Journal of Inorganic Materials ›› 2021, Vol. 36 ›› Issue (6): 592-600.DOI: 10.15541/jim20200266
• REVIEW • Previous Articles Next Articles
LI Tingting1,2(
), ZHANG Zhiming1, HAN Zhengbo2(
)
Received:2020-05-15
Revised:2020-07-09
Published:2021-06-20
Online:2020-08-28
Contact:
HAN Zhengbo, professor. E-mail: ceshzb@lnu.edu.cn
About author:LI Tingting(1980-), female, PhD. E-mail: litingting2046@163.com
Supported by:CLC Number:
LI Tingting, ZHANG Zhiming, HAN Zhengbo. Research Progress in Polymer-based Metal-organic Framework Nanofibrous Membranes Based on Electrospinning[J]. Journal of Inorganic Materials, 2021, 36(6): 592-600.
Fig. 3 (a) Preparation method and formation mechanism of the in situ ZIF-8/PAN fibers[22]; (b) Scheme of in situ growth of UiO-66-NH2 on PAN NFM[23]; (c) Fabrication process of ZIF-8, MIL-88B(Fe), HKUST-1 and MIL-53(Al) NFMs[25]
Fig. 7 (a) CO2 adsorption isotherms and CO2/N2 adsorption selectivity of PAN/ZIF-8 NFMs[33], (b) selective adsorption of cationic dyes by bio-MOF/PAN filter[37], and (c) adsorption mechanism of Cu(II) and Cr(VI) on the ZIF-67/CA NFM surface[39]
Fig. 8 (a) Possible mechanism of photocatalytic degradation of MB on PLA/ZIF-8@GO fibers[41], and (b) illustration of UiO-66-NH2 NFM used for protection against toxic industrial chemicals and chemical warfare agents[42]
Fig. 10 (a) Proton conductive process of oriented electrospun nanofiber and HRTEM image of cross-sectional aligned nanofiber[55], and (b) antibacterial activities of CS-PEO and CS-PEO-3% ZIF-8 NFMs[56]
| [1] |
KALAJ M, BENTZ K C, AYALA JR S, et al. MOF-polymer hybrid materials: from simple composites to tailored architectures. Chemical Reviews, 2020,120(16):8267-8302.
DOI URL |
| [2] |
ZHANG Y, YUN S, FENG X, et al. Preparation of nanofibrous metal-organic framework filters for efficient air pollution control. Journal of the American Chemical Society, 2016,138(18):5785-5788.
DOI URL |
| [3] |
ZHAO J, LEE D T, YAGA R W, et al. Ultra-fast degradation of chemical warfare agents using MOF-nanofiber kebabs. Angewandte Chemie International Edition, 2016,55(42):13224-13228.
DOI URL |
| [4] | ZHANG Y, GUAN J, WANG X, et al. Balsam-pear-skin-like porous polyacrylonitrile nanofibrous membranes grafted with polyethyleneimine for postcombustion CO2 capture. ACS Applied Materials & Interfaces, 2017,9(46):41087-41098. |
| [5] |
WANG C, LIU C, LI J, et al. Electrospun metal-organic framework derived hierarchical carbon nanofibers with high performance for supercapacitors. Chemical Communications, 2017,53(10):1751-1754.
DOI URL |
| [6] | ZHANG Y, ZHANG Y, WANG X, et al. Ultrahigh metal-organic framework loading and flexible nanofibrous membranes for efficient CO2 capture with long-term, ultrastable recyclability. ACS Applied Materials & Interfaces, 2018,10(40):34802-34810. |
| [7] | GIBSON P, SCHREUDER-GIBSON H, RIVIN D. Transport properties of porous membranes based on electrospun nanofibers. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 187-188:469-481. |
| [8] |
CENTRON A, YANGA Y, SPEAKMAN S, et al. Growth of metal-organic frameworks on polymer surfaces. Journal of the American Chemical Society, 2010,132(44):15687-15691.
DOI URL |
| [9] |
OSTERMANN R, CRAVILLON J, WEIDMANN C, et al. Metal- organic framework nanofibers via electrospinning. Chemical Communications, 2011,47(1):442-444.
DOI URL |
| [10] |
LAURILA E, THUNBERG J, ARGENT S P, et al. Enhanced synthesis of metal-organic frameworks on the surface of electrospun cellulose nanofibers. Advanced Engineering Materials, 2015,17(9):1282-1286.
