Preparation and Characteristic of One-dimensional Magnesium Borate Nanomaterials

doi:10.3724/SP.J.1077.2010.00947

Abstract

Abstract:

Single-crystalline magnesium borate nanorods were fabricated by solvothermal method at the supercritical conditions. This reaction condition enabled the formation of magnesium borate with one dimensional nanostructure without the involvement of surfactants. The microstructures of as-synthesized products prepared at different reaction stages were characterized by X-ray diffraction. The results show that Mg₂B₂O₅ structure is obtained through an intermediate transition from Mg(OH)₂ to MgBO₂(OH), and then from MgBO₂(OH) to Mg₂B₂O₅. The morphology of the products at corresponding stages were observed by scanning electron microscope(SEM), showing that the formation process of Mg₂B₂O₅ nanorods was from flake-like to short columnar and then to rod. The result suggests that the formation of Mg₂B₂O₅nanorods follow a process from nucleation → dissolution → anisotropic growing → recrystallization.

Key words: magnesium borate, nanomaterial, solvothermal method

CLC Number:

TB35

LI Tian-Bao, LIANG Jian, XU Bing-She, WANG Jin. Preparation and Characteristic of One-dimensional Magnesium Borate Nanomaterials[J]. Journal of Inorganic Materials, 2010, 25(9): 947-951.

References

[1]Peng L M, Zhu S J, Ma Z Y, et al. High temperature creep deformation of Al18B4O33 whisker-reinforced 8009 Al composite.Mater. Sci. Eng. A,1999, 265(1/2):63-70
[2]Shahare D L, Dhoble S J, Moharil S V. Preparation and characterization of magnesium-borate phosphor.J. Mater. Sci. Lett,1993, 12(23):1873-1874
[3]Wu P L, Tian Z, Wang L D, et al. Effect of changing rate of residual stress on thermal expansion behavior of magnesium borate whisker-reinforced aluminum composite.Thermochim. Acta,2007, 455(1/2):7-10
[4]Kuchibhatla S V N T, Karakoti A S, Bera D, et al. One dimensional nanostructured materials.Prog. Mater. Sci,2007, 52(5):699-913
[5]Xia Y, Yang P, Sun Y, et al. One-dimensional nanostructures: synthesis, characterization, and applications.Adv. Mater,2003, 15(5):353-389
[6]Ma R, Bando Y, Sato T. Nanowires of metal borates.Appl. Phys. Lett,2002, 81(18):3467-3469
[7]Li Y, Fan Z, Lu J G, et al. Synthesis of magnesium borate (Mg2B2O5) nanowires by chemical vapor deposition method.Chem. Mater,2004, 16 (13):2512-2514
[8]Ma R, Bando, Y, Golberg D, et al. Nanotubes of magnesium borate.Angew. Chem. Int. Ed,2003, 42(16):1836-1838
[9]Elssfah E M, Elsanousi H A, Zhang J, et al. Synthesis of magnesium borate nanorods.Mater. Lett,2007, 61(22):4358-4361
[10]Zhang J, Li Z, Zhang B. Formation and structure of single crystalline magnesium borate (Mg3B2O6) nanobelts.Mater. Chem. Phys,2006, 98(2/3):195-197
[11]Rao C N R, Deepak F L, Gundiah G, et al. Inorganic nanowires.Prog. Solid State Chem,2003, 31(1/2):5-147
[12]Lu J G, Chang P, Fan Z. Quasi-one-dimensional metal oxide materials- synthesis, properties and applications.Mater. Sci. Eng. R,2006, 52(1/2/3):49-91
[13]Rabenau A. The role hydrothermal synthesis in preparative chemistry.Angew. Chem. Int. Ed. Engl,1985, 24(12):1026-1040

