Manganese Dioxide Morphology on Electrochemical Performance of Ti3C2Tx@MnO2 Composites

doi:10.15541/jim20190309

Abstract

Abstract:

Ti₃C₂T_x@MnO₂ composites with different morphologies were prepared by liquid-phase coprecipitation and hydrothermal method using Ti₃C₂T_x@PDA as matrix, KMnO₄ as manganese source, CTAB or PEG as surfactant. Effect of MnO₂ morphology (δ-MnO₂ nanofragments, α-MnO₂ nanorods, α-MnO₂ nanoflowers and α-MnO₂ nanowires) on phase structure and electrochemical performance of Ti₃C₂T_x was analyzed by FE-SEM, XRD, Raman, FT-IR, BET, and electrochemical measurements. The results show that Ti₃C₂T_x@α-MnO₂ nanowires possesses better comprehensive electrochemical properties (340.9 F?g ^-1 at 2 mV?s ^-1), nearly 2.5 times higher than using CTAB, and smaller charge transfer resistance, as well as excellent cycle stability.

Key words: MXene, polydopamine, surfactant, manganese dioxide, electrochemical performance

CLC Number:

TB333

LI Xue-Lin, ZHU Jian-Feng, JIAO Yu-Hong, HUANG Jia-Xuan, ZHAO Qian-Nan. Manganese Dioxide Morphology on Electrochemical Performance of Ti₃C₂T_x@MnO₂ Composites[J]. Journal of Inorganic Materials, 2020, 35(1): 119-125.

Figures/Tables 7

Fig. 1 FE-SEM mages of the samples

Fig. 2 FE-SEM images (a), TEM images (b) and EDS mappings (c-f) of Ti3C2Tx@PDA

Fig. 3 XRD patterns of samples (a) and corresponding drawing of partial enlargement (b)

Fig. 4 Raman spectra (a), FT-IR spectra (b), Nitrogen sorption isotherms (c) and pore size distributions (d) of samples

Fig. 5 CV curves at different scan rate (a) and GCD curves at different current densities (b) of Ti3C2Tx@α-MnO2 nanowires

Fig. 6 Electrochemical performance of samples

Table 1 Details of various parameters based Spectroscopy Impedance on the equivalent circuit derived by fitting Electrochemical (EIS) data of prepared samples

Sample	R_e/Ω	C_dl/μF	R_ct/Ω	Z_w/(Ω^-1?s^1/2)	C_L/mF
Ti₃C₂T_x	2.043	12.04	0.4575	0.04459	39.82
Ti₃C₂T_x@PDA	2.397	43.26	0.4671	0.09429	65.16
Ti₃C₂T_x@δ-MnO₂ nanofragments	2.678	187.1	1.333	0.0999	343.5
Ti₃C₂T_x@α-MnO₂ nanorods	2.989	31.7	1.358	0.04104	263.1
Ti₃C₂T_x@α-MnO₂ nanoflowers	2.304	20.89	1.925	0.001071	65.97
Ti₃C₂T_x@α-MnO₂ nanowires	2.592	135.3	1.268	0.1547	373.5

