金刚石基燃料电池催化剂的研究进展

doi:10.15541/jim20160483

无机材料学报 ›› 2017, Vol. 32 ›› Issue (7): 673-680.DOI: 10.15541/jim20160483 CSTR: 32189.14.10.15541/jim20160483

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金刚石基燃料电池催化剂的研究进展

董亮^1,2, 王艳辉², 臧建兵²

(1. 东北大学秦皇岛分校河北省电介质与电解质功能材料重点实验室, 秦皇岛066004; 2. 燕山大学亚稳材料制备技术与科学国家重点实验室, 秦皇岛066004)

收稿日期:2016-08-29 修回日期:2016-11-10 出版日期:2017-07-20 网络出版日期:2017-06-23
作者简介:董亮(1985–), 男, 讲师. E-mail: dongliang@neuq.edu.cn
基金资助:
国家自然科学基金(51602043);中央高校基本科研业务费(N152303001);河北省高等学校科学技术研究项目(QN2015315);东北大学秦皇岛分校校内科研基金(XNB201624)

Recent Progress in Diamond-based Electrocatalysts for Fuel Cells

DONG Liang^1,2, WANG Yan-Hui², ZANG Jian-Bing²

(1. Northeastern University at Qinghuangdao, Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, Qinghuangdao 066004, China; 2. Yanshan University, State Key Laboratory of Metastable Materials Science and Technology, Qinghuangdao 066004, China)

Received:2016-08-29 Revised:2016-11-10 Published:2017-07-20 Online:2017-06-23
About author:DONG Liang. E-mail: dongliang@neuq.edu.cn
Supported by:
National Natural Science Foundation of China (51602043);Fundamental Research Funds for the Central Universities (N152303001);Foundation for Science and Technology Research in Higher Education of Hebei (QN2015315);Research Funds of Northeastern University at Qinhuangdao (XNB201624)

摘要/Abstract

摘要：

金刚石是由共价键方式连接的sp³杂化碳原子组成, 具有极强的稳定性。含硼金刚石(BDD)薄膜、BDD颗粒、非掺杂纳米金刚石(ND)等新型金刚石又兼具一定的导电性, 因此成为高稳定性燃料电池催化剂的理想载体材料。研究者进一步发现通过对上述新型金刚石进行适当功能化处理, 可以进一步提高催化剂的催化活性和稳定性。对金刚石进行掺杂处理, 既包括向金刚石晶格中掺杂, 也包括向金刚石衍生的石墨结构中进行掺杂, 能够得到新型高稳定性燃料电池非铂催化剂, 且金刚石sp³结构在提高非铂催化剂稳定性方面作用独特。本文总结介绍了相关研究成果, 希望能为后续研究提供参考借鉴。

关键词: 金刚石, 燃料电池, 稳定性, 综述

Abstract:

Attributed to highly stable structure of sp³ hybridized carbon atoms, diamond has excellent physical and chemical stabilities. As new conductive diamond materials, boron-doped diamond (BDD) films and particles, as well as undoped nanodiamond (ND) has become the ideal support of the high stability electrocatalysts for fuel cells. Futher investigation showed that the activity and stability of electrocatalysts could be futher improved if the new diamond materials were properly processed. The doping treatment, including doping into diamond and the graphite structure from conversion of diamond, was used to produce diamond-based non-Pt electrocatalysts for fuel cells. It was considered that the sp³ structure of diamond played a unique role in enhancing the stability of diamond-based non-Pt electrocatalysts. In this paper, related studies of diamond-based electrocatalysts were summarized for the references of future study.

Key words: diamond, fuel cell, durability, review

中图分类号:

TQ152

董亮, 王艳辉, 臧建兵. 金刚石基燃料电池催化剂的研究进展[J]. 无机材料学报, 2017, 32(7): 673-680.

DONG Liang, WANG Yan-Hui, ZANG Jian-Bing. Recent Progress in Diamond-based Electrocatalysts for Fuel Cells[J]. Journal of Inorganic Materials, 2017, 32(7): 673-680.

图/表 5

图1 碳载被氧化导致催化剂失活的示意图

Fig. 1 Schematic illustration of losing activity the catalysts by oxidized carbon support

图2 Pt/C(Pt/E-Tek)、Pt/HDP和Pt/ODP在CO饱和的0.5 mol/L H2SO4中的循环伏安曲线[42]

Fig. 2 CV curves of Pt/C(Pt/E-Tek), Pt/HDP and Pt/ODP in COads 0.5 mol/L H2SO4[42]

图3 (a)Pt/C、Pt/ND@G-1300和Pt/ND@G-1600在ADT过程中ESA变化情况对比图, (b)ADT完成前后三种催化剂的半波电位变化情况[51]

