, LU Yajie, WANG Yingjun, WANG Zhen, LU Jianxi. Functional Bioadaptability in Medical Bioceramics: Biological Mechanism and Application [J]. Journal of Inorganic Materials, 2024, 39(1): 1-16.
[4]	SHI Zhe, LIU Weiye, ZHAI Dong, XIE Jianjun, ZHU Yufang. Akermanite Scaffolds for Bone Tissue Engineering: 3D Printing Using Polymer Precursor and Scaffold Properties [J]. Journal of Inorganic Materials, 2023, 38(7): 763-770.
[5]	WU Wei, BAKHET Shahd, ASANTE Naomi Addai, KAREEM Shefiu, KOMBO Omar Ramadhan, LI Binbin, DAI Honglian. In vitro Study of Biphasic Calcium Magnesium Phosphate Microspheres for Angiogenesis and Bone Formation [J]. Journal of Inorganic Materials, 2023, 38(7): 830-838.
[6]	YUAN Jingkun, XIONG Shufeng, CHEN Zhangwei. Research Trends and Challenges of Additive Manufacturing of Polymer-derived Ceramics [J]. Journal of Inorganic Materials, 2023, 38(5): 477-488.
[7]	LUO Shuwen, MA Mingsheng, LIU Feng, LIU Zhifu. Corrosion Behavior and Mechanism of LTCC Materials in Ca-B-Si System [J]. Journal of Inorganic Materials, 2023, 38(5): 553-560.
[8]	WU Junlin, DING Jiyang, HUANG Xinyou, ZHU Danyang, HUANG Dong, DAI Zhengfa, YANG Wenqin, JIANG Xingfen, ZHOU Jianrong, SUN Zhijia, LI Jiang. Fabrication and Microstructure of Gd₂O₂S:Tb Scintillation Ceramics from Water-bath Synthesized Nano-powders: Influence of H₂SO₄/Gd₂O₃ Molar Ratio [J]. Journal of Inorganic Materials, 2023, 38(4): 452-460.
[9]	LIU Yan, ZHANG Keying, LI Tianyu, ZHOU Bo, LIU Xuejian, HUANG Zhengren. Electric-field Assisted Joining Technology for the Ceramics Materials: Current Status and Development Trend [J]. Journal of Inorganic Materials, 2023, 38(2): 113-124.
[10]	SUN Jingwei, WANG Honglei, SUN Chuhan, ZHOU Xingui, JI Xiaoyu. Effects of Carbon Sources on Structure and Properties of TaC Ceramic Powder Prepared by Polymer Derived Ceramics [J]. Journal of Inorganic Materials, 2023, 38(2): 184-192.
[11]	JIN Xihai, DONG Manjiang, KAN Yanmei, LIANG Bo, DONG Shaoming. Fabrication of Transparent AlON by Gel Casting and Pressureless Sintering [J]. Journal of Inorganic Materials, 2023, 38(2): 193-198.
[12]	KANG Wenshuo, GUO Xiaojie, ZOU Kai, ZHAO Xiangyong, ZHOU Zhiyong, LIANG Ruihong. Enhanced Resistivity Induced by the Second Phase with Layered Structure in BiFeO₃-BaTiO₃ Ceramics [J]. Journal of Inorganic Materials, 2023, 38(12): 1420-1426.
[13]	LI Haiyan, KUANG Fenghua, WU Haolong, LIU Xiaogen, BAO Yiwang, WAN Detian. Temperature Dependence of Residual Tensile Stresses and Its Influences on Crack Propagation Behaviour [J]. Journal of Inorganic Materials, 2023, 38(11): 1265-1270.
[14]	HUANG Yihua, HUANG Zhengren, SHA Wenhao, ZHOU Yabin, TAN Zhouxi, ZHANG Mingkang. Thick SiC Green Bodies: Degreasing Analysis and Pressureless High Density Sintering [J]. Journal of Inorganic Materials, 2023, 38(10): 1163-1168.
[15]	WU Songze, ZHOU Yang, LI Runfeng, LIU Xiaoqian, LI Cuiwei, HUANG Zhenying. Reaction Sintered Porous Ceramics Using Iron Tailings: Preparation and Properties [J]. Journal of Inorganic Materials, 2023, 38(10): 1193-1199.