Ti3C2Tx MXene基电磁波吸收材料: 制备调控、多元体系与关键挑战

doi:10.15541/jim20260365

无机材料学报

• 综述 •

Ti₃C₂T_x MXene基电磁波吸收材料: 制备调控、多元体系与关键挑战

姜雪雯¹, 胡飞越², 李梦茹², 李威¹, 张锐¹, 王海龙¹, 邵刚¹, 郑英姿¹, 张帆², 范冰冰¹

1.郑州大学材料科学与工程学院, 郑州 450001;
2.河南省科学院先进陶瓷研究所, 郑州 450046

收稿日期:2026-08-27 修回日期:2026-10-14
通讯作者: 范冰冰, 教授. E-mail: fanbingbing@zzu.edu.cn; 胡飞越, 助理研究员. E-mail: hufeiyue0527@163.com
作者简介:姜雪雯(1999-), 女, 博士研究生. E-mail: jiangxuewen07@163.com
基金资助:
国家自然科学基金(52572086, 52502077); 中原千人计划-中原科技创新领军人才项目(264200510043); 河南省重点研发计划(251111232100); 2025年皇家学会沃尔夫森访问研究员奖学金第一轮(RSWVF/25/R1/1008)

Ti₃C₂T_x MXene-based Electromagnetic Wave Absorbers: Synthesis Control, Multicomponent Design, and Critical Challenges

JIANG Xuewen¹, HU Feiyue², LI Mengru², LI Wei¹, ZHANG Rui¹, WANG Hailong¹, SHAO Gang¹, ZHENG Yingzi¹, ZHANG Fan², FAN Bingbing¹

1. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China;
2. Institute of Advanced Ceramics, Henan Academy of Sciences, Zhengzhou 450046, China

Received:2026-08-27 Revised:2026-10-14
Contact: FAN Bingbing, professor. E-mail: fanbingbing@zzu.edu.cn; HU Feiyue, assistant professor. E-mail: hufeiyue0527@163.com
About author:JIANG Xuewen (1999-), female, PhD candidate. E-mail: jiangxuewen07@163.com
Supported by:
National Natural Science Foundation of China (52572086, 52502077); Zhongyuan Thousand Talents Program-Leading Talents in Science and Technology Innovation (264200510043); Key Research and Development Project of Henan Province (251111232100); Royal Society Wolfson Visiting Fellowships 2025 Round 1 (RSWVF/25/R1/1008)

摘要/Abstract

摘要： 随着无线通信与电子设备的快速发展, 电磁污染问题日益严重, 开发兼具“薄、轻、宽、强”特性的电磁波吸收材料具有重要意义。Ti₃C₂T_x MXene具有较高的电导率、丰富的表面官能团、可调的层间结构以及较大的比表面积, 可通过导电损耗、偶极极化、缺陷极化、界面极化以及多重反射与散射等途径衰减电磁波, 已成为电磁波吸收领域的重要候选材料。然而, 过高的电导率容易引起阻抗失配, 其吸波性能还受到制备工艺、表面化学、片层结构、复合组分和微观形貌的共同影响。本文以Ti₃C₂T_x MXene及其复合材料为主要对象, 分析不同刻蚀/剥离条件与复合组分对材料结构、电磁参数及吸波性能的影响。首先介绍了Ti₃C₂T_x MXene的组成及其基本性质, 重点分析Ti₃C₂T_x MXene的导电性、力学性能和氧化稳定性。随后总结不同刻蚀与剥离方法对Ti₃C₂T_x MXene片层结构和缺陷的影响, 并建立制备参数与吸波性能之间的联系。在此基础上, 系统梳理纯Ti₃C₂T_x MXene及其介电、磁介电复合吸波材料的研究进展, 重点讨论碳材料、聚合物和陶瓷对导电网络与界面极化的调节作用, 以及磁性金属、合金和铁氧体在引入磁损耗、改善磁介电协同和优化阻抗匹配方面的作用。最后, 对Ti₃C₂T_x MXene吸波材料的关键挑战和未来发展方向进行了展望。

