氧化物共晶陶瓷的成分设计、强韧化机制与高温性能研究进展

doi:10.15541/jim20260342

无机材料学报

• 综述 •

氧化物共晶陶瓷的成分设计、强韧化机制与高温性能研究进展

刘思思¹, 张卓¹, 张静¹, 张宁¹, 苏海军^1,2

1.西北工业大学凝固技术全国重点实验室, 西安 710072;
2.西北工业大学深圳研究院, 深圳 518057

收稿日期:2026-08-12 修回日期:2026-10-21
通讯作者: 张卓, 副教授. E-mail: zhangzhuo@nwpu.edu.cn; 苏海军, 教授. E-mail: shjnpu@nwpu.edu.cn
作者简介:刘思思(2003–), 女, 硕士研究生. E-mail: 18182085642@163.com
基金资助:
国家重点研发计划(2024YFB3714501); 西北工业大学凝固技术全国重点实验室开放课题(2026-TS-15); 国家自然科学基金项目(52202070); 陕西省教育厅重点科学研究计划项目(24JS054); 西安市科学技术协会青年人才托举计划项目(0959202613017)

Research Progress on Oxide Eutectic Ceramics: Composition Design, Strengthening and Toughening Mechanisms, and High Temperature Performance

LIU Sisi¹, ZHANG Zhuo¹, ZHANG Jing¹, ZHANG Ning¹, SU Haijun^1,2

1. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China;
2. Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518057, China

Received:2026-08-12 Revised:2026-10-21
Contact: ZHANG Zhuo, associate professor. E-mail: zhangzhuo@nwpu.edu.cn; SU Haijun, professor. E-mail: shjnpu@nwpu.edu.cn
About author:LIU Sisi (2003–), female, Master candidate. E-mail: 18182085642@163.com
Supported by:
National Key R&D Program of China (2024YFB3714501); Fund of the State Key Laboratory of Solidification Processing in NPU (2026-TS-15); National Natural Science Foundation of China (52202070); Scientific Research Program Funded by Education Department of Shaanxi Provincial Government (24JS054); Young Talent Support Plan of Xi'an Association for Science and Technology(0959202613017)

摘要/Abstract

摘要： 氧化物共晶陶瓷由熔体经共晶反应直接凝固形成,具有三维互穿网络结构、无晶界/非晶相及原子级强结合界面等特征,兼具优异的高温强度保持率、抗蠕变和耐环境腐蚀性能,是航空航天、能源动力等领域极具潜力的超高温结构材料。然而,其本征脆性与室温断裂韧性偏低仍是制约其工程应用的关键瓶颈。本文从成分设计、强韧化机制及高温性能三个方面系统综述了该领域的研究进展。在成分设计方面,总结了Al₂O₃基、ZrO₂基和高熵氧化物共晶陶瓷的基体选择策略,分析了单元素(Cr、Co)、多元素(Ce/Cr、Ce/Pr/Cr)及稀土离子掺杂对微观结构与性能的调控作用,并讨论了掺杂相(Y₂O₃、TiO₂)对共晶组织稳定性的影响。在强韧化机制方面,从共晶组织调控增韧(共晶组织细化、共晶组织形貌调控、晶体取向)与其他强韧化方法(ZrO₂相变增韧、颗粒/晶须/纤维增韧、表面工程)两个层面,阐述了多尺度协同强韧化策略。在高温性能方面,综述了共晶陶瓷的抗蠕变性能、耐钙镁铝硅酸盐(CaO-MgO-Al₂O₃-SiO₂, CMAS)与水氧腐蚀性能、高温摩擦磨损行为及热稳定性,突出了三维互穿共晶网络结构在高温服役中的独特优势。最后,指出了当前研究的不足与未来发展方向(多尺度协同增韧、高熵共晶体系拓展、复杂环境下服役性能优化),以期为高性能氧化物共晶陶瓷的可控制备与应用提供参考。

关键词: 氧化物共晶陶瓷, 成分设计, 强韧化, 高温性能, 综述

Abstract: Oxide eutectic ceramics are directly solidified from the melt via eutectic reactions, featuring three-dimensional interpenetrating network structures, the absence of conventional grain boundaries and amorphous phases, and atomically strong interfaces. These characteristics endow them with excellent high-temperature strength retention, creep resistance, and environmental corrosion resistance, making them promising candidates for ultrahigh-temperature structural applications in aerospace and energy systems. However, their intrinsic brittleness and relatively low fracture toughness at room temperature remain major obstacles to engineering applications. This review systematically summarizes recent advances in oxide eutectic ceramics in three aspects: composition design, strengthening and toughening strategies, and high-temperature performance. In terms of composition design, the selection strategies of Al₂O₃-based, ZrO₂-based, and high-entropy oxide eutectic ceramics are summarized, with particular emphasis on the effects of single-element doping (Cr, Co), multi-element doping (Ce/Cr, Ce/Pr/Cr), and rare-earth ion doping on microstructure and property regulation. The effects of doped phases, such as Y₂O₃ and TiO₂, on the stability of eutectic microstructures are also discussed. Regarding strengthening and toughening, strategies based on eutectic microstructure regulation, including eutectic refinement, morphology control, and crystallographic orientation control, are reviewed together with other strengthening and toughening approaches, such as ZrO₂ phase-transformation toughening, particle/whisker/fiber reinforcement, and surface engineering, highlighting the potential of multiscale synergistic toughening. In terms of high-temperature properties, creep resistance, calcium-magnesium-aluminosilicate (CaO-MgO-Al₂O₃-SiO₂, CMAS) and water-oxygen corrosion resistance, high-temperature friction and wear behavior, and thermal stability of oxide eutectic ceramics are reviewed, with particular emphasis on the unique advantages of three-dimensional interpenetrating eutectic networks under high-temperature service conditions. Finally, the current challenges and future research directions are outlined, including multiscale synergistic toughening, the expansion of high-entropy eutectic systems, and the optimization of service performance under complex environmental conditions. This review aims to provide a reference for the controllable fabrication and application of high-performance oxide eutectic ceramics.

