LiMn2-2xLixNixO4(0≤X≤0.1)阴极材料的结构和电化学性能

无机材料学报

LiMn_2-2xLi_xNi_xO₄(0≤X≤0.1)阴极材料的结构和电化学性能

涂健; 曹高劭; 庄大高; 赵新兵

浙江大学材料科学与工程系, 杭州 310027

收稿日期:2004-08-31 修回日期:2004-10-10 出版日期:2005-09-20 网络出版日期:2005-09-20

Structural and Electrochemical Characterization of LiMn_2-2xLi_xNi_xO₄ (0≤x≤0.1) Cathode Materials

TU Jian; CAO Gao-Shao; ZHUANG Da-Gao; ZHAO Xin-Bing

Department of Materials Science and Engineering; Zhejiang University; Hangzhou 310027, China

Received:2004-08-31 Revised:2004-10-10 Published:2005-09-20 Online:2005-09-20

摘要/Abstract

摘要： 采用高温固相法,合成了LiMn_2-2xLi_xNi_xO₄(x=0.03、0.05、0.075、0.100)试样.用X射线衍射(XRD)和场发射扫描电镜(FESEM)对试样的晶体结构和形貌进行了表征.从试样的充放电性能,室温和高温下(55℃)循环性能等方面,并结合X射线吸收精细结构(X-rayabsorptionfinestructure,XAFS)所得到的试样中MnO₆八面体中键长的变化分析了锂镍协同掺杂对尖晶石结构的稳定作用.实验表明:与尖晶石LiMn₂O₄相比,LiMn_2-2xLi_xNi_xO₄试样在室温和55℃时具有良好的容量保持能力,是由于Li,Ni协同掺杂对试样的结构起了稳定作用.

关键词: 锂离子电池, 阴极材料, 双掺杂, 结构分析

Abstract: Lithium and nickel co-doped LiMn_2-2xLi_xNi_xO₄ cathode materials (x= 0, 0.03, 0.05, 0.075, 0.1) were synthesized by a high temperature solid-state reaction route. The microstructures and morphologies of the samples were characterized by X-ray powder diffraction, X-ray absorption fine structure analysis and field emitted scanning electronic microscopy. The bond lengths of the MnO6 octahedrons and the electrochemical performances in both room temperature and elevated temperature (55℃) were characterized and discussed in comparison with LiMn₂O₄ spinel. The result reveals that LiMn_2-2xLi_xNi_xO₄ samples have a good reversibility. It is suggested that the co-doping of lithium and nickel in LiMn₂O₄-based compounds could stabilize the spinel structure and improve the capacity retention of the cathode materils.

Key words: lithium ion battery, cathode material, co-doping, structure analysis

中图分类号:

TM911

涂健,曹高劭,庄大高,赵新兵. LiMn_2-2xLi_xNi_xO₄(0≤X≤0.1)阴极材料的结构和电化学性能[J]. 无机材料学报.

TU Jian,CAO Gao-Shao,ZHUANG Da-Gao,ZHAO Xin-Bing. Structural and Electrochemical Characterization of LiMn_2-2xLi_xNi_xO₄ (0≤x≤0.1) Cathode Materials[J]. Journal of Inorganic Materials.

参考文献

[1] Megahed S, Ebner W. J. Power Sources, 1994, 54: 155-162.
[2] Sigala C, Guyomard D, Vebaere A, et al. Solid State Ionic, 1995, 81 (3-4): 167-170.
[3] Thackery M M, Johnson P J, De Picciotto L A, et al. Mater. Res. Bull., 1984, 19: 179-187.
[4] Ma S, Noguchi H, Yoshio M. J. Power Sources, 2001, 97-98: 385-388.
[5] Blyr A, Sigala C, Amatucci G, et al. J. Electrochem. Soc., 1996, 143 (6): L136-L138.
[6] Pasquier A du, Blyr A, Cressent A, et al. J. M. J. Power Sources, 1999, 81-82: 54-59.
[7] Li G, Lijima Y, Kudo Y, et al. Solid State Ionics, 2002, 146: 55-63.
[8] Shin Y, Manthiram A. J. Chem. Mater., 2003, 15: 2954-2961.
[9] Thackery M M, Yang S, Kahaian A J, et al. Electrochem. Solid-state Lett., 1998, 1: 7-9.
[10] Amatucci G C, Pieira N, Zheng T, et al. J. Power Sources, 1999, 81-82: 39-43.
[11] Shao-horn Y, Hackney S A, Kahaian A J, et al. J. Power Sources, 1999, 81-82: 496-499.
[12] Gao Y, Dahn J R. Solid State Ionics, 1996, 84: 33-40.
[13] Shin Y, Manthiram A. Electrochem. Solid-state Lett., 2003, 6: A249-A251.
[14] Wohlfahrt-Mehrens M, Vogler C, Garche J. J. Power Sources, 2004, 127: 58-64.
[15] Xia Y, Yoshio M. J Power Sources, 1997, 66: 129-133.
[16] Sun Y, Jin S. J. Mater. Chem., 1998, 8 (11): 2399-2404.
[17] Sun Y K, Yoon C S, Kim C K, et al. J. Mater. Chem., 2001, 11: 2519-2522.
[18] Xia Y, Hedeshima Y, Kumada N, et al. J. Power Sources, 1998, 24: 24-28.
[19] Lee J H, Hong J K, Jang D H, et al. J. Power Sources, 2000, 89: 7-14.
[20] 杨书廷, 贾俊华, 陈红军(YANG Shu-Ting, et al). 无机材料学报(Journal of Inorganic materials), 2003, 18 (2): 301-306.
[21] Zhong Q, Banakdarpour A, Zhang M, et al. J. Electrochem. Soc., 1997, 144 (1): 205-213.
[22] Roberson A D, Lu S H, Howard W F. J. Electrochem. Soc., 1997, 144 (10): 3505-3512.
[23] Ali E. Solid State Ionics, 2004, 167 (3-4): 237-242.
[24] Liu Z, Wang H, Fang L, et al. J. Power Sources, 2002, 104: 101-107.
[25] Ozawa N, Donoue K, Yao T. Electrochem. Solid-state Lett., 2003 6 (6): A106-A108.
[26] Shin Y, Manthiram A. Electrochem. Solid-state Lett., 2003, 6 (2:) A34-A36.
[27] Shin Y, Manthiram A. J Power Sources, 2004, 126: 169-174.
[28] Sun Y, Oh B, Lee H. J. Electrocemica Acta, 2000, 46: 541-546.
[29] Li G, Ikuta H, Uchida T. J. Electrochem. Soc., 1996, 143 (1): 178-183.
[30] Amine K, Tukamoto H, Yasuda H, et al. J. Power Sources, 1997, 68: 604-608.
[31] Youhei S, Izumi N, Toshio T, et al. J. Solid State Chemisty, 1997, 133: 587-590.
[32] Yanko M, Todorov H Y, Yoshio M. J. Power Sources, 1999, 77: 198-201.
[33] Gao Y, Reimers J N, Dahn J R. Phy. Rev. B, 1996, 54 (6): 3878-3881.
[34] Zheng T, Dahn J R. Phy. Rev. B, 1997, 56 (7): 3800-3805.

