无机材料学报

• 综述 •    

铅基织构压电陶瓷发展历程、现状与挑战

吴杰1,2, 杨帅1, 王明文1, 李景雷1, 李纯纯1, 李飞1   

  1. 1.西安交通大学 电子科学与工程学院, 电子陶瓷与器件教育部重点实验室, 西安 710049;
    2.西安工业大学 材料与化工学院, 陕西省光电功能材料与器件重点实验室, 西安 710021
  • 收稿日期:2024-12-23 修回日期:2025-02-05
  • 作者简介:吴 杰(1989-), 男, 博士, 副教授 E-mail: hitwujie@163.com
  • 基金资助:
    国家自然科学基金(52325205, 52302154),陕西省重点研发技术项目(2024PT-ZCK-14)

Development and Challenge of Textured PT-based Piezoelectric Ceramics

WU Jie1,2, YANG Shuai1, WANG Mingwen1, LI Jinglei1, LI Chunchun1, LI Fei1   

  1. 1. Key Laboratory of the Ministry of Education, School of Electronic Science and Engineering, Xi’an Jiaotong University, Xi'an 710049, China;
    2. Shaanxi Key Laboratory of Photoelectric Functional Materials and Devices, School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, China
  • Received:2024-12-23 Revised:2025-02-05
  • About author:WU Jie (1989-), male, PhD, associated professor. E-mail: hitwujie@163.com
  • Supported by:
    National Natural Science Foundation of China (52325205, 52302154), the Key R&D Project of Shaanxi (2024PT-ZCK-14)

摘要: 压电材料是一种重要的信息功能材料,能够实现机械能与电能之间的相互转化。近年来,织构压电陶瓷技术已经成为研发新一代高性能压电材料的重要途径。通过调控晶粒的取向排布,织构压电陶瓷表现出类似压电单晶的优异压电性能和机电性能,并具有良好的温度稳定性。同时,作为多晶陶瓷,织构陶瓷保留了传统陶瓷材料的制备加工简单、机械性能良好及适用共型异性等优点。本文围绕钛酸铅基压电材料体系,从压电织构陶瓷制备技术、织构用模板籽晶以及织构压电陶瓷技术的发展历程和研究现状等方面,对相关研究结果进行系统梳理,总结压电织构陶瓷技术优势。在此基础上,分析了铅基织构压电陶瓷研究在模板筛选理论、织构陶瓷微观结构和宏观性能间的构性关系,以及基于织构压电陶瓷的压电器件开发等方面存在的科学难题和未来挑战。本文旨在全面介绍织构压电陶瓷技术和理论,帮助研究者深入认识织构压电陶瓷技术,推动高性能压电陶瓷研发和制备技术发展,进而助力我国高端压电器件的创新和跨越发展。

关键词: 织构陶瓷, 铅基压电材料, 模板籽晶生长法, 片状微晶模板, 综述

Abstract: Piezoelectric materials, which serve as converters between mechanical energy and electric energy, are important functional materials. Recently, the technology for textured piezoelectric ceramics has become an important technical approach for developing the next generation of high-performance piezoelectric materials. By tailoring grain orientation, textured piezoelectric ceramics exhibit properties akin to single crystals, exhibiting enhanced piezoelectric and electromechanical properties, as well as improved thermal stability. Furthermore, the polycrystalline nature of textured ceramics inherits the advantages of traditional ceramic materials, including ease of fabrication, favorable mechanical properties, and suitability of special-shape and syntype. This paper provides a brief introduction of texturing technique, development of perovskite templates for textured ceramics and research results related to lead titanate based textured piezoelectric ceramics. It systematically combs the development and status of the piezoelectric texture ceramicswhile summarizing the technical advantages of piezoelectric texture ceramics. Additionally, the existing scientific problems and future challenges of PT-based textured piezoelectric ceramics are analyzed, focusing on the suitability of templates and matrix via theoretical prediction, the relationship between microstructure and macroscopic properties of textured ceramics, and piezoelectric devices based on textured piezoelectric ceramics. By reviewing the PT-based texture piezoelectric ceramics, this paper aims to provide an in-depth introduction to texturing techniques and theories. It seeks to enhance understanding of textured piezoelectric ceramics and promote the development of high-performance piezoelectric materials. In results, it is hoped that this work will benefit to the breakthrough innovation and leap forward development of next generation high-end piezoelectric devices.

Key words: textured ceramics, lead-based piezoelectric materials, templated grain growth, micro-platelet templates, review

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