Key words: oxide eutectic ceramic, composition design, strengthening and toughening, high-temperature performance, review

中图分类号:

TQ174

刘思思, 张卓, 张静, 张宁, 苏海军. 氧化物共晶陶瓷的成分设计、强韧化机制与高温性能研究进展[J]. 无机材料学报, DOI: 10.15541/jim20260342.

LIU Sisi, ZHANG Zhuo, ZHANG Jing, ZHANG Ning, SU Haijun. Research Progress on Oxide Eutectic Ceramics: Composition Design, Strengthening and Toughening Mechanisms, and High Temperature Performance[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20260342.

参考文献

[1] LI X X, FU Q G, WEN Z H, et al. Research progress on ultra-high temperature ceramic structural materials for extreme environments. Journal of Inorganic Materials, 2025, 40(10): 1045.
[2] LIU H F, SU H J, SHEN Z L, et al. Research progress on ultrahigh temperature oxide eutectic ceramics by laser additive manufacturing. Journal of Inorganic Materials, 2022, 37(3): 255.
[3] JIANG H, SU H J, YU M H, et al. Research progress on microstructure evolution and mechanical properties of ultra-high temperature oxide eutectic ceramics solidified by high temperature gradient solidification. Journal of the Chinese Ceramic Society, 2026, 54(2): 414.
[4] WANG X, ZHANG N, ZHONG Y J, et al. Microstructure evolution and crystallography of directionally solidified Al₂O₃/Y₃Al₅O₁₂eutectic ceramics prepared by the modified Bridgman method. Journal of Materials Science & Technology, 2019, 35(9): 1982.
[5] MAZEROLLES L, PERRIERE L, LARTIGUE-KORINEK S, et al. Microstructures, crystallography of interfaces, and creep behavior of melt-growth composites. Journal of the European Ceramic Society, 2008, 28(12): 2301.
[6] WEI J W, CHEN Z Y, CAO X, et al. Evolutions of the microstructure and mechanical properties of Al₂O₃/YAG DSEC during high‐temperature heat treatment. Advanced Engineering Materials, 2026, 28(16): e71031.
[7] BENAMARA O, CHERIF M, DUFFAR T, et al. Microstructure and crystallography of Al₂O₃-Y₃Al₅O₁₂-ZrO₂ ternary eutectic oxide grown by the micropulling down technique. Journal of Crystal Growth, 2015, 429: 27.
[8] MOKHTARI F, CHEN P, NEHARI A, et al. Experimental and numerical study on Al₂O₃-YAG binary and Al₂O₃-YAG-ZrO₂ ternary eutectic ceramic rods at different µ-PD growth stages. Journal of Alloys and Compounds, 2026, 1065: 188169.
[9] 贾晓娇, 张军, 苏海军, 等. 激光悬浮区熔Al₂O₃基共晶自生复合材料微观组织与力学性能. 金属学报, 2012, 48(12): 1479.
[10] ZHAO D, SU H J, HAO S Q, et al. Insight into faceted-nonfaceted transition of directionally solidified eutectic ceramic composites by laser floating zone melting and infrared imaging. Composites Part B: Engineering, 2024, 277: 111372.
[11] 付雪松, 孙胃涛, 韩文波, 等. 基于高温熔凝法Al₂O₃/ZrO₂/YAG共晶陶瓷显微组织演变规律. 材料工程, 2017, 45(2): 46.
[12] 于学鑫, 李城昕, 孟超鑫, 等. 整体高温辅助激光定向能量沉积Al₂O₃/ZrO₂共晶陶瓷组织性能研究. 航空制造技术, 2025, 68(8): 57.
[13] 孙海滨, 刘俊成, 白佳海, 等. 氧化物共晶自生复合陶瓷的研究进展. 陶瓷学报, 2009, 30(2): 243.
[14] WANG S H, PEÑA J I, LUN Z Y, et al. Optimization of growth theory of the directionally solidified alumina based eutectic ceramics. Journal of Alloys and Compounds, 2024, 982: 173783.
[15] KAJAN J, DAMAZYAN G, TINKOVA V, et al. A feature of the horizontal directional solidification (HDS) method affects the microstructure of Al₂O₃/YAG eutectic ceramics. Crystals, 2024, 14(10): 858.
[16] GAO R, CHU Z F, WANG S H, et al. The evolution of Al₂O₃/GdAlO₃/ZrO₂ ternary eutectic ceramic microstructure and property with the growth rate. Journal of Materials Research, 2024, 39(5): 801.
[17] WANG S H, LIU J C, LAN D H, et al. Microstructural stability and high temperature strength of directionally solidified Al₂O₃/Er₃Al₅O₁₂/ZrO₂ eutectic ceramics. Ceramics International, 2024, 50(1): 306.
[18] OTSUKA A, WAKU Y, TANAKA R. Corrosion of a unidirectionally solidified Al₂O₃/YAG eutectic composite in a combustion environment. Journal of the European Ceramic Society, 2005, 25(8): 1269.
[19] SU H J, ZHANG J, CUI C J, et al. Rapid solidification behaviour of Al₂O₃/Y₃Al₅O₁₂ (YAG) binary eutectic ceramic in situ composites. Materials Science and Engineering: A, 2008, 479(1/2): 380.
[20] ZHANG J, SU H J, SONG K, et al. Microstructure, growth mechanism and mechanical property of Al₂O₃-based eutectic ceramic in situ composites. Journal of the European Ceramic Society, 2011, 31(7): 1191.
[21] OLIETE P B, MERINO R I, PEÑA J I, et al. Binary and ternary eutectic composites of the CaO-ZrO₂-MgO system for porous ceramic supports. Journal of the European Ceramic Society, 2026, 46(5): 118022.
