Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Preparation and Characterization of Biomorphic Silicon Carbide from Durra

WANG Qing1,2, WANG Dong-Hua1,2, JIN Guo-Qiang1, GUO Xiang-Yun1   

  1. 1. Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Taiyuan 030001, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, China
  • Received:2007-06-22 Revised:2007-08-15 Published:2008-05-20 Online:2008-05-20

Abstract: Durra was firstly transformed into carbon template by high-temperature pyrolysis and then converted into biomorphic SiC by infiltration of liquid Si in Ar atmosphere at 1600℃. The purified SiC sample was characterized by X-ray diffraction, scanning electron microscope and mercury intrusion. The results suggest that the sample mainly consist of β-SiC and perfectly replicate the microstructure and morphology of the carbon template. The durra-derived SiC has a mean pore diameter of 91.4μm and porosity of 76.6%, and both of them are similar to those of the carbon template, 88.5 μm and 71.2%, respectively. The specific surface area of SiC is 33.7m2/g, which is less than that of the carbon template, 59.4m2/g. The surface fractal dimension is 2.73 for the SiC sample and 2.70 for the template by analyzing the mercury intrusion data. The durra-derived SiC has characteristics of large grain size and high porosity.

Key words: biomorphic silicon carbide, microstructure, infiltration of liquid Si

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