关键词: Ti₃C₂T_x MXene, 电磁波吸收, 结构调控, 介电损耗, 磁损耗, 综述

Abstract: With the rapid development of wireless communications and electronic devices, electromagnetic pollution has become an increasingly serious concern, creating a strong demand for electromagnetic wave absorbers that are thin, lightweight, broadband, and highly efficient. Ti₃C₂T_x MXene has emerged as a promising candidate owing to its high electrical conductivity, abundant surface terminations, tunable interlayer structure, and large specific surface area. These characteristics enable electromagnetic wave attenuation through conduction loss, dipolar polarization, defect polarization, interfacial polarization, and multiple reflection and scattering. However, its excessively high conductivity may cause impedance mismatch, while its absorption performance is jointly governed by the preparation process, surface chemistry, sheet structure, composite constituents, and microstructural configuration. Accordingly, this review focuses on Ti₃C₂T_x MXene and its composites and examines the effects of different etching and delamination conditions and composite constituents on their structures, electromagnetic parameters, and absorption performance. The composition and fundamental properties of Ti₃C₂T_x MXene are first introduced, with particular emphasis on its electrical conductivity, mechanical properties, and oxidation stability. Various etching and delamination methods are then summarized, and their effects on the sheet structure and defect characteristics of Ti₃C₂T_x MXene are discussed to clarify the relationship between preparation parameters and electromagnetic wave absorption. Recent advances in pristine Ti₃C₂T_x MXene and its dielectric and magnetic-dielectric composites are subsequently reviewed. Particular attention is paid to how carbon materials, polymers, and ceramics regulate conductive networks and interfacial polarization, as well as how magnetic metals, alloys, and ferrites introduce magnetic loss, promote dielectric-magnetic synergy, and improve impedance matching. Finally, the key challenges and future development directions of Ti₃C₂T_x MXene-based electromagnetic wave absorbers are discussed.

Key words: Ti₃C₂T_x MXene, electromagnetic wave absorption, structural regulation, dielectric loss, magnetic loss, review

中图分类号:

TB34

姜雪雯, 胡飞越, 李梦茹, 李威, 张锐, 王海龙, 邵刚, 郑英姿, 张帆, 范冰冰. Ti₃C₂T_x MXene基电磁波吸收材料: 制备调控、多元体系与关键挑战[J]. 无机材料学报, DOI: 10.15541/jim20260365.

JIANG Xuewen, HU Feiyue, LI Mengru, LI Wei, ZHANG Rui, WANG Hailong, SHAO Gang, ZHENG Yingzi, ZHANG Fan, FAN Bingbing. Ti₃C₂T_x MXene-based Electromagnetic Wave Absorbers: Synthesis Control, Multicomponent Design, and Critical Challenges[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20260365.

