无机材料学报 ›› 2020, Vol. 35 ›› Issue (7): 759-768.DOI: 10.15541/jim20190401 CSTR: 32189.14.10.15541/jim20190401
所属专题： 生物材料论文精选(2020)
张晓旭1,2,朱东彬1,2,3(
),梁金生1,2
收稿日期:2019-08-09
修回日期:2019-10-02
出版日期:2020-07-20
网络出版日期:2020-01-20
作者简介:张晓旭(1991-), 男, 博士研究生. E-mail: 15202203589@163.com基金资助:
ZHANG Xiaoxu1,2,ZHU Dongbin1,2,3(),LIANG Jinsheng1,2
Received:2019-08-09
Revised:2019-10-02
Published:2020-07-20
Online:2020-01-20
Supported by:摘要：
近年来, 齿科氧化锆陶瓷凭借高强韧性、良好生物相容性和美观自然色泽而成为牙齿临床修复的首选对象, 可用于修复、固定局部义齿和种植牙。然而, 在低温潮湿环境中氧化锆陶瓷易发生t-m相变老化, 服役寿命显著缩短, 严重影响其临床稳定性。本文综述了氧化锆陶瓷低温老化的特点、机制及其老化动力学规律, 并介绍了表征氧化锆低温老化现象的常规技术手段以及光学相干断层扫描、聚焦离子束等新方法; 总结了低温老化行为的主要影响因素以及抗老化措施, 具体可通过调整材料体系、改进加工方式等来增强氧化锆的韧性, 解决其存在的低温老化问题。随着齿科氧化锆陶瓷抗老化性能的提高以及健康功能化的未来需求, 其在齿科修复领域的应用将会越来越广泛。
中图分类号:
张晓旭,朱东彬,梁金生. 齿科氧化锆陶瓷水热稳定性研究进展[J]. 无机材料学报, 2020, 35(7): 759-768.
ZHANG Xiaoxu,ZHU Dongbin,LIANG Jinsheng. Progress on Hydrothermal Stability of Dental Zirconia Ceramics[J]. Journal of Inorganic Materials, 2020, 35(7): 759-768.
图1 氧化锆老化前后的形貌对比[17]
Fig. 1 SEM images of zirconia microstructure (a) without and (b) with LTD, and AFM images of zirconia (c) without and (d) with LTD[17]
图2 (a)氧化锆低温老化过程示意图及其(b)氧空位老化机制[23]
Fig. 2 (a) Schematic views of zirconia LTD process, and (b) oxygen vacancies of LTD mechanism[23]
图3 m-ZrO2晶核的初始尺寸和生长速率理论模型[32]
Fig. 3 Theoretical model of initial dimensions and growth rate of m-ZrO2 nuclei[32] (a) Top view of surface; (b) Cross section view
图4 μ-Raman分析3Y-TZP陶瓷老化动力学[33]
Fig. 4 Ageing kinetics analysis with 3Y-TZP by μ-Raman spectroscopy[33] (a) m-ZrO2 content depth and corresponding optical images; (b)Transformed depth varies with ageing time
图5 老化后3Y-TZP不同入射角的XRD图谱[37]
Fig. 5 XRD profiles for different incidence angles ω in the surface of the 3Y-TZP specimen after LTD test[37]
| Equation | |
|---|---|
| Linear | ${{V}_{\text{m}}}=\frac{I_{\text{m}}^{181}+I_{\text{m}}^{190}}{k(I_{\text{t}}^{147}+\delta I_{\text{t}}^{265})+I_{\text{m}}^{181}+I_{\text{m}}^{190}}$ Clarke and Adar[ Katagiri, et al.[ Lim, et al.[ |
| Power law[ | ${{V}_{\text{m}}}=\sqrt{0.19-\frac{0.13}{\frac{I_{\text{m}}^{181}+I_{\text{m}}^{190}}{I_{\text{t}}^{147}+I_{\text{m}}^{181}+I_{\text{m}}^{190}}-1.01}}-0.56$ |
| Logarithmic[ | ${{V}_{\text{m}}}=0.65+0.39\lg \left( \frac{I_{\text{m}}^{181}+I_{\text{m}}^{190}}{I_{\text{t}}^{147}+I_{\text{t}}^{265}+I_{\text{m}}^{181}+I_{\text{m}}^{190}} \right)$ |
表1 基于拉曼光谱的单斜相定量分析模型
Table 1 Proposed models for monoclinic phase quantification by Raman spectroscopy
| Equation | |
|---|---|
| Linear | ${{V}_{\text{m}}}=\frac{I_{\text{m}}^{181}+I_{\text{m}}^{190}}{k(I_{\text{t}}^{147}+\delta I_{\text{t}}^{265})+I_{\text{m}}^{181}+I_{\text{m}}^{190}}$ Clarke and Adar[ Katagiri, et al.[ Lim, et al.[ |
| Power law[ | ${{V}_{\text{m}}}=\sqrt{0.19-\frac{0.13}{\frac{I_{\text{m}}^{181}+I_{\text{m}}^{190}}{I_{\text{t}}^{147}+I_{\text{m}}^{181}+I_{\text{m}}^{190}}-1.01}}-0.56$ |
| Logarithmic[ | ${{V}_{\text{m}}}=0.65+0.39\lg \left( \frac{I_{\text{m}}^{181}+I_{\text{m}}^{190}}{I_{\text{t}}^{147}+I_{\text{t}}^{265}+I_{\text{m}}^{181}+I_{\text{m}}^{190}} \right)$ |
图6 Y-TZP陶瓷微观形貌[45]
Fig. 6 SEM images of the Y-TZP ceramic[45] (a) before and (b) after LTD
图7 2Y-TZP陶瓷晶粒尺寸[50]
Fig. 7 2Y-TZP ceramic[50] (a) SEM images together with the corresponding grain size distribution, and (b) semi-quantitative Y2O3 distribution
图8 表面氮处理的样品老化后形貌[60]
Fig. 8 Morphologies of samples treated with surface nitrogen after aging[60] (a) LSCM image of N-1600; (b) SEM image of N-1400; AFM images of N-1400 (c) surface and (d) bulk
图9 3Y-0.25Al陶瓷[69]
Fig. 9 3Y-0.25Al ceramic[69] (a) TEM image of grain boundaries; (b) Corresponding Al elemental map
图10 0.05A-TZ/SiO2的样品形貌[74]
Fig.10 0.05A-TZ/SiO2 specimen images of fractured surface[74] (a) TEM image; (b) SEM image
图11 3Y-TZP/SWNT陶瓷中单壁碳纳米管的分布[76]
Fig. 11 SEM images of the SWNT distribution within the 3Y-TZP/SWNT ceramic[76] (a) C1.5-UB; (b) C1.5-UP
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