[22] ZHONG Y J, LI Z, WANG X. Insight into tuning of ZrO₂ distribution and mechanical properties of directionally solidified Al₂O₃/(5Re_0.2)AG/ZrO₂ eutectic ceramic composites. Composites Part B: Engineering, 2023, 266: 111016.
[23] LI B, XIANG M Y, BAO H, et al. Fabrication of Al₂O₃/YAG eutectic ceramics utilizing a fast combustion reaction heating method. Chinese Science Bulletin, 2015, 60(3): 322.
[24] WU D J, LI C X, XU M Z, et al. Holistic high-temperature assistance for laser directed energy deposition of Al₂O₃/ZrO₂ eutectic ceramics: cracking behavior. Advances in Manufacturing, 2026, 14(2): 474.
[25] WANG Z G, MA Y H, OUYANG J H, et al. In situ fabrication and microstructural evolution of Al₂O₃-ZrO₂ nanoeutectic ceramics by a novel pulse discharge plasma assisted melting method. Journal of the European Ceramic Society, 2018, 38(11): 4155.
[26] WANG S H, CHU Z F, LIU J C. Microstructure and mechanical properties of directionally solidified Al₂O₃/GdAlO₃ eutectic ceramic prepared with horizontal high-frequency zone melting. Ceramics International, 2019, 45(8): 10279.
[27] YU M H, SU H J, SHEN Z L, et al. Microstructure evolution and mechanical property of melt-grown Al₂O₃/GdAlO₃ eutectic ceramic directly prepared by laser powder bed fusion. Journal of Alloys and Compounds, 2025, 1039: 183191.
[28] OLIETE P B, MESA M C, MERINO R I, et al. Processing, microstructure and optical properties of the directionally solidified Al₂O₃-EuAlO₃ eutectic rods. Journal of Crystal Growth, 2012, 360: 123.
[29] SUN L C, ZHOU C, DU T F, et al. Directionally solidified Al₂O₃/Er₃Al₅O₁₂ and Al₂O₃/Yb₃Al₅O₁₂ eutectic ceramics prepared by optical floating zone melting. Journal of Inorganic Materials, 2021, 36(6): 652.
[30] SHEN Z L, SU H J, YU M H, et al. Unveiling exotic multi-scale microstructure transformation and crack formation mechanisms in eutectic ceramic composite by laser powder bed fusion. Composites Part B: Engineering, 2025, 288: 111883.
[31] JIANG H, SU H J, YU M H, et al. LDED-induced pore defects in Al₂O₃/GdAlO₃/ZrO₂ eutectic ceramics: Influence of specimen geometry on pore evolution mechanism. Journal of Materials Science & Technology, 2026, 269: 295.
[32] ZHOU C, SUN L C, LI J, et al. Effect of seed crystal in directionally solidified high‐entropy (Y_0.2Gd_0.2Ho_0.2Er_0.2Yb_0.2)AG/Al₂O₃ eutectic ceramic. Journal of the American Ceramic Society, 2026, 109(1): e70371.
[33] XIONG Z W, ZHANG K, LIAO W H, et al. In-situ synthesis of high-entropy Al₂O₃/RE₃Al₅O₁₂/ZrO₂ ceramic by laser powder bed fusion with exceptional properties. Journal of Advanced Ceramics, 2024, 13(12): 2004.
[34] ORERA V M, MERINO R I, PARDO J A, et al. Microstructure and physical properties of some oxide eutectic composites processed by directional solidification. Acta Materialia, 2000, 48(18/19): 4683.
[35] ORERA A, OLIETE P B, MERINO R I, et al. Eutectic ceramics of the CeO₂-ZrO₂-MgO system produced by laser-assisted directional solidification. Journal of Solid State Chemistry, 2022, 315: 123525.
[36] MOSHTAGHIOUN B M, PEÑA J I, MERINO R I. Can Y₂O₃-MgO eutectics be new promising structural and optical ceramics? Acta Materialia, 2021, 216: 117139.
[37] MOSHTAGHIOUN B M, PEÑA J I. Non-Hall-Petch hardness dependence in ultrafine fibrous MgAl₂O₄-MgO eutectic ceramics fabricated by the laser-heated floating zone (LFZ) method. Journal of the European Ceramic Society, 2019, 39(10): 3208.
[38] ORTEGA-SAN-MARTIN L, PEÑA J I, LARREA Á, et al. Directionally solidified CeO₂ (or GDC)/CoO eutectic ceramics as cermet precursors for SOFCs anodes: Microstructure cross-over. Journal of the European Ceramic Society, 2011, 31(7): 1269.
[39] LIU H F, ZHANG B W, ZHANG B, et al. Advances, challenges and prospects in one-step preparation of melt-grown Al₂O₃-based eutectic in-situ composite ceramics by laser additive manufacturing. Ceramics International, 2026, 52(7): 8213.
[40] WAKU Y, NAKAGAWA N, WAKAMOTO T, et al. A ductile ceramic eutectic composite with high strength at 1,873 K. Nature, 1997, 389(6646): 49.
[41] ZHANG R Z, REECE M J. Review of high entropy ceramics: design, synthesis, structure and properties. Journal of Materials Chemistry A, 2019, 7(39): 22148.
