Preparation, Properties and Application Prospects of Ferroelectic Nanomaterials

Abstract

Abstract: The preparation, structure and properties of ferroelectric nanometer sized powders, nanocomposites, and nanoceramics were introduced. The change of structure and properties caused by the reduction
of particle size and pertinent mechanisms were discussed. Transparent nanocomposites were expected to be applied as the optical memories, optical computer, etc devices, while the nanoceramics can be
widely used to improve the characteristic parameters of current capacitors due to the greatly enhanced dielectric permittivity, breakdown voltage, ageing-resistivity, mechanical strength, etc. Better quality
of devices will be obtained by using the nanosized powders.

Key words: ferroelectrics, nanopowder, nanoceramic, nanocomposite, size effect, dielectric properties

CLC Number:

TM22

LU Sheng-Guo,LI Biao-Rong,MAK Chee-Leung,WONG Kin-Hung. Preparation, Properties and Application Prospects of Ferroelectic Nanomaterials[J]. Journal of Inorganic Materials.

References

[1] Kanzig W, Helv. Phys. Acta, 1951, 24: 175--216.
[2] Anliker M, Brugger H R, Kanzig W. Helv. Phys. Acta, 1954, 27: 99--124.
[3] Smolensky G A. J. Phys. Soc. Jpn., suppl., 1970, 28: 26--58.
[4] Yao Xi, Chen Zhili, Cross L E. J. Appl. Phys., 1983, 54: 3399--3403.
[5] Wang P C, Chen Z L, He X M, et al. Ferroelectr. Lett., 1985, 4 (2): 47--51.
[6] 姚熹, 张良莹. 物理, 1992, 21 (2): 99--105.
[7] Ishikawa K, Koshikawa K, Okada N. Phys. Rev., 1988, B37 (10): 5852-5855.
[8] Zhong W L, Wang Y G, Zhang P L, et al. Phys. Rev., 1994, B50: 698--703.
[9] Frey M H, Payne D A. Phys. Rev., 1996, B54 (5): 3158--3168.
[10] Chattopadhyay S, Ayyub P, Palkar V R, et al. Phys. Rev., 1995, B52 (18): 13177--13183.
[11] Park Y, Knowles K M, Cho K. J. Appl. Phys., 1998, 83 (11): 5702--5708.
[12] Lu S G, Liu H L, Han Y, et al. Ferroelectr. Lett., 1994, 18: 115--120.
[13] Schlag S, Eicke H F. Solid State Commun., 1994, 91 (11): 883--887.
[14] Shih W Y, Shih W H, Aksay I A. Phys. Rev., 1994, B50 (21): 15575--15585.
[15] Lu S G, Mak C L, Wong K H, J. Am. Ceram. Soc., 2001, 84 (1): 79--84.
[16] Lu S G, Mak C L, Wong K H. Ferroelectrics, 2001, 264: 1733--1738.
[17] Lu S G, Mak C L, Wong K H, et al. J. Harbin Univ. Sci. Tech., 2002, 7 (6): 16--17.
[18] Lu S G, Mak C L, Wong K H. Appl. Phys. Lett., 2001, 79 (26): 4310--4312.
[19] Lu S G, Mak C L, Wong K H. (in preparation).
[20] Glasel H J, Hartmann E, Hirsch D, et al. J. Mater. Sci., 1999, 34 (10): 2319--2323.
[21] Lu S G, Liu H L, Han Y, et al. Ferroelectrics, 1997, 197: 679--682.
[22] Naka S, Nakakita F, Suwa Y, et al. Bull. Chem. Soc. Jpn., 1974, 47: 1168--1171.
[23] Hsiang H I, Yen F S. J. Am. Ceram. Soc., 1996, 79: 1053--1060.
[24] Uchino K, Sadanaga E, Hirose T. J. Am. Ceram. Soc., 1989, 72 (8): 1555--1558.
[25] Park Y, Lee W J, Kim H G. J. Phys. Condense. Matter., 1997, 9: 9445--9456.
[26] McCauley D, Newnham R E, Randall C A. J. Am. Ceram. Soc., 1998, 81 (4): 979--987.
[27] Newnham R E, Bowen L J, et al. Mater. in Eng., 1980, 2: 93--106.
[28] Newnham R E, Skinner D P, Cross L E. Mater. Res. Bull., 1978, 13: 525--536.
[29] Newnham R E. Ann. Rev. Mater. Sci., 1986, 16: 47--68.
[30] Newnham R E. Adv. Ceram. Mater., 1988, 3 (1): 12--16.
[31] Lu S G, Mak C. L, Wong K H. J. Appl. Phys., 2003, 94 (5): 3422--3426.
[32] 李标荣.电子陶瓷工艺原理. 武汉: 华中理工大学出版社, 1986, 1994. 59--141.
[33] 李标荣, 王筱珍, 张绪礼.无机电介质. 武汉: 华中理工大学出版社, 1995. 86--94.
[34] Akdogan E K, Leonard M R, and SafariA. In: Nalwa H S, ed. Handbook of Low and High Dielectric
Constant Materials and Their Applications, Volume 2: Phenomena, Properties, and Applications. San Diego: Academic Press, San Diego, 1999. 61--112.