DOI URL |
| [11] |
ROSE M, BOHRINGER B, JOLLY M, et al. MOF processing by electrospinning for functional textiles. Advanced Engineering Materials, 2011,13(4):356-360.
DOI URL |
| [12] |
LIAN Z, HUIMIN L, ZHAOFEI O. In situ crystal growth of zeolitic imidazolate frameworks (ZIF) on electrospun polyurethane nanofibers. Dalton Transactions, 2014,43(18):6684-6688.
DOI URL |
| [13] |
ARMSTRONG M R, SHAN B, MARINGANTI S V, et al. Hierarchical pore structures and high ZIF-8 loading on matrimid electrospun fibers by additive removal from a blended polymer precursor. Industrial & Engineering Chemistry Research, 2016,55(37):9944-9951.
DOI URL |
| [14] | AN S, LEE J S, JOSHI B N, et al. Freestanding fiber mats of zeolitic imidazolate framework 7 via one-step, scalable electrospinning. Journal of Applied Polymer Science, 2016,133(32):43788. |
| [15] |
ISMAIL F M, ABDELLAH A M, ALI P A, et al. Bilayer sandwich-like membranes of metal organic frameworks electrospun polymeric nanofibers via SiO2 nanoparticles seeding. Materials Today Communications, 2017,12:119-124.
DOI URL |
| [16] | HAO Z, WU J, WANG C, et al. Electrospun polyimide/metal- organic framework nanofibrous membrane with superior thermal stability for efficient PM2.5 capture. ACS Applied Materials & Interfaces, 2019,11(12):11904-11909. |
| [17] | EFOME J E, RANA D, MATSUURA T, et al. Insight studies on metal-organic framework nanofibrous membrane adsorption and activation for heavy metal ions removal from aqueous solution. ACS Applied Materials & Interfaces, 2018,10(22):18619-18629. |
| [18] |
EFOME J E, RANA D, MATSUURA T, et al. Experiment and modeling for flux and permeate concentration of heavy metal ion in adsorptive membrane filtration using a metal-organic framework incorporated nanofibrous membrane. Chemical Engineering Journal, 2018,352:737-744.
DOI URL |
| [19] |
EFOME J E, RANA D, MATSUURA T, et al. Metal-organic frameworks supported on nanofibers to remove heavy metals. Journal of Materials Chemistry A, 2018,6(10):4550-4555.
DOI URL |
| [20] | SHOOTO N D, WANKASI D, SIKHWVHILU C, et al. Novel super adsorbents (PVA and PVA/Cu-MOF nanofibres) as effective lead ions remover in aqueous solution. Dig. J. Nanomater. Biostruct., 2016,11:425-434. |
| [21] |
SHOOTO N D, DIKIO C W, WANKASI D, et al. Novel PVA/MOF nanofibres: fabrication, evaluation and adsorption of lead ions from aqueous solution. Nanoscale Research Letters, 2016,11(1):1-13.
DOI URL |
| [22] | WANG C, ZHENG T, LUO R, et al. In situ growth of ZIF-8 on PAN fibrous filters for highly efficient U(VI) removal. ACS Applied Materials & Interfaces, 2018,10(28):24164-24171. |
| [23] |
LU A X, PLOSKONKA A M, TOVAR T M, et al. Direct surface growth of UIO-66-NH2 on polyacrylonitrile nanofibers for efficient toxic chemical removal. Industrial & Engineering Chemistry Research, 2017,56(49):14502-14506.
DOI URL |
| [24] |
LI Z, ZHOU G, DAI H, et al. Biomineralization-mimetic preparation of hybrid membranes with ultra-high loading of pristine metal-organic frameworks grown on silk nanofibers for hazard collection in water. Journal of Materials Chemistry A, 2018,6(8):3402-3413.
DOI URL |
| [25] | LIU C, WU Y N, MORLAY C, et al. General deposition of metal-organic frameworks on highly adaptive organic-inorganic hybrid electrospun fibrous substrates. ACS Applied Materials & Interfaces, 2016,8(4):2552-2561. |
| [26] |
GAO M, ZENG L, NIE J, et al. Polymer-metal-organic framework core-shell framework nanofibers via electrospinning and their gas adsorption activities. RSC Advances, 2016,6(9):7078-7085.