[42] LI Y R, PAN D H, CAO J H, et al. Recent advances in high-entropy ceramics: design principles, structural characteristics, and emerging properties. Extreme Materials, 2025, 1(2): 42.
[43] ROST C M, SACHET E, BORMAN T, et al. Entropy-stabilized oxides. Nature Communications, 2015, 6: 8485.
[44] PASTOR J Y, LLORCA J, MARTÍN A, et al. Fracture toughness and strength of Al₂O₃-Y₃Al₅O₁₂ and Al₂O₃-Y₃Al₅O₁₂-ZrO₂ directionally solidified eutectic oxides up to 1900 K. Journal of the European Ceramic Society, 2008, 28(12): 2345.
[45] ZHOU C, SUN L C, DU T F, et al. Microstructure, crystallographic texture and mechanical properties of directionally solidified high-entropy (Y_0.2Gd_0.2Ho_0.2Er_0.2Yb_0.2)AG/Al₂O₃ eutectic oxides: insights of growth rate control. Journal of Materials Science & Technology, 2026, 252: 232.
[46] WANG X, ZHONG Y J, LI H D, et al. Dual-phase eutectic ceramics with improved hardness and toughness via nano-coherent high-entropy oxides. Nature Communications, 2026, 17: 7494.
[47] SAI Q L, ZHAO Z W, XIA C T, et al. Ce-doped Al₂O₃-YAG eutectic and its application for white LEDs. Optical Materials, 2013, 35(12): 2155.
[48] LIU Y, SU H J, LU Z, et al. Collaborative enhancement of luminous efficacy and fracture toughness based on interface design of Al₂O₃/YAG:Ce³⁺ eutectic phosphor ceramic grown by laser floating zone melting. Ceramics International, 2022, 48(7): 10144.
[49] XU J, GUYOT Y, NEHARI A, et al. Cr-doped Al₂O₃-YAG binary and Al₂O₃-YAG-ZrO₂ ternary eutectic materials crystallized by the micro pulling down technique and their characterization. CrystEngComm, 2023, 25(34): 4834.
[50] LIU Y, ZHANG M F, WU D, et al. Microstructures and mechanical properties of Al₂O₃/YAG:Ce³⁺ eutectics with different Ce³⁺ concentrations grown by HDS method. Journal of Alloys and Compounds, 2020, 816: 152515.
[51] MERINO R I, OLIETE P B, MOSHTAGHIOUN B M, et al. Directionally solidified cobalt-doped MgO-MgAl₂O₄ eutectic composites for selective emitters. Applied Sciences, 2022, 12(20): 10254.
[52] XU J, GUYOT Y, NEHARI A, et al. Micro pulling down melt solidification of Co-doped Al₂O₃-YAG binary and Al₂O₃-YAG-ZrO₂ ternary eutectics systems and characterization. Optical Materials, 2026, 171: 117776.
[53] LIU Y, SU H J, LU Z, et al. Energy transfer and thermal stability enhancement in Ce/Cr co-doped Al₂O₃/YAG eutectic phosphor ceramics for broadband red-emission. Ceramics International, 2022, 48(16): 23598.
[54] LU H, SONG Q S, XU X D, et al. Improving the CRI of Al₂O₃-YAG:Ce eutectic for high-power white LEDs applications: energy-transfer and co-luminescence. Optical Materials, 2021, 121: 111415.
[55] GRIMA L, PEÑA J I, SANJUÁN M L. Ceramics with eutectic microstructure in the ZrO₂-PrO_x system. Journal of the American Ceramic Society, 2023, 106(11): 7098.
[56] OLIETE P B, LÓPEZ-ROBLEDO M J, PEÑA J I, et al. Directionally solidified Al₂O₃-ME₃Al₅O₁₂ (ME: Y, Er and Yb) eutectic coatings for thermophotovoltaic systems. Ceramics International, 2017, 43(18): 16270.
[57] MERINO R I, PARDO J A, PEÑA J I, et al. Microstructure-size dependence of the 1.520 μm Er³⁺ luminescence lifetime in Al₂O₃-ZrO₂ eutectic melt growth composites. Applied Physics Letters, 2002, 80(4): 589.
[58] SAI Q L, XIA C T. Tunable colorimetric performance of Al₂O₃-YAG: Ce³⁺ eutectic crystal by Ce³⁺ concentration. Journal of Luminescence, 2017, 186: 68.
[59] HRYN L O, SIRYK Y V, BARANOV V V, et al. The effect of cerium doping and rate of crystallization on the microstructure of the Al₂O₃/YAG eutectic composite. Functional Materials, 2023, 30(4): 606.
[60] SHAKHNO A, ZORENKO T, WITKIEWICZ-ŁUKASZEK S, et al. Ce³⁺ doped Al₂O₃-YAG eutectic as an efficient light converter for white LEDs. Materials, 2023, 16(7): 2701.
[61] ZHAI S Y, PAN W, LIU J C. Regulation of Y₂O₃ addition on structure and properties of Al₂O₃/ZrO₂(Y₂O₃) directionally solidified eutectic ceramic. Ceramics International, 2023, 49(18): 30240.
[62] BENAMARA O, LEBBOU K. The impact of the composition and solidification rate on the microstructure and the crystallographic orientations of Al₂O₃-YAG-ZrO₂ eutectic solidified by the micro-pulling down technique. RSC Advances, 2021, 11(22): 13602.
[63] CALDERON MORENO J, YOSHIMURA M. Rapidly solidified eutectic composites in the system Al₂O₃-Y₂O₃-ZrO₂: ternary regions in the subsolidus diagram. Solid State Ionics, 2002, 154/155: 311.
