Progress on TiO2-based Nanomaterials and Its Utilization in the Clean Energy Technology

doi:10.3724/SP.J.1077.2012.00001

Abstract

Abstract:

TiO₂ nanomaterials are the research hotspots among recent nanotechnologies, and those are demonstrated having the crucial application prospects in the solar light photocatalytic splitting water into hydrogen, the photocatalytic reduction of CO₂, as well as dye-sensitized solar cells. This article mainly reviewed recent research trends of TiO₂-based nanomaterials, the existing problems, and the advances in the clean energy utilization. Especially, the hot research issues such as non-metallic element doping, high energy facets exposed titania, and compact film for dye-sensitized solar cells, were commented and prospected.

Key words: photocatalytic water splitting, reduction of carbon dioxide, titanium dioxide, dye-sensitized solar cells, photocatalytic, review

CLC Number:

TB321

ZHANG Qing-Hong. Progress on TiO₂-based Nanomaterials and Its Utilization in the Clean Energy Technology[J]. Journal of Inorganic Materials, 2012, 27(1): 1-10.

Figures/Tables 4

Fig. 1 UV-Vis diffuse reflectance spectra of nitrogen doping TiO2[9] and TiO2/Ta3N5 nanocomposite photocatalyst

Fig. 2 SEM image of anatase TiO2 with {001} facets exposed[27]

Fig. 3 (a) XRD pattern of the anatase single crystals; (b) FE-SEM image of the anatase single crystals; (c) Interfacial angle between {001} and {101} facets (68.3°±0.3° on average). The white dashed lines indicate the (001) and (101) crystal planes of anatase TiO2, respectively; (d) Small rhombus {110} facets (indicated by red circle) of the anatase single crystals; (e) Schematic diagram of the anatase single crystal; (f) The variation of MB concentration by photochemical reaction with the anatase TiO2 single crystals and the irregular TiO2 product[30]

Fig. 4 Morphology and atomic structure of anatase TiO2 crystals[32]

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[98]	作者学术成就介绍:
[99]	张青红, 男, 博士, 东华大学教授, 博士生导师. 主要从事光催化、染料敏化太阳能电池、自组装、有机/无机杂化材料的研究, 在二氧化钛纳米结构的晶相控制、形貌调控、构效关系、锐钛矿水性溶胶、可见光催化等方面成果突出, 已在Chem. Commun., Appl. Catal. B: Environ., Langmuir, J. Mater. Chem., J. Am. Ceram. Soc. 等国内外核心刊物发表学术论文80余篇, 论文他引超过1100余篇次, 单篇论文他引超过200余篇次, 获20余项中国发明专利授权, 合著《纳米氧化钛光催化材料及应用》一部. 先后主持科技部十一五支撑计划子课题1项、国家自然科学基金项目3项, 参与上海市纳米科技专项3项, 作为主要研究人员分别于2002年、2006年获得上海市自然科学奖二等奖各1项.

Progress on TiO₂-based Nanomaterials and Its Utilization in the Clean Energy Technology

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