参考文献

[1] HAN M K, YIN X W, HANTANASIRISAKUL K, et al.Anisotropic MXene aerogels with a mechanically tunable ratio of electromagnetic wave reflection to absorption. Advanced Optical Materials, 2019, 7(10): 1900267.
[2] ZHAN B B, ZHANG Y R, TAN Z Y, et al.Multi-dimensional, multi-interfacial, and multi-path synergy enables broadband absorption, corrosion resistance, Joule heating, and thermal performances in hierarchical carbon/Ni nanoparticles-carbon nanocoils foams. InfoMat, 2026, 8(2): e70098.
[3] HUANG G A, ZU D F, JIANG X W, et al.Phase evolution and broadband electromagnetic wave absorption mechanisms of electrospun polymer-derived SiC-based fibrous ceramic membranes. Journal of Advanced Ceramics, 2026, 15(8): 9221349.
[4] ZHANG Y J, PAN L, ZHANG P G, et al.Gradient multilayer design of Ti₃C₂T_x MXene nanocomposite for strong and broadband microwave absorption. Small Science, 2022, 2(7): 2200018.
[5] JIANG X W, WANG Q, SONG L M, et al.Enhancing electromagnetic wave absorption with core-shell structured SiO₂@MXene@MoS₂ nanospheres. Carbon Energy, 2024, 6(8): e502.
[6] NEZAFAT Z, JAFARI G, JAVANSHIR S, et al.MXene-based metal oxide/metal composites for microwave absorption and shielding: recent advances and future perspectives. Advanced Composites and Hybrid Materials, 2025, 8(6): 447.
[7] GUAN X M, YANG Z H, ZHOU M, et al.2D MXene nanomaterials: synthesis, mechanism, and multifunctional applications in microwave absorption. Small Structures, 2022, 3(10): 2200102.
[8] ZHOU P P, YUAN S L, CAO W Y, et al.MXene-based materials: compositional engineering for high-performance microwave absorption. Rare Metals, 2026, 45(3): e70262.
[9] MA X C, ZHI Q, LI W, et al.High-temperature oxidation mechanism and electromagnetic wave absorption properties of Fe2AlB2. Journal of Inorganic Materials, 2026, 41(1): 45.
[10] LI B Y, CHANG L, ZHANG X C, et al.Progress and perspectives on Ti₃C₂T_x MXene-based composite materials for electromagnetic wave absorption. Journal of Materials Chemistry C, 2026, 14(19): 7990.
[11] TANG S W, CHENG S N, YU C, et al.Impedance-matchable 3D MXene sponge/NiFe@NC heterostructure with tunable pores for efficient electromagnetic wave absorption and thermal resistance. Science China Materials, 2026, 69(3): 1706.
[12] 范冰冰, 邱洪辰, 李梦茹, 等. 高熵陶瓷吸波材料研究进展. 硅酸盐学报, 2023, 51(12): 3204.
[13] CAO Y R, ZHAO Y, ZHOU C, et al.Balancing MoS₂ growth and MXene in situ oxidation to construct dual Schottky contacts for enhanced dielectric loss and broadband electromagnetic wave absorption. Advanced Functional Materials, 2026, 36(34): e28608.
[14] MA Y Z, WEI S N, LIU R X, et al.A review on MXene-based microwave absorption composites: engineering, component optimization and structure regulation. Journal of Materials Chemistry C, 2024, 12(25): 9068.
[15] YANG P A, DENG W J, LUO J F, et al.Preparation and structure optimization of 2D MXene nanocomposites for microwave absorbing application. Materials Today Physics, 2024, 40: 101291.
[16] WANG X W, ZHAO C, LI C P, et al.Progress in MXene-based materials for microwave absorption. Journal of Materials Science & Technology, 2024, 180: 207.
[17] ANAYEE M, SHUCK C E, SHEKHIREV M, et al.Kinetics of Ti₃AlC₂ etching for Ti₃C₂T_x MXene synthesis. Chemistry of Materials, 2022, 34(21): 9589.
[18] ASLAM M K, NIU Y B, XU M W.MXenes for non-lithium-ion (Na, K, Ca, Mg, and Al) batteries and supercapacitors. Advanced Energy Materials, 2021, 11(2): 2000681.
[19] FEI L, LEI L, WANG D G.Progress of two-dimensional MXene in new-type thin-film solar cells. Journal of Inorganic Materials, 2024, 39(2): 215.
[20] LIU H, LIU Y J.Recent research progress of MXene and its composites in the field of electromagnetic wave absorption. Materials Today Physics, 2026, 60: 101963.
[21] DOWNES M, SHUCK C E, MCBRIDE B, et al.Comprehensive synthesis of Ti₃C₂T_x from MAX phase to MXene. Nature Protocols, 2024, 19(6): 1807.
[22] XU S T, ZHANG X, ZHENG T, et al.Advancements in high-performance MXene composite fibers integrated with various functional materials: fabrication, functionalization, property enhancement, and applications. Journal of Materials Science & Technology, 2026, 252: 57.