Fig. 3 (a) Changes of Pt/C, Pt/ND@G-1300 and Pt/ND@G-1600 ESA related (vs. initial) with cycle number, (b) half-wave potentials of Pt/GND1300, Pt/GND1600 and Pt/C before and after ADT[51]

图4 VA-BND制备流程示意图[52]

Fig. 4 The procedures for VA-BND preparation[52]

图5 Co-N-C/ND与Co-N-C在氧饱和0.1 mol/L KOH溶液中的I-t对比曲线[57]

Fig. 5 I-t curves for Co-N-C/ND and Co-N-C in O2-saturated 0.1 mol/L KOH solution[57]

参考文献 59

[1]	黄镇江, 刘凤君. 燃料电池及其应用. 北京: 电子工业出版社, 2005: 5-14.
[2]	SHARAF O Z, ORHAN M F.An overview of fuel cell technology: fundamentals and applications.Renew. Sust. Energ. Rev., 2014, 32: 810-853.
[3]	O'HAYRE R, CHA S W, PRINZ F B, et al. Fuel Cell Fundamentals. The second edition. New York: John Wiley & Sons, 2016: 3-23.
[4]	ARICO A, SRINIVASAN S, ANTONUCCI V.DMFCs: From fundamental aspects to technology development.Fuel cells, 2001, 1(2): 133-161.
[5]	MCNICOL B, RAND D, WILLIAMS K.Direct methanol-air fuel cells for road transportation.J. Power Sources, 1999, 83(1): 15-31.
[6]	YU X, YE S.Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC.J. Power Sources, 2007, 172(1): 133-144.
[7]	KANGASNIEMI K H, CONDIT D, JARVI T.Characterization of vulcan electrochemically oxidized under simulated pem fuel cell conditions.J. Electrochem. Soc., 2004, 151(4): E125-E132.
[8]	REISER C A, BREGOLI L, PATTERSON T W, et al.A reverse- current decay mechanism for fuel cells.Electrochem. Solid-State Lett., 2005, 8(6): A273-A276.
[9]	LIU M, CHEN W.Green synthesis of silver nanoclusters supported on carbon nanodots: enhanced photoluminescence and high catalytic activity for oxygen reduction reaction.Nanoscale, 2013, 5(24): 12558-12564.
[10]	SHAO Y, YIN G, GAO Y, et al.Durability study of Pt∕C and Pt∕CNTs catalysts under simulated pem fuel cell conditions.J. Electrochem. Soc., 2006, 153(6): A1093-A1097.
[11]	LIU M, LU Y, CHEN W.PdAg nanorings supported on graphene nanosheets: highly methanol‐tolerant cathode electrocatalyst for alkaline fuel cells.Adv. Funct. Mater., 2013, 23(10): 1289-1296.
[12]	LIU M, ZHANG R, CHEN W.Graphene-supported nanoelectrocatalysts for fuel cells: synthesis, properties, and applications.Chem. Rev., 2014, 114(10): 5117-5160.
[13]	LU Y, JIANG Y, WU H, et al.Nano-PtPd cubes on graphene exhibit enhanced activity and durability in methanol electrooxidation after Co stripping-cleaning.J. Phys. Chem. C, 2013, 117(6): 2926-2938.
[14]	LU Y, JIANG Y, CHEN W.Graphene nanosheet-tailored ptpd concave nanocubes with enhanced electrocatalytic activity and durability for methanol oxidation.Nanoscale, 2014, 6(6): 3309-3315.
[15]	ZHANG R, CHEN W.Non-Precious Ir-V bimetallic nanoclusters assembled on reduced graphene nanosheets as catalysts for the oxygen reduction reaction.J. Mater. Chem. A, 2013, 1(37): 11457-11464.
[16]	ZHANG R, HE S, LU Y, et al.Fe, Co, N-functionalized carbon nanotubes in situ grown on 3d porous N-doped carbon foams as a noble metal-free catalyst for oxygen reduction.J. Mater. Chem. A, 2015, 3(7): 3559-3567.
[17]	LIU M, HE S, CHEN W.Free-standing 3D hierarchical carbon foam-supported PtCo nanowires with “Pt Skin” as advanced electrocatalysts.Electrochim. Acta, 2016, 199: 218-226.
[18]	方啸虎. 超硬材料科学与技术. 北京: 中国建材工业出版社, 1998: 17-21.
[19]	AVGOUROPOULOS G, IOANNIDES T.CO Tolerance of Pt and Rh catalysts: effect of co in the gas-phase oxidation of H2 over Pt and Rh supported catalysts.Appl. Catal. B- Environ., 2005, 56(1): 77-86.
[20]	GARC A G, SILVA-CHONG J, GUILL N-VILLAFUERTE O, et al. CO tolerant catalysts for PEM fuel cells: spectroelectrochemical studies.Catal. Today, 2006, 116(3): 415-421.
[21]	FERREIRA P, SHAO-HORN Y, MORGAN D, et al.Instability of Pt∕C electrocatalysts in proton exchange membrane fuel cells a mechanistic investigation.J. Electrochem. Soc., 2005, 152(11): A2256-A2271.
