磷铝酸盐玻璃中铋离子近红外发光与光学碱度反常现象

doi:10.3724/SP.J.1077.2012.00615

无机材料学报 ›› 2012, Vol. 27 ›› Issue (6): 615-619.DOI: 10.3724/SP.J.1077.2012.00615 CSTR: 32189.14.SP.J.1077.2012.00615

磷铝酸盐玻璃中铋离子近红外发光与光学碱度反常现象

宋志国^1,2,3, 李臣¹, 杨正文1^,2,3, 尹兆益^1,2,3, 周大成^1,2,3, 尚吉花¹, 余雪^1,2,3, 邱建备^1,2,3

(昆明理工大学 1. 材料科学与工程学院; 2. 云南省材料制备与加工重点实验室; 3. 稀贵及有色金属先进材料教育部重点实验室, 昆明 650093)

收稿日期:2011-07-12 修回日期:2011-09-07 出版日期:2012-06-20 网络出版日期:2012-05-07
作者简介:宋志国(1977-), 男, 博士, 副教授. E-mail: songzg@kmust.edu.cn
基金资助:
973计划(2011CB211700); 云南省自然科学基金(2009CC009、2008027E)

Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass

SONG Zhi-Guo^1,2,3, LI Chen¹,YANG Zheng-Wen^1,2,3, YIN Zhao-Yi^1,2,3, ZHOU Da-Cheng^1,2,3, SHANG Ji-Hua¹, YU Xue^1,2,3, QIU Jian-Bei^1,2,3

(1. School of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Key Lab of materials of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China; 3. Key Lab of Advanced Materials in Rare & Precious and Nonferrous Metals (Kunming University of Science and Technology), Ministry of Education, Kunming 650093, China)

Received:2011-07-12 Revised:2011-09-07 Published:2012-06-20 Online:2012-05-07
About author:SONG Zhi-Guo. E-mail: songzg@kmust.edu.cn
Supported by:
973 Program (2011CB211700); Natural Science Foundation of Yunnan Province (2009CC009, 2008027E)

摘要/Abstract

摘要： 研究了铋离子掺杂磷铝酸盐玻璃近红外发光与光学碱度的反常现象. 研究发现, 通过改变碱金属离子半径调节玻璃基质光学碱度, 在808 nm激光激发下铋离子位于1300 nm波段的近红外宽带发光强度随光学碱度的增大而增强, 而在690 nm激光激发下得到的1100 nm波段近红外发光强度则随着光学碱度的增大而减弱. 该玻璃1300 nm波段近红外发光强度与光学碱度依存关系与以往报道结果相反, 且也与1100 nm波段发光特性相反. 根据上述结果可以推测玻璃中1100和1300 nm波段的近红外发光源于不同价态的铋离子, 而该玻璃体系的基质结构自还原作用是导致上述现象产生的主要原因.

关键词: 铋掺杂, 近红外, 超宽带, 光学碱度, 玻璃

Abstract: The effect of optical basicity on near infrared (NIR) luminescence properties of bismuth-doped aluminophosphate glasses was investigated. The result show that with increase in the radius of alkali metal ions in glass host, the intensity of NIR emission band at about 1300 nm from Bi ions increases, while the intensity of NIR emission band at 1100 nm decreases. The dependence of intensity of NIR emission band at 1300 nm on the optical basicity of glass host is found to be opposite to those in previous reports as well as to that of NIR emission band at 1100 nm. The infrared emissions peaked at 1100 and 1300 nm may originate from different valent Bi ion, and the relationship between optical basicity and infrared luminescence of bismuth-doped aluminophosphate glasses can be due to the reduction effect of glass matrix.

Key words: bismuth doped, infrared fluorescence, optical basicity, glass

中图分类号:

TQ174

宋志国, 李臣, 杨正文, 尹兆益, 周大成, 尚吉花, 余雪, 邱建备. 磷铝酸盐玻璃中铋离子近红外发光与光学碱度反常现象[J]. 无机材料学报, 2012, 27(6): 615-619.

SONG Zhi-Guo, LI Chen,YANG Zheng-Wen, YIN Zhao-Yi, ZHOU Da-Cheng, SHANG Ji-Hua, YU Xue, QIU Jian-Bei. Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass[J]. Journal of Inorganic Materials, 2012, 27(6): 615-619.

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磷铝酸盐玻璃中铋离子近红外发光与光学碱度反常现象

Abnormal Relationship between Optical Basicity and Infrared Luminescence Properties of Bismuth-doped Aluminophosphate Glass

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