[23] SHEIN I R, IVANOVSKII A L.Graphene-like titanium carbides and nitrides Tin+1Cn, Tin+1Nn (n=1, 2, and 3) from de-intercalated MAX phases: first-principles probing of their structural, electronic properties and relative stability. Computational Materials Science, 2012, 65: 104.
[24] KHAZAEI M, ARAI M, SASAKI T, et al.Novel electronic and magnetic properties of two-dimensional transition metal carbides and nitrides. Advanced Functional Materials, 2013, 23(17): 2185.
[25] NAGUIB M, BARSOUM M W, GOGOTSI Y.Ten years of progress in the synthesis and development of MXenes. Advanced Materials, 2021, 33(39): 2103393.
[26] LIPATOV A, ALHABEB M, LU H D, et al.Electrical and elastic properties of individual single-layer Nb4C3Tx MXene flakes. Advanced Electronic Materials, 2020, 6(4): 1901382.
[27] LIPATOV A, LU H D, ALHABEB M, et al. Elastic properties of 2D Ti₃C₂T_x MXene monolayers and bilayers. Science Advances, 2018, 4(6): eaat0491.
[28] RONG C, SU T, YU T H, et al.Shear properties and stable wrinkle resistance in 2D Ti₃C₂T_x MXene monolayers. Nature Communications, 2026, 17: 2411.
[29] THANASARNSURAPONG T, JANA S K, DETRATTANAWICHAI P, et al.Accelerating lattice thermal conductivity calculations in MXenes: a machine learning force field approach. ACS Materials Au, 2025, 5(5): 823.
[30] RAN X, LIU C J, CHEN B.Surface tension-mediated assembly of MXene films for high-performance electromagnetic interference shielding and thermal management applications. Carbon, 2026, 247: 121028.
[31] CHEN L, SHI X G, YU N J, et al.Measurement and analysis of thermal conductivity of Ti₃C₂T_x MXene films. Materials, 2018, 11(9): 1701.
[32] WU H, GU J X, LI Z C, et al.Characterization of phonon thermal transport of Ti₃C₂T_x MXene thin film. Journal of Physics: Condensed Matter, 2022, 34(15): 155704.
[33] WAN Z, LI C, LIU R H, et al.Probing thermal transport on a suspended Ti₃C₂T_x MXene film via a photothermally actuated resonator. ACS Applied Materials & Interfaces, 2024, 16(4): 4999.
[34] SHI X X, YU Z, LIU Z, et al.Scalable, high-yield monolayer MXene preparation from multilayer MXene for many applications. Angewandte Chemie International Edition, 2025, 64(6): e202418420.
[35] 朱莉莉, 康帅, 胡祖明, 等. MXene及其复合吸波材料组成与结构的研究进展. 复合材料学报, 2023, 40(6): 3167.
[36] ZHANG C J, MA Y L, ZHANG X T, et al.Two-dimensional transition metal carbides and nitrides (MXenes): synthesis, properties, and electrochemical energy storage applications. Energy & Environmental Materials, 2020, 3(1): 29.
[37] ZHANG C J, PINILLA S, MCEVOY N, et al.Oxidation stability of colloidal two-dimensional titanium carbides (MXenes). Chemistry of Materials, 2017, 29(11): 4848.
[38] NAGUIB M, KURTOGLU M, PRESSER V, et al.Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced Materials, 2011, 23(37): 4248.
[39] LIU Z L, ZHAO X, XUE F H, et al.Shear-rheological-assisted MXene dispersion in epoxy resin for efficient electromagnetic absorption. Advanced Functional Materials, 2024, 34(49): 2409069.
[40] ALHABEB M, MALESKI K, ANASORI B, et al.Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti₃C₂T_x MXene). Chemistry of Materials, 2017, 29(18): 7633.
[41] MASHTALIR O, NAGUIB M, DYATKIN B, et al.Kinetics of aluminum extraction from Ti3AlC2 in hydrofluoric acid. Materials Chemistry and Physics, 2013, 139(1): 147.
[42] JIN S, GUO Y T, WANG F L, et al.The synthesis of MXenes. MRS Bulletin, 2023, 48(3): 245.
[43] YANG J, NAGUIB M, GHIDIU M, et al.Two-dimensional Nb-based M4C3 solid solutions (MXenes). Journal of the American Ceramic Society, 2016, 99(2): 660.
[44] GHIDIU M, LUKATSKAYA M R, ZHAO M Q, et al.Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature, 2014, 516(7529): 78.
[45] ANAYEE M, KURRA N, ALHABEB M, et al.Role of acid mixtures etching on the surface chemistry and sodium ion storage in Ti₃C₂T_x MXene. Chemical Communications, 2020, 56(45): 6090.
[46] LIPATOV A, ALHABEB M, LUKATSKAYA M R, et al.Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Advanced Electronic Materials, 2016, 2(12): 1600255.
[47] HALIM J, LUKATSKAYA M R, COOK K M, et al.Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chemistry of Materials, 2014, 26(7): 2374.
