C/C复合材料高温抗氧化涂层的研究现状与展望

doi:10.3724/SP.J.1077.2010.00337

摘要/Abstract

摘要：

C/C复合材料在高温下的氧化严重制约了该材料在航空航天领域的推广应用，涂层技术是目前解决该材料高温易氧化的最佳手段.本文综述了C/C复合材料高温抗氧化技术在玻璃涂层、金属涂层、陶瓷涂层和复合涂层等体系方面的研究现状，总结了C/C复合材料高温抗氧化涂层在传统制备工艺的改善以及新方法的开发等方面取得的研究成果，并提出了C/C复合材料高温抗氧化涂层当前研究中存在的问题和今后潜在的发展方向.

关键词: C/C复合材料, 涂层, 氧化

Abstract:

Oxidation of carbon/carbon (C/C) composites limits their applications as the high-temperature structural materials in aeronautics and aerospace fields. Coating is a logical method for protection of C/C composites against oxidation at high temperature. The research status of several oxidation resistant coatings, including glass, metal, ceramic and composite coatings are reviewed. Development of the traditional preparation technologies and exploitation of new methods for the preparation of oxidation resistant coatings are introduced. The present problems and the potential development direction on the investigation of oxidation resistant coatings for C/C composites are also proposed.

Key words: carbon/carbon composites, coating, oxidation

中图分类号:

O472
','1');return false;" target="_blank">
O472

李贺军,薛晖,付前刚,张雨雷,史小红,李克智. C/C复合材料高温抗氧化涂层的研究现状与展望[J]. 无机材料学报, 2010, 25(4): 337-343.

LI He-Jun,XUE Hui,FU Qian-Gang,ZHANG Yu-Lei,SHI Xiao-Hong,LI Ke-Zhi. Research Status and Prospect of Antioxidation Coatings for Carbon/Carbon Composites[J]. Journal of Inorganic Materials, 2010, 25(4): 337-343.

