深海服役环境下碳化硅陶瓷材料的腐蚀及磨损行为

doi:10.15541/jim20240536

无机材料学报

• 研究论文 •

深海服役环境下碳化硅陶瓷材料的腐蚀及磨损行为

王鲁杰^1,3,4,5, 张玉新³, 李彤阳^1,3,4,5, 于源^1,3,4,5, 任鹏伟¹, 王建章¹, 汤华国^1,3,4,5, 姚秀敏², 黄毅华², 刘学建², 乔竹辉^1,3,4,5

1.中国科学院兰州化学物理研究所, 固体润滑国家重点实验室,兰州 730000;
2.中国科学院上海硅酸盐研究所, 关键陶瓷材料全国重点实验室,上海 200050;
3.烟台先进材料与绿色制造山东省实验室, 烟台 264006;
4.烟台中科先进材料与绿色化工产业技术研究院, 烟台 264006;
5.青岛资源化学与新材料研究中心,青岛 266100

收稿日期:2024-12-25 修回日期:2025-02-20
作者简介:王鲁杰(1990-), 男, 副研究员. E-mail: ljwang@licp.cas.cn
基金资助:
国家重点研发计划(2022YFB3706204); 关键陶瓷材料重点实验室开放课题(SKL202405SIC); 山东省基金项目 (ZR2021JQ20); 甘肃省青年科学基金 (23JRRA598)

Corrosion and Wear Behavior of Silicon Carbide Ceramic in Deep-sea Service Environment

WANG Lujie^1,3,4,5, ZHANG Yuxin³, LI Tongyang^1,3,4,5, YU Yuan^1,3,4,5, REN Pengwei¹, WANG Jianzhang¹, TANG Huaguo^1,3,4,5, YAO Xiumin², HUANG Yihua², LIU Xuejian², QIAO Zhuhui^1,3,4,5

1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
2. State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;
3. Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai 264006, China;
4. Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering, Yantai 264006, China;
5. Qingdao Center of Resource Chemistry & New Materials, Qingdao 266100, China;

Received:2024-12-25 Revised:2025-02-20
About author:WANG Lujie(1990-), male, associate professor. E-mail: ljwang@licp.cas.cn
Supported by:
National Key Technology R&D Program of China (2022YFB3706204); the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructures (SKL202405SIC); Shandong Provincial Natural Science Foundation (ZR2021JQ20); Youth Science Foundations of Gansu Province (23JRRA598)

摘要/Abstract

摘要： 深水轴系密封材料是制约深水装置发展水平的关键核心技术。碳化硅(SiC)陶瓷材料因其高模量、高热导率、低密度、耐腐蚀等特点成为新一代深海密封材料。深海环境下巨大的海水压力导致材料的腐蚀和磨损过程与常压相比差异较大,而关于深海环境下SiC陶瓷材料的腐蚀磨损过程研究尚未有相关报道。本研究通过改变人工海水静压力的方式模拟0~5 km深海环境,原位分析表征深海环境下SiC陶瓷材料的腐蚀和磨损行为,探索深海静压力对SiC陶瓷腐蚀和磨损的影响规律。SiC陶瓷材料在0~5 km深海环境中表现出十分优异的耐腐蚀行为,200 h浸泡后材料表面没有观察到明显腐蚀、氧化或海水盐类侵蚀行为,也未发生质量损失。随着海深增加,SiC与水之间的化学反应减弱,这进一步增强了其耐腐蚀性能。SiC陶瓷材料经过海水腐蚀后力学性能保持稳定,弯曲强度在5 km海深腐蚀200 h后仅有低于5%的轻微下降,而维氏硬度和断裂韧性均保持不变。在海水润滑条件下,SiC陶瓷材料具有十分优异的耐磨损性能,磨损率为(2~4)×10^-8 mm³/(N·m),远低于与其配副的氮化硅(Si₃N₄)陶瓷材料((4~10)×10^-5mm³/(N·m))。值得一提的是,随着海水深度增加,SiC陶瓷耐水腐蚀能力增强,同时水的润滑承载作用增大,导致SiC陶瓷磨损率随海深增加呈现下降趋势。综上,SiC陶瓷材料在深海密封方面展现出强大的应用潜力。

