Journal of Inorganic Materials

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Thermal Conductivity and Catalytic Mechanism of Recrystallized Graphite by Titanium

QIU Hai-Peng; SONG Yong-Zhong; GUO Quan-Gui; ZHAI Geng-Tai; LIU Lang   

  1. Institute of Coal Chemistry; Chinese Academy of Sciences; Taiyuan 030001; China
  • Received:2001-12-17 Revised:2002-01-21 Published:2003-01-20 Online:2003-01-20

Abstract: The recrystallized graphite was prepared from calcined coke, coal-tar pitch and titanium by hot-pressing
progress in order to investigate the effects of the amount of titanium on the thermal conductivity, bending strength and microstructure of
recrystallized graphite. Experimental results show that the recrystallized graphite exhibits higher thermal conductivity and higher bending
strength than the pure graphite prepared by the same process. For the orientation of graphite layers of the present RG-15 materials, the thermal
conductivity and the bending strength are 424W/(m·k) and 50.2MPa at room temperature, respectively. Microstructure analysis reveals that a
little amount of titanium can increase the degree of graphitization of recrystallized graphite, but overlarge amount of titanium dopant makes
basic physical properties worse. For the recrystallized graphite with titanium concentration of 15wt%, the degree of development and arrangement
of graphite crystallite is the best. The degree of graphitization of the present RG-15 material is 96.4% and the value of La is 306nm. XRD analysis
indicates that titanium added to carbon substrate is in the form of TiC precipitates. The catalytic role of titanium to preparing recrystallized
graphite can be explained by the liquid phase transition mechanism.

Key words: thermal conductivity, recrystallized graphite, microstructure, catalytic mechanism3

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