DOI URL |
| [27] |
WU Y N, LI F, LIU H, et al. Electrospun fibrous mats as skeletons to produce free-standing MOF[ membranes. Journal of Materials Chemistry, 2012,22(33):16971-16978.
DOI URL |
| [28] |
BECHELANY M, DROBEK M, VALLICARI C, et al. Highly crystalline MOF-based materials grown on electrospun nanofibers. Nanoscale, 2015,7(13):5794-5802.
DOI URL |
| [29] | DWYER D B, LEE D T, BOYER S, et al. Toxic organophosphate hydrolysis using nanofiber-templated UIO-66-NH2 metal-organic framework polycrystalline cylinders. ACS Applied Materials & Interfaces, 2018,10(30):25794-25803. |
| [30] |
ZHOU M, LI J, ZHANG M, et al. A polydopamine layer as the nucleation center of MOF deposition on “inert” polymer surfaces to fabricate hierarchically structured porous films. Chemical Communications, 2015,51(13):2706-2709.
DOI URL |
| [31] |
FAN L, XUE M, KANG Z, et al. Electrospinning technology applied in zeolitic imidazolate framework membrane synthesis. Journal of Materials Chemistry, 2012,22(48):25272-25276.
DOI URL |
| [32] |
ARMSTRONG M, SIROU P, SHAN B, et al. Prolonged HKUST-1 functionality under extreme hydrothermal conditions by electrospinning polystyrene fibers as a new coating method. Microporous and Mesoporous Materials, 2018,270:34-39.
DOI URL |
| [33] |
CHOI C, KADAM R L, GAILWAD S, et al. Metal organic frameworks immobilized polyacrylonitrile fiber mats with polyethyleneimine impregnation for CO2 capture. Microporous and Mesoporous Materials, 2020,296:110006.
DOI URL |
| [34] |
FAN X, YU L, LI L, et al. Characterization and application of zeolitic imidazolate framework-8@polyvinyl alcohol nanofibers mats prepared by electrospinning. Materials Research Express, 2017,4(2):026404.
DOI URL |
| [35] |
ZHAN Y, GUAN X, REN E, et al. Fabrication of zeolitic imidazolate framework-8 functional polyacrylonitrile nanofibrous mats for dye removal. Journal of Polymer Research, 2019,26(6):145.
DOI URL |
| [36] |
ZHAO R, TIAN Y, LI S, et al. An electrospun fiber based metal-organic framework composite membrane for fast, continuous, and simultaneous removal of insoluble and soluble contaminants from water. Journal of Materials Chemistry A, 2019,7(39):22559-22570.
DOI URL |
| [37] | LI T, LIU L, ZHANG Z, et al. Preparation of nanofibrous metal-organic framework filter for rapid adsorption and selective separation of cationic dye from aqueous solution. Separation and Purification Technology, 2020,237:116360. |
| [38] |
JAMSHIDIFARD S, KOUSHKBAGHI S, HOSSEINI S, et al. Incorporation of UIO-66-NH2 MOF into the PAN/chitosan nanofibers for adsorption and membrane filtration of Pb(II), Cd(II) and Cr(VI) ions from aqueous solutions. Journal of Hazardous Materials, 2019,368:10-20.
DOI URL |
| [39] | HOU X, ZHOU H, ZHANG J, et al. High adsorption pearl-necklace-like composite membrane based on metal-organic framework for heavy metal ion removal. Particle & Particle Systems Characterization, 2018,35(6):1700438. |
| [40] |
LEUS K, KRISHNARAJ C, VERHOEVEN L, et al. Catalytic carpets: Pt@MIL-101@electrospun PCL, a surprisingly active and robust hydrogenation catalyst. Journal of Catalysis, 2018,360:81-88.
DOI URL |
| [41] |
DAI X, LI X, ZHANG M, et al. Zeolitic imidazole framework/ graphene oxide hybrid functionalized poly (lactic acid) electrospun membranes: A promising environmentally friendly water treatment material. ACS Omega, 2018,3(6):6860-6866.
DOI URL |
| [42] | LU A X, MCENTEE M, BROWE M A, et al. Mofabric: electrospun nanofiber mats from PVDF/UIO-66-NH2 for chemical protection and decontamination. ACS Applied Materials & Interfaces, 2017,9(15):13632-13636. |
| [43] | PETERSON G W, LU A X, EPPS T H. Tuning the morphology and activity of electrospun polystyrene/UIO-66-NH2 metal-organic framework composites to enhance chemical warfare agent removal. ACS Applied Materials & Interfaces, 2017,9(37):32248-32254. |
| [44] |
MCCARTHY D L, LIU J, DWYER D B, et al. Electrospun metal-organic framework polymer composites for the catalytic degradation of methyl paraoxon. New Journal of Chemistry, 2017,41(17):8748-8753.