关键词: 碳化硅, 深海, 腐蚀, 磨损

Abstract: Deepwater shaft sealing materials are one of the critical core technologies limiting the advancement of deepwater equipment. Silicon carbide (SiC) ceramics, due to their outstanding high modulus, high thermal conductivity, low density, and excellent corrosion resistance, have become an ideal choice for next-generation deep-sea sealing materials. The immense seawater pressure in deep-sea environments causes significant differences in corrosion and wear processes compared to conventional atmospheric pressure conditions. However, research on the corrosion and wear behavior of SiC ceramics in deep-sea environments remains relatively insufficient. In this study, the static pressure of artificial seawater was adjusted to simulate deep-sea conditions at depths ranging from 0 to 5 km. In-situ characterization of the materials’ performance in deep-sea environments was conducted, and the influence of static pressure on their corrosion and wear properties was explored. The results indicated that SiC ceramics exhibited outstanding corrosion resistance in deep-sea environments at depths between 0 and 5 km. After immersion for 200 h, no significant corrosion, oxidation, or seawater salt-related erosion was observed on the material’s surface, and no mass loss occurred. As seawater depth increased, the chemical reaction between SiC and water gradually weakened, further enhancing the corrosion resistance of SiC ceramics. After seawater corrosion, the mechanical properties of SiC ceramics remained stable. The flexural strength of the material decreased by less than 5% after 200 h-corrosion in a 5 km deep-sea environment, and whether Vickers hardness or fracture toughness has little changes. Under seawater lubrication conditions, SiC ceramics exhibited excellent wear resistance, with a wear rate of (2-4)×10^-8 mm³/(N·m), much lower than that of the paired silicon nitride (Si₃N₄) ceramic material ((4-10)×10^-5 mm³/(N·m)). Notably, as seawater depth increased, both the material’s resistance to water corrosion and the lubricating load-bearing capacity of seawater were significantly enhanced, leading to a decrease in the wear rate with increasing depth. In conclusion, SiC ceramics demonstrate significant potential for application in deep-sea sealing technologies.

Key words: silicon carbide, deep sea, corrosion, wear

中图分类号:

TQ174

王鲁杰, 张玉新, 李彤阳, 于源, 任鹏伟, 王建章, 汤华国, 姚秀敏, 黄毅华, 刘学建, 乔竹辉. 深海服役环境下碳化硅陶瓷材料的腐蚀及磨损行为[J]. 无机材料学报, DOI: 10.15541/jim20240536.

WANG Lujie, ZHANG Yuxin, LI Tongyang, YU Yuan, REN Pengwei, WANG Jianzhang, TANG Huaguo, YAO Xiumin, HUANG Yihua, LIU Xuejian, QIAO Zhuhui. Corrosion and Wear Behavior of Silicon Carbide Ceramic in Deep-sea Service Environment[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20240536.

