锂离子电池中钒氧化物电极材料的研究现状

无机材料学报

锂离子电池中钒氧化物电极材料的研究现状

陈昌国; 刘渝萍; 李兰

重庆大学化学化工学院重庆 400044

收稿日期:2003-11-17 修回日期:2004-03-09 出版日期:2004-11-20 网络出版日期:2004-11-20

Development of Vanadium Oxide in Lithium Ion Batteries

CHEN Chang-Guo; LIU Yu-Ping; LI Lan

College of Chemistry and Chemical Engineering; Chongqing University; Chongqing 400044; China

Received:2003-11-17 Revised:2004-03-09 Published:2004-11-20 Online:2004-11-20

摘要/Abstract

摘要： 综述了钒氧化物在锂离子电池中的应用,重点介绍了V₂O₅、V₆O₁₃、VO₂、V₃O₇、V₆O₁₄的结构、制备方法以及其锂离子电池的电化学性质,说明了V₄O₉、V₂O₃难在锂离子电池中应用的原因,讨论了钒氧化物作锂离子电池的正极材料的优点以及存在的问题,最后提出钒氧化物有希望成为实用的锂离子电池阴极材料.

关键词: 锂离子电池, 钒氧化物, 电极材料

Abstract: The development of vanadium oxides in lithium ion batteries was summaried. The structure, synthesis methods, electrochemical performances of V₂O₅, V_6
13, VO₂, V₃O₇ and V₆O₁₄ in lithium ion batteries were reviewed. The reasons for V₄O₉, V₂O₃ excluded from the application in lithium ion batteries were explained. Then the advantage and problem of vanadium oxides as cathode materials of lithium ion batteries were pointed out. Finally the authors considered that those vanadium oxides could be promising as cathode materials of lithium ion batteries.

Key words: lithium ion battery, vanadium oxides, electrode material

中图分类号:

TM911

陈昌国,刘渝萍,李兰. 锂离子电池中钒氧化物电极材料的研究现状[J]. 无机材料学报.

CHEN Chang-Guo,LIU Yu-Ping,LI Lan. Development of Vanadium Oxide in Lithium Ion Batteries[J]. Journal of Inorganic Materials.

参考文献

[1] 任旭梅, 吴川, 何国蓉, 等. 化学研究与应用, 2000, 12 (4): 360--364.
[2] 詹晖, 周运鸿. 电源技术, 1999, 23 (3): S102--S105.
[3] 刘景, 温兆银, 吴梅梅, 等(Liu Jing, et al). 无机材料学报(Journal of Inorganic Materials), 2002, 17 (1): 1--9.
[4] 张国昀, 姜长印, 万春荣, 等. 电源技术, 2001, 25: S175--S178.
[5] 周静, 陈文, 徐庆, 等. 分子科学学报, 2001, 17 (2): 71--76.
[6] 张青莲, 申泮文. 无机化学丛书, 第八卷. 北京: 科学出版社, 1998. 173--281.
[7] 童茂松, 戴国瑞, 高鼎三, 等. 功能材料, 2000, 31 (3): 230--232.
[8] Yoshiaki Asami. 新型碳材料, 1997, 12 (1): 19--23.
[9] Legendre J J, Livage J. J of colloid and interfer science, 1983, 94 (1): 75--83.
[10] Chung S K, Chmilenko N A, Borovykov A Ya, et al. J. Power Sources, 1999, 84: 6--11.
[11] Owens B B, Passerini S, Smyrl W H. Electrochem. Acta, 1999, 45: 215--224.
[12] 储炜, 吴升辉, 尤金跨. 电源技术, 1998, 22 (6): 256--260.
[13] 钟俊辉. 电源技术, 1997, 21 (4): 174--177.
[14] Wang Dequan, Liao Zhenjiang, Feng Xikang, et al. J. Power Sources, 1989, 26 (3-4): 347--353.
[15] Frazer E J, Phang S. J. Power Sources, 1983, 10 (1): 33--41.
[16] Saidi M Y, Koksbang R, Saidi E S, et al. J. Power Sources, 1997, 68 (2): 726--729.
[17] West K, Zachau-Christiansen B, Jacobsen T, et al. J. Power Sources, 1985, 14 (1-3): 235--245.
[18] Menetrier M, Levasseur A, Delmas. Materials Science and Engineering B, 1989, 3 (1-2): 103--107.
[19] Saidi M Y, Barker J. Solid State Ionics, 1995, 78 (1-2): 169--173.
[20] Barker J, Koksbang R. Solid State Ionics, 1995, 78 (1-2): 162--167.
[21] 刘丽敏, 李长江. 北京化工学院学报(自然科学版), 1993, 20 (3): 118--121.
[22] Murphy D W, Christian P A, DiSalvo F J, et al. J. Electrochem. Soc., 1981, 128 (10): 2053--2060.
[23] Abraham K M, Goldman J L, Dempsey M D. J. Electrochem. Soc., 1981, 128 (12): 2493--2501.
[24] 余渡元, 仇卫华, 刘庆国, 等. 化学通报, 1992, 7: 30--31.
[25] 叶复汉. 材料科学发展, 1989, 3 (1): 81--85.
[26] 刘国强, 徐宁, 曾潮流, 等. 电源技术, 2002, 26 (2): 114--118.
[27] 徐时清, 赵康, 谷臣清. 稀有金属, 2002, 26 (3): 169--172.
[28] 卢勇, 林理彬. 功能材料, 2001, 32 (6): 657--659.
[29] 许旻, 邱家稳, 何延春, 等. 真空与低温, 2001, 7 (3): 136--138.
[30] Christian P A, Di Salvo F J, Murphy D W. Nonaqueous Secondary Cell Using Vanadium Oxide Positive Electrode. U. S. Pat, 4228226, 1980.
[31] Molenda J, Stoklosa A. Solid State Ionics, 1989, 36 (10): 43--52.
[32] Tsang C, Manthiram A. J. Electrochem. Soc., 1997, 144 (2): 520--524.
[33] Saidi M Y, Koksbang R, Saidi E S, et al. Electrochim. Acta, 1997, 42 (8): 1181--1187.
[34] Hammouche A, Hammou A. Electrochim. Acta, 1987, 32 (10): 1451--1452.
[35] Tranchant A, Messina R, Perichon J. J. Electroanal. Chem., 1980, 113 (10): 225--232.