DOI URL |
| [45] |
XU Y, WEN Y, ZHU W, et al. Electrospun nanofibrous mats as skeletons to produce MOF membranes for the detection of explosives. Materials Letters, 2012,87:20-23.
DOI URL |
| [46] |
SHANGGUAN J, BAI L, LI Y, et al. Layer-by-layer decoration of nofs on electrospun nanofibers. RSC Advances, 2018,8(19):10509-10515.
DOI URL |
| [47] |
LI T T, LIU L, GAO M L, et al. A highly stable nanofibrous Eu-MOF membrane as a convenient fluorescent test paper for rapid and cyclic detection of nitrobenzene. Chemical Communications, 2019,55(34):4941-4944.
DOI URL |
| [48] |
ASIABI M, MEHDINIA A, JABBARI A. Preparation of water stable methyl-modified metal-organic framework-5/polyacrylonitrile composite nanofibers via electrospinning and their application for solid-phase extraction of two estrogenic drugs in urine samples. Journal of Chromatography A, 2015,1426:24-32.
DOI URL |
| [49] |
ASIABI M, MEHDINIA A, JABBARI A. Electrospun biocompatible chitosan/MIL-101 (Fe) composite nanofibers for solid-phase extraction of Δ9-tetrahydrocannabinol in whole blood samples using box-behnken experimental design. Journal of Chromatography A, 2017,1479:71-80.
DOI URL |
| [50] |
LIU F, XU H. Development of a novel polystyrene/metal-organic framework-199 electrospun nanofiber adsorbent for thin film microextraction of aldehydes in human urine. Talanta, 2017,162:261-267.
DOI URL |
| [51] |
MEHRAFZA N, SARAZI M. Electrospun polyacrylonitrile-zeolite imidazolate framework-8 nanofibers for the thin-film microextraction of bisphenol A. Separation Science Plus, 2018,1(5):382-388.
DOI URL |
| [52] |
YAN Z, WU M, HU B, et al. Electrospun UIO-66/polyacrylonitrile nanofibers as efficient sorbent for pipette tip solid phase extraction of phytohormones in vegetable samples. Journal of Chromatography A, 2018,1542:19-27.
DOI URL |
| [53] |
ARABORKHI B, SERESHTI H, ABBASI A. Electrospun metal-organic framework/polyacrylonitrile composite nanofibrous mat as a microsorbent for the extraction of tetracycline residue in human blood plasma. Journal of Separation Science, 2019,42(8):1500-1508.
DOI URL |
| [54] | YANG F, EFOME J E, RANA D, et al. Metal-organic frameworks supported on nanofiber for desalination by direct contact membrane distillation. ACS Applied Materials & Interfaces, 2018,10(13):11251-11260. |
| [55] |
WU B, PAN J, GE L, et al. Oriented MOF-polymer composite nanofiber membranes for high proton conductivity at high temperature and anhydrous condition. Scientific Reports, 2014,4:4334.
DOI URL |
| [56] |
KOHSARI I, SHARIATINIA Z, POURMORTAZAVI S M. Antibacterial electrospun chitosan-polyethylene oxide nanocomposite mats containing ZIF-8 nanoparticles. International Journal of Biological Macromolecules, 2016,91:778-788.
DOI URL |
| [57] |
SINGBUMRUNG K, MOTINA K, PISITSAK P, et al. Preparation of Cu-BTC/PVA fibers with antibacterial applications. Fibers and Polymers, 2018,19(7):1373-1378.
DOI URL |
| [58] |
GUO Y, CAO Y, CHEN Z, et al. Fluorinated metal-organic framework as bifunctional filler toward highly improving output performance of triboelectric nanogenerators. Nano Energy, 2020,70:104517.