LiMn_2-2xLi_xNi_xO₄(0≤X≤0.1)阴极材料的结构和电化学性能

Structural and Electrochemical Characterization of LiMn_2-2xLi_xNi_xO₄ (0≤x≤0.1) Cathode Materials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	刘鹏东, 王桢, 刘永锋, 温广武. 硅泥在锂离子电池中的应用研究进展[J]. 无机材料学报, 2024, 39(9): 992-1004.
[2]	程节, 周月, 罗薪涛, 高美婷, 骆思妃, 蔡丹敏, 吴雪垠, 朱立才, 袁中直. 蛋黄壳结构FeF₃·0.33H₂O@N掺杂碳纳米笼正极材料的构筑及其电化学性能[J]. 无机材料学报, 2024, 39(3): 299-305.
[3]	胡梦菲, 黄丽萍, 李贺, 张国军, 吴厚政. 锂/钠离子电池硬碳负极材料的研究进展[J]. 无机材料学报, 2024, 39(1): 32-44.
[4]	苏楠, 邱介山, 王治宇. 高容量氟掺杂碳包覆纳米硅负极材料: 气相氟化法制备及其储锂性能[J]. 无机材料学报, 2023, 38(8): 947-953.
[5]	杨卓, 卢勇, 赵庆, 陈军. X射线衍射Rietveld精修及其在锂离子电池正极材料中的应用[J]. 无机材料学报, 2023, 38(6): 589-605.
[6]	宿拿拿, 韩静茹, 郭印毫, 王晨宇, 石文华, 吴亮, 胡执一, 刘婧, 李昱, 苏宝连. 基于ZIF-8的三维网络硅碳复合材料锂离子电池性能研究[J]. 无机材料学报, 2022, 37(9): 1016-1022.
[7]	王洋, 范广新, 刘培, 尹金佩, 刘宝忠, 朱林剑, 罗成果. 钾离子掺杂提高锂离子电池正极锰酸锂性能的微观机制[J]. 无机材料学报, 2022, 37(9): 1023-1029.
[8]	朱河圳, 王选朋, 韩康, 杨晨, 万睿哲, 吴黎明, 麦立强. 超高镍LiNi_0.91Co_0.06Al_0.03O₂@Ca₃(PO₄)₂正极材料的储锂稳定性的提升机制[J]. 无机材料学报, 2022, 37(9): 1030-1036.
[9]	冯锟, 朱勇, 张凯强, 陈长, 刘宇, 高彦峰. 勃姆石纳米片增强锂离子电池隔膜性能研究[J]. 无机材料学报, 2022, 37(9): 1009-1015.
[10]	陈莹, 栾伟玲, 陈浩峰, 朱轩辰. 基于应力场的锂离子电池正极多尺度失效研究[J]. 无机材料学报, 2022, 37(8): 918-924.
[11]	江依义, 沈旻, 宋半夏, 李南, 丁祥欢, 郭乐毅, 马国强. 双功能电解液添加剂对锂离子电池高温高电压性能的影响[J]. 无机材料学报, 2022, 37(7): 710-716.
[12]	苏东良, 崔锦, 翟朋博, 郭向欣. 石榴石型Li_6.4La₃Zr_1.4Ta_0.6O₁₂对Si/C负极表面固体电解质中间相的调控机制研究[J]. 无机材料学报, 2022, 37(7): 802-808.
[13]	肖美霞, 李苗苗, 宋二红, 宋海洋, 李钊, 毕佳颖. 表面端基卤化Ti₃C₂ MXene应用于锂离子电池高容量电极材料的研究[J]. 无机材料学报, 2022, 37(6): 660-668.
[14]	王禹桐, 张非凡, 许乃才, 王春霞, 崔立山, 黄国勇. 水系锂离子电池负极材料LiTi₂(PO₄)₃的研究进展[J]. 无机材料学报, 2022, 37(5): 481-492.
[15]	李昆儒, 胡省辉, 张正富, 郭玉忠, 黄瑞安. 源于溪木贼的高性能锂离子电池三维多孔生物质硅/碳复合负极材料[J]. 无机材料学报, 2021, 36(9): 929-935.