[1]	LI Shiqi, BAO Qunqun, HU Ping, SHI Jianlin. Anti-metastatic Immunotherapy of Advanced Tumors Based on EDTA Intercalated Zinc-aluminum Layered Double Hydroxide [J]. Journal of Inorganic Materials, 2024, 39(9): 1044-1052.
[2]	ZHANG Zhe, SUN Tingting, WANG Lianjun, JIANG Wan. Flexible Thermoelectric Films with Different Ag₂Se Dimensions: Performance Optimization and Device Integration [J]. Journal of Inorganic Materials, 2024, 39(11): 1221-1227.
[3]	LI Yanyan, PENG Yusi, LIN Chenglong, LUO Xiaoying, TENG Zheng, ZHANG Xi, HUANG Zhengren, YANG Yong. Nanomaterials and Biosensing Technology for the SARS-CoV-2 Detection [J]. Journal of Inorganic Materials, 2023, 38(1): 3-31.
[4]	LIU Yao, YOU Xunhai, ZHAO Bing, LUO Xiaoying, CHEN Xing. Functional Nanomaterials for Electrochemical SRAS-CoV-2 Biosensors: a Review [J]. Journal of Inorganic Materials, 2023, 38(1): 32-42.
[5]	CAO Zhijun, LI Zaijun. Ruthenium-biocarbon Mimic Enzyme: Synthesis and Application in Colorimetric Detection of Pesticide Chlorpyrifos [J]. Journal of Inorganic Materials, 2022, 37(5): 554-560.
[6]	LEI Weiyan, WANG Yue, WU Shiran, SHI Dongxin, SHEN Yi, LI Fengfeng. 2D Nanomaterials from Group VA Single-element: Research Progress in Biomedical Fields [J]. Journal of Inorganic Materials, 2022, 37(11): 1181-1191.
[7]	LI Huaxin, CHEN Junyong, XIAO Zhou, YUE Xian, YU Xianbo, XIANG Junhui. Research Progress of Biomimetic Self-assembly of Nanomaterials in Morphology and Performance Control [J]. Journal of Inorganic Materials, 2021, 36(7): 695-710.
[8]	YANG Mai, ZHU Min, CHEN Yu, ZHU Yufang. FePS₃ Nanosheets: Preparation and Potential in Photothermal-photodynamic Therapy [J]. Journal of Inorganic Materials, 2021, 36(10): 1074-1082.
[9]	CHENG Xiaokun, ZHANG Yue, Lü Haijun, LIU Xinying, HOU Senlin, CHEN Aibing. Porous Carbon Nanomaterials Based Tumor Targeting Drug Delivery System: a Review [J]. Journal of Inorganic Materials, 2021, 36(1): 9-24.
[10]	DING Sheng, NING Kai, YUAN Binxia, PAN Weiguo, YIN Shibin, LIU Jianfeng. Durability of Fe-N/C Catalysts with Different Nanostructures for Electrochemical Oxygen Reduction in Alkaline Solution [J]. Journal of Inorganic Materials, 2020, 35(8): 953-958.
[11]	ZHANG Zhi-Ming,FANG Xiao-Sheng. Preparation and Photodetection Property of ZnO Nanorods/ZnCo₂O₄ Nanoplates Heterojunction [J]. Journal of Inorganic Materials, 2019, 34(9): 991-996.
[12]	SUI Li-Li, WANG Run, ZHAO Dan, SHEN Shu-Chang, SUN Li, XU Ying-Ming, CHENG Xiao-Li, HUO Li-Hua. Construction of Hierarchical α-MoO₃ Hollow Microspheres and Its High Adsorption Performance towards Organic Dyes [J]. Journal of Inorganic Materials, 2019, 34(2): 193-200.
[13]	ZHANG Yi-Qing, LIU Li, ZHANG Shu-Juan, WAN Zheng-Rui, LIU Hong-Ying, ZHOU Li-Qun. Preparation and Dehydrogenation Property of NH₂-UIO-66 Supported RuCuMo Nanocatalyst [J]. Journal of Inorganic Materials, 2019, 34(12): 1316-1324.
[14]	ZHANG Li-Xian, LIANG Yan-Qin, WANG Shao-Dan, LU Hong, LIU Ai-Feng, WEI Qiang. One-step Synthesis of Black TiO₂ Composite Coating on Glass by Pulsed Laser Spraying [J]. Journal of Inorganic Materials, 2019, 34(1): 109-113.
[15]	ZHANG Jiao-Xia, YI Jing, JIAO Yue-Ting, LI Shi-Yun, SHI Xin-Lan, SUN Kai. Preparation and Application of Water-soluble TiO₂-ionic Liquids Hybrid Nanomaterials [J]. Journal of Inorganic Materials, 2018, 33(5): 577-581.