[48] SOUNDIRARAJU B, GEORGE B K.Two-dimensional titanium nitride (Ti2N) MXene: synthesis, characterization, and potential application as surface-enhanced Raman scattering substrate. ACS Nano, 2017, 11(9): 8892.
[49] LI M, LU J, LUO K, et al.Element replacement approach by reaction with lewis acidic molten salts to synthesize nanolaminated MAX phases and MXenes. Journal of the American Chemical Society, 2019, 141(11): 4730.
[50] DING H M, LI Y B, LI M, et al.Chemical scissor-mediated structural editing of layered transition metal carbides. Science, 2023, 379(6637): 1130.
[51] NAGUIB M, MASHTALIR O, CARLE J, et al.Two-dimensional transition metal carbides. ACS Nano, 2012, 6(2): 1322.
[52] MASHTALIR O, NAGUIB M, MOCHALIN V N, et al.Intercalation and delamination of layered carbides and carbonitrides. Nature Communications, 2013, 4: 1716.
[53] MUNIR S, RASHEED A, RASHEED T, et al.Exploring the influence of critical parameters for the effective synthesis of high-quality 2D MXene. ACS Omega, 2020, 5(41): 26845.
[54] 尹镇航, 郭建华, 蒋兴华. 基于二维MXene的吸波材料研究进展. 化工新型材料, 2021, 49(9): 5.
[55] WEI Y, ZHANG P, SOOMRO R A, et al.Advances in the synthesis of 2D MXenes. Advanced Materials, 2021, 33(39): 2103148.
[56] YU M, HUANG Y, LIU X D, et al.Synthetic strategy of biomimetic sea urchin-like Co-NC@PANI modified MXene-based magnetic aerogels with enhanced electromagnetic wave absorption properties. Nano Research, 2024, 17(3): 2025.
[57] LU B K, JIN G K, CUI Y H, et al.Carbon dots intercalated MXene for flexible organic hydrogel absorbers with synergistically enhanced dielectric loss. Nano-Micro Letters, 2026, 18(1): 302.
[58] LIU S S, LIAN Y Y, ZHAO Y Z, et al.Recent advances of MXene-based nanocomposites towards microwave absorption: a review. Advanced Composites and Hybrid Materials, 2025, 8(1): 144.
[59] LI Y, DONG C L, WANG S J, et al.Micro-macro regulating heterogeneous interface engineering in 3D N-doped carbon fiber/MXene/TiO₂ nano-aerogel for boosting electromagnetic wave absorption. Nano Research, 2025, 18(2): 94907169.
[60] HE H, WANG L Y, QIAN Y X, et al.Multifunctional 3D MXene@MDCF nanoarchitectures via hierarchical networks self-assembled strategy achieving superior electromagnetic wave absorption and flame retardancy with enhanced thermal management. Small, 2026, 22(30): e11298.
[61] QING Y C, ZHOU W C, LUO F, et al.Titanium carbide (MXene) nanosheets as promising microwave absorbers. Ceramics International, 2016, 42(14): 16412.
[62] TONG Y, HE M, ZHOU Y M, et al.Electromagnetic wave absorption properties in the centimetre-band of Ti₃C₂T_x MXenes with diverse etching time. Journal of Materials Science: Materials in Electronics, 2018, 29(10): 8078.
[63] ZHU L L, WU W W, CHEN J J, et al.High-performance electromagnetic wave absorption by two-dimensional mesoporous monolayer Ti₃C₂T_x MXene. Chemical Engineering Journal, 2024, 488: 150649.
[64] DU Q R, MEN Q Q, LI R S, et al.Electrostatic adsorption enables layer stacking thickness-dependent hollow Ti₃C₂T_x MXene bowls for superior electromagnetic wave absorption. Small, 2022, 18(47): 2203609.
[65] ZENG X J, ZHAO C, JIANG X, et al.Functional tailoring of multi-dimensional pure MXene nanostructures for significantly accelerated electromagnetic wave absorption. Small, 2023, 19(41): 2303393.
[66] WANG W Z, CHENG H R, WANG J F, et al.Recent progress and prospect of MXene-based microwave absorbing materials. Materials Research Bulletin, 2024, 179: 112954.
[67] GAO C G, SUN X L, CHEN J, et al.SiBCN-rGO ceramic fibers based on wet spinning technology: microstructure, mechanical and microwave-absorbing properties. Journal of Inorganic Materials, 2025, 40(3): 290.
[68] LI Q, ZHANG Z, QI L P, et al.Toward the application of high frequency electromagnetic wave absorption by carbon nanostructures. Advanced Science, 2019, 6(8): 1801057.
[69] WANG H M, ZHAN B B, ZHANG Y R, et al.Multi-scale synergistic regulation strategy to develop mesoporous carbon hollow nanospheres/bean-shaped nanofibers for corrosion-resistant, flexible, and lightweight microwave absorbers. Research, 2026, 9: 1051.
[70] SUN C H, LI Q Y, JIA Z R, et al.Hierarchically flower-like structure assembled with porous nanosheet-supported MXene for ultrathin electromagnetic wave absorption. Chemical Engineering Journal, 2023, 454: 140277.
