Research Progress of Biomimetic Self-assembly of Nanomaterials in Morphology and Performance Control

doi:10.15541/jim20200443

Abstract

Abstract:

Nano materials exhibit many excellent properties compared with macro scale materials due to their special properties at nanoscale. They exhibit good application prospects in various fields such as mechanics, acoustics, optics, magnetism, electricity, thermology and so on. In this fascinating field, biomimetic self-assembly technology of nano materials has become one of the main methods to prepare nano materials, which simulates the life activities in vivo and makes the nano materials spontaneously form stable structures based on the noncovalent bond interaction. The biomimetic self-assembly technology is an important technology in the “bottom-up” method, which is expected to replace the traditional “top-down” processing technology, and realize the construction of specific structure and function devices on the nanoscale by single atom or molecule. Moreover, although the bionic self-assembly technology is mainly chemical process, it also has physical process, and combines advantages of “bionics” and has characteristics of directional construction of nano materials, which is a hot research means of many interdisciplinary. This paper reviews different biomimetic self-assembly synthesis strategies for nano materials in morphology and performance control, including phase selective self-assembly of shielding effect, bionic self-assembly of biphase interface synergy effect, integrated fabrication of functional devices with field induced localization effect, photoinduced self-assembly and phase separation self-assembly driven by hydroxyl hydrogen bond. The characteristics of biomimetic self-assembled nano materials are summarized. This paper also introduced the application of self-assembly technology in sensors, surface Raman scattering, biomedical and other fields. In addition, the prospects for the development of biomimetic self-assembly technology of nanomaterials are prospected.

Key words: nanomaterials, biomimetic self-assembly, shielding effect, biphasic interface, field induction, review

CLC Number:

TQ174

LI Huaxin, CHEN Junyong, XIAO Zhou, YUE Xian, YU Xianbo, XIANG Junhui. Research Progress of Biomimetic Self-assembly of Nanomaterials in Morphology and Performance Control[J]. Journal of Inorganic Materials, 2021, 36(7): 695-710.

Figures/Tables 10

Fig. 1 (a) Schematic procedure of micropattern fabrication employing a shielding reagent[32] and (b) route of self-assembled surface nanopatterns based on shielding effect[37]

Fig. 2 Schematic diagram of Pickering emulsion stability mechanism[40] (a) O/W emulsion; (b) W/O emulsion; (c) Changes of surface tension when particles with radius rare adsorbed on the oil-water interface

Fig. 3 Preparation process and characterization of ultra-thin polyimide nanofilms[41] (BBR: Brilliant Blue R; AB: Aniline Blue; AF: Acid Fuchsin; RB: Rose Bengal; MO: Methyl Orange)

Fig. 4 (a) Schematic diagram of formation and transfer of interfacial self-assembly mlfs[42]; (b) Schematic diagram of anisotropic X-shaped goethite crystal self-assembly at oil/water interface to form micron scale hollow spheres[44]; (c) Schematic diagram of self-assembly of crystalline diblock copolymer at oil/water interface[45] (BCP: Block Copolymer)

Fig. 5 Effect of gold nanoparticles (AuNP) on self-assembly size in different phase interfaces[46]

Fig. 6 (a,b) Schematic diagram of self-assembly and electric field induced self-assembly and assembly process with different morphologies[52]; (c) Schematic diagram of magnetic field-induced self-assembly of one-dimensional nanocube belts[56]; (d) Schematic diagram of magnetic nanopillar array (FFPDMS column array) inducing self-assembly of iron oxide nanoparticles[57]

Fig. 7 (a) Schematic diagram of self-assembly and reassembly induced by light and metal ions[58]; (b) Preparation of HRP-loaded temperature-sensitive polymer vesicles by seed Photo-PISA[59]; (c) Light-induced in-situ self-assembly synthesis of polymer nanostructures[60]

Fig. 8 (a) Preparation of hydrophobic polysiloxane in aqueous phase by Sol-Gel method[61]; (b) Schematic diagram of preparation of ternary composite hydrophobic polyurethane sponge PU/HEC/SiO2 by hydroxyl hydrogen bond induction self-assembly[61]; (c) Schematic diagram of PVA/SiO2 with hydrophobicity induced by hydroxyl hydrogen bond[62]

Fig. 9 (a) SnS2/Zn2SnO4 hybrid membrane sensor performance under different applications: human exhalation, palm sweating, urine and water droplets on baby diapers[74]; (b) Glucose sensor based on GOx loaded H/G4-PANI hydrogel for detecting glucose[85]; (c) Real-time response of strain sensor arrays on human skin[83]

Fig. 10 (a) Rat liver hemostasis. Left: Liver produced massive bleeding after sagittal incision in the left lobe (Con. group). Right: Treatment with approximately 1%(w/v) (16 mmol/L) I3QGK aqueous solution leads to rapid hemostasis (I3QGK group)[120]; (b) Single-photon laser scanning confocal microscope for self-assembling peptides in PC-3 cells[122]

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