参考文献

[1] BORCHERS A, PIELER T.Programming pluripotent precursor cells derived from Xenopus embryos to generate specific tissues and organs.Genes, 2010, 1(3): 413.
[2] SHEN C, KHONSARI M M, SPADAFORA M,et al. Tribological performance of polyamide-imide seal ring under seawater lubrication. Tribology Letters, 2016, 62(3): 39.
[3] SHANKAR S, KRISHNA KUMAR P.Frictional characteristics of diamond like carbon and tungsten carbide/carbon coated high carbon high chromium steel against carbon in dry sliding conformal contact for mechanical seals.Mechanics & Industry, 2017, 18(1): 115.
[4] PEREIRA P, VILHENA L M, SACRAMENTO J,et al. Tribological behaviour of different formulations of WC composites. Wear, 2022, 506: 204415.
[5] YAO X M, WANG X J, LIU X J, et al. Friction-wear properties and mechanism of hard facing pairs of SiC and WC. Journal of Inorganic Materials, 2019, 34(6): 673.
[6] CHEN Q, BAI S X, YE Y C.Highly thermal conductive silicon carbide ceramics matrix composites for thermal management: a review.Journal of Inorganic Materials, 2023, 38(6): 634.
[7] RAMASUBRAMANIAN K, NIKHIL C, RAO S,et al. Tribological behavior of diamond coated reaction-bonded silicon carbide under dry and seawater environment. Surface and Coatings Technology, 2024, 476: 130204.
[8] GUO X Z, WANG R, ZHENG P,et al. Pressureless sintering of multilayer graphene reinforced silicon carbide ceramics for mechanical seals. Advances in Applied Ceramics, 2019, 118(7): 409.
[9] CAI N N, GUO D D, WU G P,et al. Decreasing resistivity of silicon carbide ceramics by incorporation of graphene. Materials, 2020, 13(16): 3586.
[10] DIAO Q W, ZOU H B, REN X Y,et al. A focused review on the tribological behavior of C/SiC composites: present status and future prospects. Journal of the European Ceramic Society, 2023, 43(9): 3875.
[11] ZHANG W, YAMASHITA S, KITA H.Progress in tribological research of SiC ceramics in unlubricated sliding-a review.Materials & Design, 2020, 190: 108528.
[12] ZHANG W.Tribology of SiC ceramics under lubrication: features, developments, and perspectives.Current Opinion in Solid State and Materials Science, 2022, 26(4): 101000.
[13] YAMAMOTO Y, URA A.Influence of interposed wear particles on the wear and friction of silicon carbide in different dry atmospheres.Wear, 1992, 154(1): 141.
[14] PRESSER V, KRUMMHAUER O, NICKEL K G,et al. Tribological and hydrothermal behaviour of silicon carbide under water lubrication. Wear, 2009, 266(7/8): 771.
[15] MATSUDA M, KATO K, HASHIMOTO A.Friction and wear properties of silicon carbide in water from different sources.Tribology Letters, 2011, 43(1): 33.
[16] REN P W, MENG H M, XIA Q J,et al. Tribocorrosion of 316L stainless steel by in situ electrochemical methods under deep-sea high hydrostatic pressure environment. Corrosion Science, 2022, 202: 110315.
[17] REN P W, MENG H M, XIA Q J,et al. Influence of seawater depth and electrode potential on the tribocorrosion of Ti6Al4V alloy under the simulated deep-sea environment by in situ electrochemical technique. Corrosion Science, 2021, 180: 109185.
[18] REN P W, MENG H M, XIA Q J,et al. Study on the tribocorrosion behavior of Cu-Ni-Zn alloy in deep-sea environment by in situ electrochemical method. Wear, 2023, 514: 204594.
[19] VERICHEV S N, MISHAKIN V V, NUZHDIN D A,et al. Experimental study of abrasive wear of structural materials under the high hydrostatic pressure. Ocean Engineering, 2015, 99: 9.
[20] MISHAKIN V V, VERICHEV S N, RAZOV E N.Investigation of the influence of high hydrostatic pressure on the abrasive wear of hard-alloy materials.Journal of Friction and Wear, 2017, 38(4): 286.
[21] WANG J Z, CHEN J, CHEN B B,et al. Wear behaviors and wear mechanisms of several alloys under simulated deep-sea environment covering seawater hydrostatic pressure. Tribology International, 2012, 56: 38.
[22] WANG L J, QIAO Z H, QI Q,et al. Improving abrasive wear resistance of Si₃N₄ ceramics with self-matching through tungsten induced tribochemical wear. Wear, 2022, 494: 204254.
[23] FENG D, QIN Z B, REN Q X,et al. Occurrence forms of major impurity elements in silicon carbide. Ceramics International, 2022, 48(1): 205.
[24] XIANG D D, HE Q C, LAN D,et al. Regulating the phase composition and microstructure of Fe₃Si/SiC nanofiber composites to enhance electromagnetic wave absorption. Chemical Engineering Journal, 2024, 498: 155406.
[25] KIM W, LIM S H, HONG H,et al. Optimum boundaries for maximum load-carrying capacity in water-lubricated composite journal bearings incorporating turbulences and inertial effects based on elastohydrodynamic analysis. Journal of Computational Design and Engineering, 2022, 9(6): 2506.
[26] ZHANG X L, YIN Z W, JIANG D,et al. The design of hydrodynamic water-lubricated step thrust bearings using CFD method. Mechanics & Industry, 2014, 15(3): 197.
[27] WANG X L, ADACHI K, OTSUKA K,et al. Optimization of the surface texture for silicon carbide sliding in water. Applied Surface Science, 2006, 253(3): 1282.

深海服役环境下碳化硅陶瓷材料的腐蚀及磨损行为

Corrosion and Wear Behavior of Silicon Carbide Ceramic in Deep-sea Service Environment

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