[64] NIU F Y, WU D J, MA G Y, et al. Effect of second-phase doping on laser deposited Al₂O₃ ceramics. Rapid Prototyping Journal, 2015, 21(2): 201.
[65] 付连生, 付莹, 张瑞祥, 等. Y₂O₃添加量对Al₂O₃/ZrO₂共晶陶瓷显微组织及力学性能的影响. 材料科学与工艺, 2023, 31(4): 87.
[66] WU D J, HUANG Y F, NIU F Y, et al. Effects of TiO₂ doping on microstructure and properties of directed laser deposition alumina/aluminum titanate composites. Virtual and Physical Prototyping, 2019, 14(4): 371.
[67] LIU Y, SU H J, SHEN Z L, et al. Insight into the complex coupled growth behavior of Al₂O₃/YAG eutectic ceramic based on the evolutions of microstructure and crystallographic texture. Journal of the European Ceramic Society, 2023, 43(10): 4482.
[68] ITO C, MAEDA T, HIGASHI R, et al. Application of extreme value statistics to internal pore distribution in ceramics and prediction of size dependency of strength scatter. Journal of the European Ceramic Society, 2024, 44(5): 3381.
[69] LIU J L, CHEN L Y, YAO S, et al. Microstructural refinement in oxide eutectic ceramics by post-flash annealing. Journal of the American Ceramic Society, 2026, 109(6): e70891.
[70] TIAN Y J, XU B, YU D L, et al. Ultrahard nanotwinned cubic boron nitride. Nature, 2013, 493(7432): 385.
[71] FU X, CHEN G Q, ZU Y F, et al. Microstructure refinement of melt-grown Al₂O₃/YAG/ZrO₂ eutectic composite by a new method: melt superheating treatment. Scripta Materialia, 2013, 68(9): 731.
[72] WANG S H, LIU J C. Microstructure analysis of Al₂O₃/Er₃Al₅O₁₂/ZrO₂ DSECs prepared using high-frequency zone melting method. Journal of Alloys and Compounds, 2020, 830: 154653.
[73] ZHAI S Y, LIU J C, LAN D H, et al. High temperature tensile strength of large size Al₂O₃/ZrO₂(Y₂O₃) directionally solidified eutectic ceramics. Materials Letters, 2022, 307: 130950.
[74] ZHANG B W, KUAI P, LIU H F, et al. Effects of high-entropy design on mechanical and thermal properties of Al₂O₃-GdAlO₃ composite ceramic with eutectic composition. Journal of Alloys and Compounds, 2026, 1065: 188081.
[75] LLORCA J, ORERA V M. Directionally solidified eutectic ceramic oxides. Progress in Materials Science, 2006, 51(6): 711.
[76] YAN S, WU D J, MA G Y, et al. Formation mechanism and process optimization of nano Al₂O₃-ZrO₂ eutectic ceramic via laser engineered net shaping (LENS). Ceramics International, 2017, 43(17): 14742.
[77] SUN H F, ZHOU C, DU T F, et al. Preparation, microstructures, and mechanical properties of directionally solidified Al₂O₃/Lu₃Al₅O₁₂ eutectic ceramics. International Journal of Applied Ceramic Technology, 2022, 19(2): 695.
[78] SONG K, ZHANG J, JIA X J, et al. Microstructure of Al₂O₃/YAG/ZrO₂ hypereutectic alloy directionally solidified by laser floating zone method. Acta Metallurgica Sinica, 2012, 48(2): 220.
[79] SU H J, LIU Y, REN Q, et al. Unveiling the dynamic instability mechanism of microstructure transformation in faceted oxide eutectic composite ceramics. Journal of Materials Science & Technology, 2023, 144: 224.
[80] MA W D, ZHANG J, SU H J, et al. Phase growth patterns for Al₂O₃/GdAlO₃ eutectics over wide ranges of compositions and solidification rates. Journal of Materials Science & Technology, 2021, 65: 89.
[81] FENG Y J, LIU X Y, ZHANG P, et al. Dendrite microstructure formation and enhanced toughness in high-entropy REAlO₃-RE₂Zr₂O₇ eutectic oxide. Journal of the American Ceramic Society, 2023, 106(12): 7736.
[82] LU Y H, ZHONG Q, YANG L P, et al. Microstructure, eutectic mechanism, and properties of Al₂O₃/YAG eutectic ceramics prepared through focused nanosecond pulsed laser-induced nucleation. JOM, 2026, 78(7): 6334.
[83] LI F Z, ZHANG Y. Microstructural characterization of Al₂O₃-ZrO₂ceramic by laser direct material deposition. Journal of Laser Applications, 2019, 31(2): 022509.
[84] WU D J, SAN J D, NIU F Y, et al. Effect and mechanism of ZrO₂ doping on the cracking behavior of melt-grown Al₂O₃ ceramics prepared by directed laser deposition. International Journal of Applied Ceramic Technology, 2020, 17(1): 227.
[85] HU Y B, WANG H, CONG W L, et al. Directed energy deposition of zirconia-toughened alumina ceramic: novel microstructure formation and mechanical performance. Journal of Manufacturing Science and Engineering, 2020, 142(2): 021005.
