• 综述 •
吴琼1, 沈炳林2, 张茂华2, 姚方周2, 邢志鹏1, 王轲1
收稿日期:
2024-12-16
修回日期:
2025-02-14
作者简介:
吴 琼(1993-), 男, 博士. E-mail: wu-qiong@mail.tsinghua.edu.cn
基金资助:
WU QIONG1, SHEN Binglin2, ZHANG Maohua2, YAO Fangzhou2, XING Zhipeng1, WANG Ke1
Received:
2024-12-16
Revised:
2025-02-14
About author:
WU Qiong (1993-), male, PhD. E-mail: wu-qiong@mail.tsinghua.edu.cn
Supported by:
摘要: 铅基织构压电陶瓷因其制备成本远低于单晶且性能显著高于非织构压电陶瓷,被视为最有潜力的PZT多晶陶瓷替代者,成为近年来材料领域的重点研究课题。基于过去数十年的研究进展,本文详细介绍了铅基织构压电陶瓷的生长原理与表征方法、模板的制备工艺与铅基织构压电陶瓷制备过程中的关键工艺。进而全面汇总了具有代表性的铅基织构压电陶瓷研究成果,讨论了不同改进策略的特点。从材料配方的角度来看,三元体系与二元体系织构压电陶瓷的各组分比例通常选择在相界处,以促进各极性态在外电场下较易翻转进而获得高的压电系数。虽然两种体系的压电系数d33接近,但三元体系的居里温度普遍高于二元体系,体现出更高的应用价值。从烧结等制备工艺的角度看,添加助烧剂可以显著促进晶粒定向生长,后退火处理可以消除晶界和孔洞缺陷内的杂相,淬火处理可以使电偶极子从无序状态中固定。这些工艺的改善都显著增强了铅基织构压电陶瓷的性能。最后,本文分析了目前存在的问题与发展的挑战,认为模板与基体材料在晶格参数和B位离子价态的差异是限制铅基织构压电陶瓷性能提升的主要原因,对不同基体材料定制匹配性好的模板将有助于进一步改善其性能。
中图分类号:
吴琼, 沈炳林, 张茂华, 姚方周, 邢志鹏, 王轲. 铅基织构压电陶瓷研究进展[J]. 无机材料学报, DOI: 10.15541/jim20240520.
WU QIONG, SHEN Binglin, ZHANG Maohua, YAO Fangzhou, XING Zhipeng, WANG Ke. Research Progress on Lead-Based Textured Piezoelectric Ceramics[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20240520.
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