DOI URL |
| [1] | CHEN Mingjun, MIAO Hongkang, XIAO Yingjun, DENG Jianbo, ZHANG Xiang, ZHAO Jiupeng, LI Yao. Photo- and Thermo-chromic Dual-responsive Materials: A Review on Design Strategies and Applications in Smart Windows [J]. Journal of Inorganic Materials, 2026, 41(6): 723-738. |
| [2] | SONG Kunjie, XIE Rongjun. Research Advances on Machine Learning-driven Development of Novel Luminescent Materials [J]. Journal of Inorganic Materials, 2026, 41(6): 689-703. |
| [3] | HU Yuqing, ZHU Yixin, LE Xianhao, WAN Qing. Lithium Tantalate Wafer: Advances in Thinning Technology and Application in Pyroelectric Infrared Detectors [J]. Journal of Inorganic Materials, 2026, 41(6): 764-774. |
| [4] | LIU Chunfan, CHEN Ke, GE Fangfang, HUANG Qing. Research Progress on Lead-bismuth Eutectic Corrosion Resistant Coatings [J]. Journal of Inorganic Materials, 2026, 41(6): 775-786. |
| [5] | HU Yang, XIE Min, ZHANG Xiaoyi, LI Xiang, GUO Xinwei, JIANG Nan, ZHOU Wenhan, ZHANG Shengli, ZENG Haibo. Research Progress on Computational and Data-driven Environmental-friendly Luminescent Materials [J]. Journal of Inorganic Materials, 2026, 41(6): 704-722. |
| [6] | WANG Junbu, HUANG Zeai, YANG Mingkai, MENG Ying, ZHOU Mingwei, ZHOU Ying. Research Progress on Anti-coking Catalytic Materials for Methane Conversion [J]. Journal of Inorganic Materials, 2026, 41(6): 739-750. |
| [7] | WANG Jinwen, YANG Zhen, ZHOU Huan, XIA Dan, YANG Lei. Biomedical Applications of Injectable Inorganic Biomaterials [J]. Journal of Inorganic Materials, 2026, 41(6): 751-763. |
| [8] | LI Hantao, SHEN Qiang, LUO Guoqiang, WANG Xuefei, GAO Ming, CHEN Chen. Research Progress on Structure and Performance Regulation of Silicon-based Anode Materials via Mechanical Ball Milling [J]. Journal of Inorganic Materials, 2026, 41(5): 561-572. |
| [9] | XIE Chenyi, MIAO Huaming, ZHANG Weiran, LIU Rongjun, WANG Yanfei, LI Duan. Research Progress on Theoretical Calculation in the Field of High-entropy Ceramics [J]. Journal of Inorganic Materials, 2026, 41(5): 545-560. |
| [10] | LI Xuan, YE Kuicai, FENG Jiayin, QIU Jiajun, QIAN Wenhao, XING Min. Surface Modification of Titanium-based Dental Implants for Soft Tissue Sealing: A Review [J]. Journal of Inorganic Materials, 2026, 41(4): 432-444. |
| [11] | PENG Dezhao, LI Rui, WANG Wenhong, WANG Zirui, ZHANG Zhizhen. Research Progress on Sodium Chloride Solid Electrolytes [J]. Journal of Inorganic Materials, 2026, 41(4): 409-420. |
| [12] | CHEN Kun, JIANG Yonggang, FENG Junzong, LI Liangjun, HU Yijie, FENG Jian. Research Progress on Lanthanum Zirconate Porous Materials for Thermal Insulation [J]. Journal of Inorganic Materials, 2026, 41(4): 421-431. |
| [13] | WEI Lianjin, QI Zhijie, WANG Xin, ZHU Junwu, FU Yongsheng. Modification of Nanodiamond and Its Application in Electrocatalytic Oxygen Reduction Reaction [J]. Journal of Inorganic Materials, 2026, 41(3): 273-288. |
| [14] | LIU Zhanyi, LI Mian, OUYANG Xiaoping, CHAI Zhifang, HUANG Qing. Recent Progress on Removal of Sr/Cs from Molten Salt in Dry Reprocessing [J]. Journal of Inorganic Materials, 2026, 41(2): 150-158. |
| [15] | SUN Lian, ZHANG Leilei, XUE Zexu, WU Kun, CHEN Ye, LI Zhiyuan, WANG Lukai, WANG Zungang. Research Progress on Zero-dimensional Metal Halide Scintillators towards Radiation Detection Applications [J]. Journal of Inorganic Materials, 2026, 41(2): 159-176. |
| Viewed | ||||||
|
Full text |
|
|||||
|
Abstract |
|
|||||