[86] LIU Y, SU H J, SHEN Z L, et al. Effect of seed orientations on crystallographic texture control in faceted Al₂O₃/YAG eutectic ceramic during directional solidification. Journal of Materials Science & Technology, 2023, 146: 86.
[87] XIONG Z W, ZHANG K, LIU T T, et al. Role of scanning speed on the microstructure and mechanical properties of additively manufactured Al₂O₃-ZrO₂. Journal of the American Ceramic Society, 2023, 106(12): 7760.
[88] ZHONG Y J, YUAN Y, LI H D, et al. Orientation relationships of seed crystal-induced Al₂O₃/GdAlO₃ eutectic ceramics. Acta Materialia, 2025, 294: 121094.
[89] ZHENG Y T, YU W J, YU Y D, et al. Fracture morphology and toughening mechanism of Al₂O₃/ZrO₂ eutectic ceramic prepared by the combustion synthesis under ultra-high temperature. International Journal of Refractory Metals and Hard Materials, 2019, 81: 21.
[90] WANG Y W, WANG X L, WANG X Y, et al. Effect of CeO₂ on the microstructure and properties of plasma-sprayed Al₂O₃-ZrO₂ ceramic coatings. Journal of Materials Engineering and Performance, 2020, 29(10): 6390.
[91] SINGH B K, SELVARASU A, GANESHAN P, et al. Morphological & physical characteristics of Ceria (CeO₂) doped Zirconia Toughened Alumina (ZTA) ceramics composites. Journal of Ceramic Processing Research, 2025, 26(5): 726.
[92] OLIETE P B, MERINO R I, PEÑA J I, et al. Phase segregation of aged MgCSZ-MgO directionally solidified eutectic composites. Journal of the American Ceramic Society, 2025, 108(6): e20443.
[93] CHEN J Q, WANG W L, SUN X N, et al. Microstructure and mechanical properties of zirconia toughened nacre-like alumina ceramics. Materials Science and Engineering: A, 2022, 855: 143908.
[94] WU D J, LU F, ZHAO D K, et al. Effect of doping SiC particles on cracks and pores of Al₂O₃-ZrO₂ eutectic ceramics fabricated by directed laser deposition. Journal of Materials Science, 2019, 54(13): 9321.
[95] WU D J, YU X X, ZHAO Z Y, et al. One-step additive manufacturing of TiC_p reinforced Al₂O₃-ZrO₂ eutectic ceramics composites by laser directed energy deposition. Ceramics International, 2023, 49(8): 12758.
[96] LAN D H, GAO R, LIU X D, et al. Microstructure and mechanical properties of ZrO₂ fiber toughened Al₂O₃/ZrO₂(Y₂O₃) solidified ceramics prepared with high frequency induction zone melting. Journal of Alloys and Compounds, 2023, 967: 171669.
[97] CHEN Z Y, LAN D H, GAO R, et al. The effect of fibers addition on the microstructure and mechanical properties of ZrO₂ fibers toughened Al₂O₃/ZrO₂ (Y₂O₃) solidified ceramics. Materials Today Communications, 2024, 40: 109817.
[98] LU B H, SU H J, LI X H, et al. From refined eutectic architecture to enhanced mechanical properties: microstructure evolution and toughening behavior in SiC whisker-reinforced eutectic ceramics composites via hot-pressing. Ceramics International, 2026, 52(13): 23411.
[99] OLIETE P B, PEÑA J I, LARREA A, et al. Ultra-high-strength nanofibrillar Al₂O₃-YAG-YSZ eutectics. Advanced Materials, 2007, 19(17): 2313.
[100]AOKI Y, MASUDA H, TOCHIGI E, et al. Overcoming the intrinsic brittleness of high-strength Al₂O₃-GdAlO₃ ceramics through refined eutectic microstructure. Nature Communications, 2024, 15: 8700.
[101]ZHAO Z M, ZHANG L, SONG Y G, et al. Microstructures and properties of rapidly solidified Y₂O₃ doped Al₂O₃/ZrO₂ composites prepared by combustion synthesis. Scripta Materialia, 2006, 55(9): 819.
[102]GURAUSKIS J, LENNIKOV V, DE LA FUENTE G F, et al. Laser-assisted, crack-free surface melting of large eutectic ceramic bodies. Journal of the European Ceramic Society, 2011, 31(7): 1251.
[103]WANG Z G, OUYANG J H, MA Y H, et al. Grain size dependence, mechanical properties and surface nanoeutectic modification of Al₂O₃-ZrO₂ ceramic. Ceramics International, 2019, 45(11): 14297.
[104]ESTER F J, LARREA A, MERINO R I. Processing and microstructural study of surface laser remelted Al₂O₃-YSZ-YAG eutectic plates. Journal of the European Ceramic Society, 2011, 31(7): 1257.
[105]SU H J, ZHANG J, MA W D, et al. In situ fabrication of highly-dense Al₂O₃/YAG nanoeutectic composite ceramics by a modified laser surface processing. Journal of the European Ceramic Society, 2014, 34(3): 739.
[106]ZHAI S Y, CAO X Y, LIU J C, et al. Microstructure characteristics and mechanical properties of Al₂O₃/MgAl₂O₄ directionally solidified eutectic ceramic. Advances in Applied Ceramics, 2022, 121(4): 119.