[71] JIANG T, ZHAO T K, JALIL A, et al.Pillared amorphous carbon nanotube/MXene nanohybrid for ultrathin broadband electromagnetic wave absorption. Chemical Engineering Journal, 2026, 528: 172520.
[72] MU Z C, WANG L Z, FAN B H, et al.In situ growth of carbon nanotubes on MXenes for high-performance electromagnetic wave absorption. RSC Advances, 2025, 15(32): 26506.
[73] GUO C, SHAO S P, ZHANG X, et al.Multifunctional MXene/rGO aerogels loaded with Co/MnO nanocomposites for enhanced electromagnetic wave absorption, thermal insulation and pressure sensing. Nano Research, 2024, 17(9): 7803.
[74] WEI J Y, LIANG Q Q, KAN X C, et al.Constructing porous magnetic Ni@C-anchored carbon foams for excellent magnetic-dielectric synergy to develop integrated microwave absorbers with efficient thermal insulation and antibacterial properties. Science China Materials, 2026, 69(8): 4994.
[75] ZHAO H Q, ZHANG C L, LI Y H, et al.Ordered cellular 2D/2D biomass-derived carbon nanosheet/MXene aerogels for ultralight and high-performance microwave absorption. Journal of Advanced Ceramics, 2025, 14(12): 9221214.
[76] WU F S, HU P Y, HU F Y, et al.Multifunctional MXene/C aerogels for enhanced microwave absorption and thermal insulation. Nano-Micro Letters, 2023, 15(1): 194.
[77] CHENG S J, JIA R F, YIN B L, et al.Controllable fabrication of MnCo₂O₄@polypyrrole@MXene ternary composites for electromagnetic wave absorption. Journal of Applied Polymer Science, 2025, 142(15): e56724.
[78] TONG Y, HE M, ZHOU Y M, et al.Hybridizing polypyrrole chains with laminated and two-dimensional Ti3C2Tx toward high-performance electromagnetic wave absorption. Applied Surface Science, 2018, 434: 283.
[79] DING X, LI T X.Fabrication of hollow polypyrrole nanocubes/Ti₃C₂T_x MXene composites for high-performance electromagnetic wave absorption performances. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2025, 712: 136463.
[80] ABDUL W, ZHAO X Y, LIU W B, et al.Lightweight MXene/polyimide aerogel composites for high-performance of electromagnetic wave absorption. Materials Today Communications, 2025, 46: 112942.
[81] YANG F, YAO J R, JIN L Q, et al.Multifunctional Ti₃C₂T_x MXene/aramid nanofiber/polyimide aerogels with efficient thermal insulation and tunable electromagnetic wave absorption performance under thermal environment. Composites Part B: Engineering, 2022, 243: 110161.
[82] LUO M, CHEN Z H, LI H T, et al.Electrostatic self-assembly induced nest-like MXene networks on fabric for ultra-broadband flexible absorption. Advanced Science, 2026, 13(40): e75438.
[83] LI Y L, LIU J C, LI D S, et al.PDMS-encapsulated liquid metal-MXene aerogels for resilient electromagnetic wave absorption in harsh environments. Rare Metals, 2025, 44(5): 3299.
[84] YAN M Y, PAN Y L, HE P, et al.Flexible hierarchical hollow SiC/SiO_x micro/nanofiber sponges for broadband electromagnetic wave absorption. Advanced Fiber Materials, 2025, 7(3): 853.
[85] HU Y F, LI Z X, JIANG H H, et al.Sandwich-structured SiC nanowire/delaminated few-layer Ti3C2Tx Mxene laminates enabling confined conduction pathways for impedance-matched broadband microwave absorption. Journal of Alloys and Compounds, 2026, 1065: 187654.
[86] LI H H, YUAN X Y, ZHAO P H, et al.A synergistic strategy for SiC/C nanofibers@MXene with core-sheath microstructure toward efficient electromagnetic wave absorption and photothermal conversion. Applied Surface Science, 2023, 613: 155998.
[87] TIAN Z Z, JIA T M, KAN X C, et al.Polarization loss enhancement induced by interfacial contact regulation strategy to develop nickel silicate/reduced graphene oxide for microwave absorption and corrosion resistance. Rare Metals, 2026, 45(5): e70327.
[88] NIU H H, TU X Y, ZHANG S, et al.Engineered core-shell SiO₂@Ti₃C₂T_x composites: towards ultra-thin electromagnetic wave absorption materials. Chemical Engineering Journal, 2022, 446: 137260.
[89] HE Y F, LIU D D, DOU S H, et al.Interface-engineered decoupled conductivity and relaxation: synergistic modulation of Debye-parameters in N-doped SiO₂/MXene broadband wave-absorbing materials. Journal of Advanced Ceramics, 2025, 14(12): 9221150.