[22]	KOH S, YU C, MANI P, et al.Activity of ordered and disordered pt-co alloy phases for the electroreduction of oxygen in catalysts with multiple coexisting phases.J. Power Sources, 2007, 172(1): 50-56.
[23]	BAR-ON I, KIRCHAIN R, ROTH R.Technical cost analysis for pem fuel cells.J. Power Sources, 2002, 109(1): 71-75.
[24]	GONG K, DU F, XIA Z, et al.Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction.Science, 2009, 323(5915): 760-764.
[25]	QU L, LIU Y, BAEK J B, et al.Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells.ACS Nano, 2010, 4(3): 1321-1326.
[26]	KRAMM U I, LEF VRE M, LAROUCHE N, et al.Correlations between mass activity and physicochemical properties of fe/n/c catalysts for the ORR in PEM fuel cell via 57Fe mößbauer spectroscopy and other techniques.J. Am. Chem. Soc., 2013, 136(3): 978-985.
[27]	SWAIN G M.The Susceptibility to surface corrosion in acidic fluoride media: a comparison of diamond, hopg, and glassy carbon electrodes.J. Electrochem. Soc., 1994, 141(12): 3382-3393.
[28]	GAO F, YANG N, SMIRNOV W, et al.Size-controllable and homogeneous platinum nanoparticles on diamond using wet chemically assisted electrodeposition.Electrochim. Acta, 2013, 90: 445-451.
[29]	LU X, HU J, FOORD J S, et al.Electrochemical deposition of Pt-Ru on diamond electrodes for the electrooxidation of methanol.J. Electroanal. Chem., 2011, 654(1): 38-43.
[30]	MAVROKEFALOS C K, NELSON G W, POLL C G, et al.Electrochemical aspects of Pt-Cu and Cu modified boron-doped diamond.Phys. Status Solidi A, 2015, 212(11): 2559-2567.
[31]	SIN G, FOTI G, COMNINELLIS C.Boron-doped diamond (bdd)-supported pt/sn nanoparticles synthesized in microemulsion systems as electrocatalysts of ethanol oxidation.J. Electroanal. Chem., 2006, 595(2): 115-124.
[32]	SALAZAR-BANDA G R, SUFFREDINI H B, AVACA L A, et al. methanol and ethanol electro-oxidation on Pt-SnO2 and Pt-Ta2O5 Sol-Gel-modified boron-doped diamond surfaces.Mater. Chem. Phys., 2009, 117(2): 434-442.
[33]	WANG J, SWAIN G, TACHIBANA T, et al.The incorporation of Pt nanoparticles into boron-doped diamond thin-films: dimensionally stable catalytic electrodes.J. New Mat. Electr. Sys, 2000, 3(1): 75-82.
[34]	LYU X, HU J, FOORD J S, et al.A novel electroless method to prepare a platinum electrocatalyst on diamond for fuel cell applications.J. Power Sources, 2013, 242: 631-637.
[35]	GONZALEZ-GONZALEZ I, TRYK D, CABRERA C R.Polycrystalline boron-doped diamond films as supports for methanol oxidation electrocatalysts.Diam. Relat. Mater., 2006, 15(2): 275-278.
[36]	EL ROUSTOM B, SINE G, FOTI G, et al.A novel method for the preparation of bi-metallic (Pt-Au) nanoparticles on boron doped diamond (BDD) substrate: application to the oxygen reduction reaction.J. Appl. Electrochem., 2007, 37(11): 1227-1236.
[37]	SPĂTARU T, PREDA L, OSICEANU P, et al. Electrochemical deposition of Pt-RuOxNh2O composites on conductive diamond and its application to methanol oxidation in acidic media.Electrocatalysis, 2016, 7(2): 140-148.
[38]	SALAZAR-BANDA G R, EGUILUZ K I, AVACA L A. Boron-doped diamond powder as catalyst support for fuel cell applications.Electrochem. Commun., 2007, 9(1): 59-64.
[39]	SPĂTARU N, ZHANG X, SPĂTARU T, et al. Platinum electrodeposition on conductive diamond powder and its application to methanol oxidation in acidic media.J. Electrochem. Soc., 2008, 155(3): B264-B269.
[40]	LA-TORRE-RIVEROS L, ABEL-TATIS E, M NDEZ-TORRES A E, et al. Synthesis of platinum and platinum-ruthenium-modified diamond nanoparticles.J. Nanopart. Res., 2011, 13(7): 2997-3009.
[41]	KIM J, CHUN Y S, LEE S K, et al.Improved electrode durability using a boron-doped diamond catalyst support for proton exchange membrane fuel cells.RSC Advances, 2015, 5(2): 1103-1108.