[107]WAKU Y, SAKATA S I, MITANI A, et al. A novel oxide composite reinforced with a ductile phase for very high temperature structural materials. Materials Research Innovations, 2001, 5(2): 94.
[108]LI J G, CAI Q W, LUO G Q, et al. Zirconia toughened alumina ceramics via forming intragranular structure. Materials, 2024, 17(6): 1309.
[109]LIU Z, SONG K, GAO B, et al. Microstructure and mechanical properties of Al₂O₃/ZrO₂directionally solidified eutectic ceramic prepared by laser 3D printing. Journal of Materials Science & Technology, 2016, 32(4): 320.
[110]WU D J, LIU H C, LU F, et al. Al₂O₃-YAG eutectic ceramic prepared by laser additive manufacturing with water-cooled substrate. Ceramics International, 2019, 45(3): 4119.
[111]ZHAI S Y, YUAN J H, LIU J C, et al. Microstructure and mechanical properties of directionally solidified Al₂O₃/YAG binary eutectic ceramic prepared with induction heating zone melting. Materials Chemistry and Physics, 2020, 242: 122503.
[112]CAO X, SU H J, GUO F W, et al. Directionally solidified Al₂O₃/GAP eutectic ceramics by micro-pulling-down method. AIP Conference Proceedings, Tomsk, 2016. 1783(1): 020021.
[113]牛方勇, 吴东江, 石龙飞, 等. Al₂O₃/ZrO₂陶瓷激光近净成形工艺研究及性能分析. 人工晶体学报, 2015, 44(11): 3223.
[114]熊志伟, 张凯, 刘婷婷, 等. 激光功率对激光粉末床熔融成形Al₂O₃-ZrO₂共晶陶瓷熔池形态、微观组织和力学性能影响的研究. 中国激光, 2024, 51(10): 1002316.
[115]SONG K, ZHANG J, LIN X, et al. Microstructure and mechanical properties of Al₂O₃/Y₃Al₅O₁₂/ZrO₂ hypereutectic directionally solidified ceramic prepared by laser floating zone. Journal of the European Ceramic Society, 2014, 34(12): 3051.
[116]欧阳家虎, 喻天罡, 马永辉, 等. 三元共晶成分Al₂O₃/YAG/ZrO₂粉体及陶瓷的制备与组织性能. 稀有金属材料与工程, 2018, 47(S1): 288.
[117]LU B H, SU H J, ZHAO D, et al. Densification mechanism and microstructure evolution of large-sized Al₂O₃/YAG/ZrO₂ eutectic ceramics by hot-pressing sintering based on micro-nano eutectic-structured powders. Journal of Materials Science & Technology, 2026, 256: 25.
[118]MESA M C, OLIETE P B, PASTOR J Y, et al. Mechanical properties up to 1900 K of Al₂O₃/Er₃Al₅O₁₂/ZrO₂ eutectic ceramics grown by the laser floating zone method. Journal of the European Ceramic Society, 2014, 34(9): 2081.
[119]HARADA Y, SUZUKI T, HIRANO K, et al. Environmental effects on ultra-high temperature creep behavior of directionally solidified oxide eutectic ceramics. Journal of the European Ceramic Society, 2005, 25(8): 1275.
[120]MAZEROLLES L, PERRIERE L, LARTIGUE-KORINEK S, et al. Creep behavior and related structural defects in Al₂O₃-Ln₂O₃ (ZrO₂) directionally solidified eutectics (Ln=Gd, Er, Y). Journal of the European Ceramic Society, 2011, 31(7): 1219.
[121]LONDAITZBÉHÈRE L, LARTIGUE-KORINEK S, MAZEROLLES L. Microstructure, interfaces and creep behaviour of Al₂O₃-Sm₂O₃ (ZrO₂) eutectic ceramic composites. Journal of Materials Science, 2017, 52(10): 5489.
[122]ZHOU C, LI J, SUN L C, et al. Alumina-based directionally solidified eutectic ceramics: microstructure, control strategies and environmental stability. Journal of Inorganic Materials, 2026, 41(7): 899.
[123]WANG R T, SU H J, TAN X, et al. High-temperature water-oxygen corrosion behavior of directionally solidified Al₂O₃/YAG eutectic ceramics at 1300–1500 ℃. Journal of Alloys and Compounds, 2025, 1044: 184587.
[124]SUN H F, SUN L C, REN X M, et al. Outstanding molten calcium-magnesium-aluminosilicate (CMAS) corrosion resistance of directionally solidified Al₂O₃/Y₃Al₅O₁₂ eutectic ceramic at 1500 ℃. Corrosion Science, 2023, 220: 111289.
[125]PORTEBOIS L, MATHIEU S, VILASI M, et al. Chemical degradation of the ternary Al₂O₃-YAG-ZrO₂ eutectic ceramic by molten CMAS. High Temperature Corrosion of Materials, 2024, 101(5): 1117.
[126]MIYOSHI K, FARMER S C, SAYIR A. Wear properties of two-phase Al₂O₃/ZrO₂ (Y₂O₃) ceramics at temperatures from 296 to 1073 K. Tribology International, 2005, 38(11/12): 974.
[127]YAN S, WU D J, NIU F Y, et al. Al₂O₃-ZrO₂ eutectic ceramic via ultrasonic-assisted laser engineered net shaping. Ceramics International, 2017, 43(17): 15905.
[128]ZHAO D, SU H J, HAO S Q, et al. Excellent thermal stability of nanostructured Al₂O₃-Y₃Al₅O₁₂-ZrO₂ eutectic ceramic composites by high-speed directional solidification. Composites Part B: Engineering, 2023, 266: 111035.