参考文献

[1]Savage G. Carboncarbon Composites. London: Chapman & Hall, 1993: 198-209.
[2]李贺军. 炭/炭复合材料. 新型炭材料, 2001, 16(2): 7-8.
[3]傅恒志. 未来航空发动机材料面临的挑战与发展趋向. 航空材料学报. 1998, 18(4): 52-61.
[4]Buckley J D. Carboncarbon, an overview. Am. Ceram. Bull., 1988, 67(2): 364-368.
[5]Jacobson N S, Curry D M. Oxidation microstructure studies of reinforced carbon/carbon.Carbon,2006, 44(7):1142-1150
[6]黄剑锋, 李贺军, 熊信柏, 等. 炭/炭复合材料高温抗氧化涂层的研究进展.新型炭材料,2005, 20(4):373-379
[7]沈学涛, 李克智, 李贺军, 等（SHEN Xue-Tao，et al）. 烧蚀产物ZrO2 对ZrC 改性C/C 复合材料烧蚀的影响. 无机材料学报 (Journal of Inorganic Materials), 2009, 24(5): 943-947.
[8]付前刚, 李贺军, 黄剑锋, 等. 炭/炭复合材料磷酸盐涂层的抗氧化性能研究.材料保护,2005, 38(3):52-54
[9]Delaval R, Palavit G, Rey J, et al. Method for Protecting a Porous Carbon-containing Material from Oxidation, and Material Obtained thereby. US Patent: 5714244, 1998.02.03.
[10]Thebault J, Laxague M, Rey J, et al. Method for Applying an AntiOxidative Coating on Brake Disks of a Carbon-containing Composite Material. US Patent: 5686144, 1997.11.11.
[11]Federico S, Monica F, Milena S. Multilayer coating with self-sealing properties for carboncarbon composites.Carbon,2003, 41(11):2105-2111
[12]Fu Q G, Li H J, Li K Z, et al. A SiC/glass oxidation protective coating for carbon/carbon composites for application at 1173K.Carbon,2007, 45(4):892-894
[13]Fu Q G, Li H J, Shi X H, et al. Doublelayer oxidation protective SiC/glass coatings for carbon/carbon composites.Surf. Coat. Tech,2006, 200(11):3473-3477
[14]Fu Q G, Li H J, Shi X H, et al. Oxidation protective glass coating for SiC coated carbon/carbon composites for application at 1773K.Mater. Lett,2006, 60(3):431-434
[15]Worrell W L, Lee K N. High Temperature Alloys. US Patent: 6127047, 2000.10.03.
[16]Huang M, Li K Z, Li H J, et al. A Cr-Al-Si oxidation resistant coating for carbon/carbon composites by slurry dipping.Carbon,2007, 45(5):1124-1126
[17]Huang M, Li K Z, Li H J, et al. Double-layer oxidation protective SiC/Cr-Al-Si coating for carbon-carbon composites.Surf. Coat. Tech,2007, 201(18):7842-7846
[18]Zhang Y L, Li H J, Fu Q G, et al. A Si-Mo oxidation protective coating for C/SiC coated carbon/carbon composites.Carbon,2008, 45(5):1130-1133
[19]张雨雷，李贺军，姚西媛，等(ZHANG Yu-Lei, et al). C/SiC/Si-Mo-Cr复合涂层碳/碳复合材料力学性能研究. 无机材料学报(Journal of Inorganic Materials), 2008, 23(4): 725-728.
[20]Fang H T, Zhu J C, Yin Z D, et al. A Si-Mo fused slurry coating for oxidation protection of carboncarbon composites.J. Mater. Sci. Lett,2001, 20(2):175-177
[21]Terentieva V S, Bogachkova O P, Goriatcheva E V. Method for Protecting Products Made of a Refractory Material Against Oxidation, and Resulting Producted Products. US Patent: 5677060,1997.10.14.
[22]曾燮榕, 李贺军, 杨峥(ZENG Xie-Rong, et al). 炭/炭复合材料表面MoSi2Si复相陶瓷涂层及其抗氧化机制. 硅酸盐学报(Journal of the Chinese Society), 1999, 27(1): 8-15.
[23]Zhao J, Guo Q G, Shi J L, et al. SiC/Si-MoSi₂ oxidation protective coatings for carbon materials.Surf. Coat. Tech,2006, 201(3/4):1861-1865
[24]冉丽萍, 易茂中, 蒋建献. 炭/炭复合材料MoSi₂/SiC 高温抗氧化复合涂层的制备及其结构.新型炭材料,2006, 21(3):231-236
[25]Huang J F, Zeng X R, Li H J, et al. MulliteAl₂O₃-SiC oxidation protective coating for carbon/carbon composites.Carbon,2003, 41(14):2825-2829
[26]Fu Q G, Li H J, Shi X H, et al. Microstructure and anti-oxidation property of CrSi₂-SiC coating for carbon/carbon composites.Appl. Surf. Sci,2006, 252(10):3475-3480
[27]Li H J, Xue H, Wang Y J, et al. A MoSi₂-SiC-Si oxidation protective coating for carbon/carbon composites.Surf. Coat. Tech,2007, 201(24):9444-9447
[28]Li K Z, Hou D S, Li H J, et al. SiWMo coating for SiC coated carbon/carbon composites against oxidation.Surf. Coat. Tech,2007, 201(24):9598-9602
[29]侯党社, 李克智, 李贺军, 等(HOU Dang-She, et al). C/C复合材料高温长寿命抗氧化复合涂层研究. 无机材料学报(Journal of Inorganic Materials), 2008, 23(2): 213-218.
[30]Li H J, Fu Q G, Shi X H, et al. SiC whisker-toughened SiC oxidation protective coating for carbon/carbon composites.Carbon,2006, 44(3):602-605
[31]Fu Q G, Li H J, Li K Z, et al. SiC whiskertoughened MoSi₂-SiC-Si coating to protect carbon/carbon composites against oxidation.Carbon,2006, 44(9):1866-1869
[32]Fu Q G, Li H J, Shi X H, et al. A SiC whiskertoughened SiC-CrSi₂ oxidation protective coating for carbon/carbon composites.Appl. Surf. Sci,2007, 253(8):3757-3760