[90] WANG Y Q, ZHAO H B, CHENG J B, et al.Hierarchical Ti₃C₂T_x@ZnO hollow spheres with excellent microwave absorption inspired by the visual phenomenon of eyeless urchins. Nano-Micro Letters, 2022, 14(1): 76.
[91] ZHANG Y, LAN D, HOU T Q, et al.Multifunctional electromagnetic wave absorbing carbon fiber/Ti3C2Tx MXene fabric with ultra-wide absorption band. Carbon, 2024, 230: 119594.
[92] ZHANG X M, TONG L Y, GAO H J, et al.3D network-structured fly ash microbeads@carbon nanotubes composites for electromagnetic wave absorption[J]. Journal of Inorganic Materials, 2026, 41(2): 208.
[93] QIAO J, SONG Q H, XUAN L X, et al.Dual cross-linked magnetic MXene aerogel with high strength and durability enables multifunctionality. Advanced Functional Materials, 2024, 34(33): 2401687.
[94] CHENG H R, PAN Y M, WANG X, et al.Ni flower/MXene-melamine foam derived 3D magnetic/conductive networks for ultra-efficient microwave absorption and infrared stealth. Nano-Micro Letters, 2022, 14(1): 63.
[95] SONG J Y, XU W T, LI J L, et al.Synthesis of Ti₃C₂T_x MXene/Ni nanoparticles composite with tunable particle size for high-performance microwave absorption. Ceramics International, 2026, 52(3): 3837.
[96] WEN C Y, LI X, ZHANG R X, et al.High-density anisotropy magnetism enhanced microwave absorption performance in Ti3C2Tx MXene@Ni microspheres. ACS Nano, 2022, 16(1): 1150.
[97] ZHANG Y, LIU X H, GUO Z Q, et al.MXene@Co hollow spheres structure boosts interfacial polarization for broadband electromagnetic wave absorption. Journal of Materials Science & Technology, 2024, 176: 167.
[98] LI K X, SHI F Y, WU Y X, et al.Heterogeneous Fe/Ti₃C₂T_x MXene derived magnetic-dielectric synergy for efficient microwave attenuation at ultrathin thickness. Materials Today Physics, 2026, 61: 102034.
[99] ZHANG S, ZHANG F, XIE Y Y, et al.Ultrathin CoNi@Ti₃C₂T_x composites with sandwich structures for efficient microwave absorption. Ceramics International, 2022, 48(22): 33751.
[100] NIU H H, JIANG X W, XIA Y D, et al.Construction of hydrangea-like core-shell SiO₂@Ti₃C₂T_x @CoNi microspheres for tunable electromagnetic wave absorbers. Journal of Advanced Ceramics, 2023, 12(4): 711.
[101] WU Z C, CHENG H W, JIN C, et al.Dimensional design and core-shell engineering of nanomaterials for electromagnetic wave absorption. Advanced Materials, 2022, 34(11): 2107538.
[102] WANG Y, ZHANG H Y, WU Q B, et al.Magnetic enhanced high-efficiency electromagnetic wave absorbing MXene/Fe3O4 composite absorbers at 2-40 GHz. Journal of Materials Chemistry C, 2023, 11(12): 4171.
[103] GUO J, SUN Y K, CHEN Z R, et al.Electrostatic self-assembled ceramic magnetic Ti₃C₂T_x nanocomposites reinforced with hollow Fe3O4 particles for strong and broadband absorption of electromagnetic waves. Ceramics International, 2025, 51(19): 29283.
[104] HE J Z, LI J J, ZHANG J L, et al.Metal ions-assisted construction of SiO₂/MXene/Fe₃O₄ aerogel as multifunctional electromagnetic wave absorbing material. Carbon, 2023, 214: 118266.
[105] YADAV R S, ANJU, KUŘITKA I. Spinel ferrite and MXene-based magnetic novel nanocomposites: an innovative high-performance electromagnetic interference shielding and microwave absorber. Critical Reviews in Solid State and Materials Sciences, 2023, 48(4): 441.
[106] GUO Y, WANG D D, BAI T T, et al.Electrostatic self-assembled NiFe₂O₄/ Ti₃C₂T_x MXene nanocomposites for efficient electromagnetic wave absorption at ultralow loading level. Advanced Composites and Hybrid Materials, 2021, 4(3): 602.
[107] GUO Z Z, LUO P E, ZONG Z, et al.Construction of Co Fe₂O₄/MXene hybrids with plentiful heterointerfaces for high-performance electromagnetic wave absorption through dielectric-magnetic cooperation strategy. Materials Today Physics, 2023, 38: 101277.
[108] YANG Y N, XU S L, HUANG Q L, et al.Two-dimensional multilayer Mn Fe₂O₄/MXene composites with excellent electromagnetic wave absorption effect. Materials Research Bulletin, 2024, 178: 112907.
[109] WANG K, LIU Z Y, HUANG S W, et al.Ti₃C₂T_x/Ni_0.2Mn_0.4Zn_0.4Fe₂O₄ ferrite nanocomposites: dual-loss mechanism with engineered composition for microwave absorption. Journal of Alloys and Compounds, 2024, 1008: 176721.