氧化物共晶陶瓷的成分设计、强韧化机制与高温性能研究进展

Research Progress on Oxide Eutectic Ceramics: Composition Design, Strengthening and Toughening Mechanisms, and High Temperature Performance

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	曹丙强, 李兴牧, 魏浩铭, 单衍苏. 脉冲激光沉积制备卤化物钙钛矿薄膜研究进展[J]. 无机材料学报, 2026, 41(9): 1178-1192.
[2]	黄淦, 薛佳祥, 檀财旺, 刘洋, 张国梁, 杨正茂, 陈招科. 核用SiC复合包壳多尺度力学损伤研究方法评述[J]. 无机材料学报, 2026, 41(9): 1157-1177.
[3]	钟鸿, 张宇豪, 单青松, 胡天鋆, 曾海波. 叠层量子点发光二极管的研究进展[J]. 无机材料学报, 2026, 41(8): 1036-1048.
[4]	马稚童, 李众少, 曹逊. 动态辐射热管理技术: 从原理、材料到协同优化设计[J]. 无机材料学报, 2026, 41(8): 1021-1035.
[5]	司会晨, 梁飞, 于浩海, 张怀金. 黄橙激光晶体材料与全固态激光器件研究进展[J]. 无机材料学报, 2026, 41(8): 1049-1068.
[6]	覃善丽, 郭佳文, 陈燕萌, 聚安安, 韦毅, 黄科林, 侯向华, 吕思师, 文志朋, 吴炼. 二维层状材料构筑电化学储能定向离子传输通道的研究进展[J]. 无机材料学报, 2026, 41(7): 883-898.
[7]	余飞宇, 王文清, 张学勤, 何汝杰. 基于增材制造陶瓷点阵的双相网络互穿复合材料的研究进展与挑战[J]. 无机材料学报, 2026, 41(7): 849-866.
[8]	周翠, 李捷, 孙鲁超, 苏海军, 王京阳. 氧化铝基定向凝固共晶陶瓷的组织特性、调控方法及环境稳定性[J]. 无机材料学报, 2026, 41(7): 899-914.
[9]	费文龙, 王亚坤, 廖良生. 蓝光ZnSeTe量子点的可控制备及其量子点发光二极管器件研究进展[J]. 无机材料学报, 2026, 41(7): 867-882.
[10]	陈明俊, 缪洪康, 肖英俊, 邓建波, 张翔, 赵九蓬, 李垚. 光-热双响应材料研究进展: 从设计策略到智能窗应用[J]. 无机材料学报, 2026, 41(6): 723-738.
[11]	宋坤洁, 解荣军. 机器学习驱动新型发光材料的研究进展[J]. 无机材料学报, 2026, 41(6): 689-703.
[12]	胡钰晴, 朱一新, 乐先浩, 万青. 钽酸锂晶圆减薄技术及其热释电红外探测器应用进展[J]. 无机材料学报, 2026, 41(6): 764-774.
[13]	刘春帆, 陈科, 葛芳芳, 黄庆. 核用耐铅铋腐蚀涂层的研究进展[J]. 无机材料学报, 2026, 41(6): 775-786.
[14]	胡扬, 谢敏, 张筱怡, 李想, 郭新伟, 姜南, 周文瀚, 张胜利, 曾海波. 计算与数据驱动环保型发光材料的研究进展[J]. 无机材料学报, 2026, 41(6): 704-722.
[15]	王俊卜, 黄泽皑, 杨茗凯, 蒙颖, 周明炜, 周莹. 甲烷转化用抗积碳催化材料研究进展[J]. 无机材料学报, 2026, 41(6): 739-750.