[42]	CELORRIO V, PLANA D, FL REZ-MONTA O J, et al. Methanol oxidation at diamond-supported Pt nanoparticles: effect of the diamond surface termination.J. Phys. Chem. C, 2013, 117(42): 21735-21742.
[43]	WANG J, SWAIN G M.Fabrication and evaluation of platinum/diamond composite electrodes for electrocatalysis preliminary studies of the oxygen-reduction reaction.J. Electrochem. Soc., 2003, 150(1): E24-E32.
[44]	ZANG J, WANG Y, ZHAO S, et al.Electrochemical properties of nanodiamond powder electrodes.Diam. Relat. Mater., 2007, 16(1): 16-20.
[45]	BIAN L, WANG Y, ZANG J, et al.Microwave synthesis and characterization of pt nanoparticles supported on undoped nanodiamond for methanol electrooxidation.Int. J. Hydrogen. Energ, 2012, 37(2): 1220-1225.
[46]	LU R, ZANG J, WANG Y, et al.Microwave synthesis and properties of nanodiamond supported ptru electrocatalyst for methanol oxidation.Electrochim. Acta, 2012, 60: 329-333.
[47]	ZANG J, WANG Y, BIAN L, et al.Graphene growth on nanodiamond as a support for a Pt electrocatalyst in methanol electro-oxidation.Carbon, 2012, 50(8): 3032-3038.
[48]	ZHAO Y, WANG Y, CHENG X, et al.Platinum nanoparticles supported on epitaxial TiC/nanodiamond as an electrocatalyst with enhanced durability for fuel cells.Carbon, 2014, 67: 409-416.
[49]	ZHAO Y, WANG Y, DONG L, et al.Core-shell structural nanodiamond@tin supported pt nanoparticles as a highly efficient and stable electrocatalyst for direct methanol fuel cells.Electrochim. Acta, 2014, 148: 8-14.
[50]	ZHAO Y, WANG Y, ZANG J, et al.A novel support of nano titania modified graphitized nanodiamond for Pt electrocatalyst in direct methanol fuel cell.Int. J. Hydrogen. Energy, 2015, 40(13): 4540-4547.
[51]	DONG L, ZANG J, WANG Y, et al.Graphitized nanodiamond as highly efficient support of electrocatalysts for oxygen reduction reaction.J. Electrochem. Soc., 2014, 161(3): F185-F191.
[52]	LIU Y, CHEN S, QUAN X, et al.Tuning the electrochemical properties of a boron and nitrogen codoped nanodiamond rod array to achieve high performance for both electro-oxidation and electro-reduction.J. Mater. Chem. A, 2013, 1(46): 14706-14712.
[53]	GAN P, FOORD J S, COMPTON R G.Surface modification of boron-doped diamond with microcrystalline copper phthalocyanine: oxygen reduction catalysis.Chemistry Open, 2015, 4(5): 606-612.
[54]	KOH J, PARK S H, CHUNG M W, et al.Diamond@carbon-onion hybrid nanostructure as a highly promising electrocatalyst for the oxygen reduction reaction.RSC Advances, 2016, 6(33): 27528-27534.
[55]	DONG L, ZANG J, SU J, et al.Nanodiamond/ nitrogen-doped graphene (core/shell) as an effective and stable metal-free electrocatalyst for oxygen reduction reaction.Electrochim. Acta, 2015, 174: 1017-1022.
[56]	LIU X, WANG Y, DONG L, et al.One-step synthesis of shell/core structural boron and nitrogen co-doped graphitic carbon/ nanodiamond as efficient electrocatalyst for the oxygen reduction reaction in alkaline media.Electrochim. Acta, 2016, 194: 161-167.
[57]	WU Y, ZANG J, DONG L, et al.High performance and bifunctional cobalt-embedded nitrogen doped carbon/nanodiamond electrocatalysts for oxygen reduction and oxygen evolution reactions in alkaline media.J. Power Sources, 2016, 305: 64-71.
[58]	ZHU Y, LIN Y, ZHANG B, et al.Nitrogen-doped annealed nanodiamonds with varied Sp2/Sp3 ratio as metal‐free electrocatalyst for the oxygen reduction reaction.ChemCatChem, 2015, 7(18): 2840-2845.
[59]	JANG D M, IM H S, BACK S H, et al.Laser-induced graphitization of colloidal nanodiamonds for excellent oxygen reduction reaction.Phys. Chem. Chem. Phys., 2014, 16(6): 2411-2416.

金刚石基燃料电池催化剂的研究进展

Recent Progress in Diamond-based Electrocatalysts for Fuel Cells

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