Ti₃C₂T_x MXene基电磁波吸收材料: 制备调控、多元体系与关键挑战

Ti₃C₂T_x MXene-based Electromagnetic Wave Absorbers: Synthesis Control, Multicomponent Design, and Critical Challenges

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	曹丙强, 李兴牧, 魏浩铭, 单衍苏. 脉冲激光沉积制备卤化物钙钛矿薄膜研究进展[J]. 无机材料学报, 2026, 41(9): 1178-1192.
[2]	黄淦, 薛佳祥, 檀财旺, 刘洋, 张国梁, 杨正茂, 陈招科. 核用SiC复合包壳多尺度力学损伤研究方法评述[J]. 无机材料学报, 2026, 41(9): 1157-1177.
[3]	钟鸿, 张宇豪, 单青松, 胡天鋆, 曾海波. 叠层量子点发光二极管的研究进展[J]. 无机材料学报, 2026, 41(8): 1036-1048.
[4]	马稚童, 李众少, 曹逊. 动态辐射热管理技术: 从原理、材料到协同优化设计[J]. 无机材料学报, 2026, 41(8): 1021-1035.
[5]	司会晨, 梁飞, 于浩海, 张怀金. 黄橙激光晶体材料与全固态激光器件研究进展[J]. 无机材料学报, 2026, 41(8): 1049-1068.
[6]	覃善丽, 郭佳文, 陈燕萌, 聚安安, 韦毅, 黄科林, 侯向华, 吕思师, 文志朋, 吴炼. 二维层状材料构筑电化学储能定向离子传输通道的研究进展[J]. 无机材料学报, 2026, 41(7): 883-898.
[7]	李阳, 陈佳宁, 卿玉长, 范冰冰. Ti₄O₇/CoNi/CNT异质结构的界面调控及吸波机制研究[J]. 无机材料学报, 2026, 41(7): 915-922.
[8]	余飞宇, 王文清, 张学勤, 何汝杰. 基于增材制造陶瓷点阵的双相网络互穿复合材料的研究进展与挑战[J]. 无机材料学报, 2026, 41(7): 849-866.
[9]	周翠, 李捷, 孙鲁超, 苏海军, 王京阳. 氧化铝基定向凝固共晶陶瓷的组织特性、调控方法及环境稳定性[J]. 无机材料学报, 2026, 41(7): 899-914.
[10]	费文龙, 王亚坤, 廖良生. 蓝光ZnSeTe量子点的可控制备及其量子点发光二极管器件研究进展[J]. 无机材料学报, 2026, 41(7): 867-882.
[11]	陈明俊, 缪洪康, 肖英俊, 邓建波, 张翔, 赵九蓬, 李垚. 光-热双响应材料研究进展: 从设计策略到智能窗应用[J]. 无机材料学报, 2026, 41(6): 723-738.
[12]	宋坤洁, 解荣军. 机器学习驱动新型发光材料的研究进展[J]. 无机材料学报, 2026, 41(6): 689-703.
[13]	胡钰晴, 朱一新, 乐先浩, 万青. 钽酸锂晶圆减薄技术及其热释电红外探测器应用进展[J]. 无机材料学报, 2026, 41(6): 764-774.
[14]	刘春帆, 陈科, 葛芳芳, 黄庆. 核用耐铅铋腐蚀涂层的研究进展[J]. 无机材料学报, 2026, 41(6): 775-786.
[15]	胡扬, 谢敏, 张筱怡, 李想, 郭新伟, 姜南, 周文瀚, 张胜利, 曾海波. 计算与数据驱动环保型发光材料的研究进展[J]. 无机材料学报, 2026, 41(6): 704-722.