References 28

[1]	LUO X, WANG J H, DOONER M , et al.Overview of current development in electrical energy storage technologies and the application potential in power system operation. Applied Energy, 2015,137(C):511-536.
[2]	MUZAFFAR A, AHAMED M B, DESHMUKH K , et al.A review on recent advances in hybrid supercapacitors: design, fabrication and applications. Renewable and Sustainable Energy Reviews, 2019,101:123-145.
[3]	WANG F X, WU X W, YUAN X H , et al.Latest advances in supercapacitors: from new electrode materials to novel device designs. Chemical Society Reviews, 2017,46(22):6816-6854.
[4]	NAGUIB M, KURTOGLU M, PRESSER V , et al.Two-dimensional nanocrystals produced by exfoliation of Ti₃AlC₂. Advanced Materials, 2011,23(37):4248-4253.
[5]	ANASORI B, LUKATSKAYA M R, GOGOTSI Y . 2D metal carbides and nitrides (MXenes) for energy storage. Nature Reviews Materials, 2017,2(2):16098.
[6]	LI X L, ZHU J F, WANG L , et al.In-sit growth of carbon nanotubes on two-dimensional titanium carbide for enhanced electrochemical performance. Electrochimica Acta, 2017,258:291-301.
[7]	HOU D, TAO H S, ZHU X Z , et al.Polydopamine and MnO₂ core-shell composites for high-performance supercapacitors. Applied Surface Science, 2017,419:580-585.
[8]	GUO D, YU X Z, SHI W , et al.Facile synthesis of well-ordered manganese oxide nanosheet arrays on carbon cloth for high- performance supercapacitors. Journal of Materials Chemistry A, 2014,2(23):8833-8838.
[9]	YU S P, LIU R T, YANG W S , et al.Synthesis and electrocatalytic performance of MnO₂-promoted Ag@Pt/MWCNT electrocatalysts for oxygen reduction reaction. Journal of Materials Chemistry A, 2014,2(15):5371-5378.
[10]	WEI C G, XU C J, LI B H , et al.Anomalous effect of K ions on electrochemical capacitance of amorphous MnO₂. Journal of Power Sources, 2013,234:1-7.
[11]	TANGGARNJANAVALUKUL C, PHATTHARASUPAKUN N, KONGPATPANICH K , et al.Charge storage performances and mechanisms of MnO₂ nanospheres, nanorods, nanotubes and nanosheets.Nanoscale, 2017,9(36):13630-13639.
[12]	FENG X M, CHEN N N, ZHANG Y , et al.The self-assembly of shape controlled functionalized graphene-MnO₂ composites for application as supercapacitors.Journal of Materials Chemistry A, 2014,2(24):9178-9184.
[13]	WU Z S, REN W C, WANG D W , et al.High-energy MnO₂ nanowire/graphene and graphene asymmetric electrochemical capacitors.ACS Nano, 2010,4(10):5835-5842.
[14]	LUKATSKAYA M R, MASHTALIR O, REN C E , et al.Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science, 2013,341(6153):1502-1505.
[15]	LIN Z Y, SUN D F, HUANG Q , et al.Carbon nanofibers bridged two-dimensional titanium carbide as a superior anode in lithium- ion battery. Journal of Materials Chemistry A, 2015,3(27):14096-14100.
[16]	MASHTALIR O, LUKATSKAYA M R, KOLESNIKOV A I , et al.The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene). Nanoscale, 2016,8(17):9128-9133.
[17]	LIU W H, WANG Z Q, SU Y L , et al.Molecularly stacking manganese dioxide/titanium carbide sheets to produce highly flexible and conductive film electrodes with improved pseudocapacitive performances. Advanced Energy Materials, 2017,7(22):1602834.
[18]	WANG J F, ZHANG G N, REN L J , et al.Topochemical oxidation preparation of regular hexagonal manganese oxide nanoplates with birnessite-type layered structure. Crystal Growth & Design, 2014,14(11):5626-5633.
[19]	JIANG J H, KUCERNAK A . Electrochemical supercapacitor material based on manganese oxide: preparation and characterization. Electrochimica Acta, 2002,47(15):2381-2386.
[20]	BAJ B G S, ASIRI A M, QUSTI A H , et al.Sonochemically synthesized MnO₂ nanoparticles as electrode material for supercapacitors.Ultrasonics Sonochemistry, 2014,21(6):1933-1938.
[21]	KANG L P, ZHANG M M, LIU Z H , et al.IR spectra of manganese oxides with either layered or tunnel structures. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 2007,67(3/4):864-869.
[22]	YANG X J, MAKITA Y, LIU Z H , et al.Structural characterization of self-assembled MnO₂ nanosheets from birnessite manganese oxide single crystals.Chemistry of Materials, 2004,16(26):5581-5588.
[23]	YUSUF M, KHAN M A, OTERO M , et al.Synthesis of CTAB intercalated graphene and its application for the adsorption of AR265 and AO7 dyes from water. Journal of Colloid & Interface Science, 2017,493:51-61.
[24]	SUI Z Y, MENG Y N, XIAO P W , et al.Nitrogen-doped graphene aerogels as efficient supercapacitor electrodes and gas adsorbents. ACS Applied Materials & Interfaces, 2015,7(3):1431-1438.
[25]	SIMON P, GOGOTSI Y . Materials for electrochemical capacitors. Nature Materials, 2008,7(11):845-854.
[26]	SUN Y, DANG H F, HUANG N B , et al.Effects of surfactants on the preparation of MnO₂ and its capacitive performance.Journal of Applied Biomaterials & Functional Materials, 2017,15:S7-S12.
[27]	ZHAO M Q, REN C E, LING Z , et al.Flexible MXene/carbon nanotube composite paper with high volumetric capacitance. Advanced Materials, 2015,27(2):339-345.
[28]	PETTONG T, IAMPRASERTKUN P, KRITTAYAVATHANANON A , et al.High-performance asymmetric supercapacitors of MnCo₂O₄ nanofibers and N-doped reduced graphene oxide aerogel.ACS Applied Materials & Interfaces, 2016,8(49):34045-34053.

Manganese Dioxide Morphology on Electrochemical Performance of Ti₃C₂T_x@MnO₂ Composites

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