Journal of Inorganic Materials

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Investigation of Charge Storage Properties in V2O5 Thin Films

WU Guangming; WU Yonggang; Ni Xingyuan; ZHOU Zhen; ZHANG Huiqin; JIN Zhemin; WU Xiang   

  1. Pohl Institute of Solid State Physics; Tongji University Shanghai 200092 China
  • Received:1996-05-27 Revised:1996-07-01 Published:1997-08-20 Online:1997-08-20

Abstract: Lithium was inserted electrochemically from an electrolyte into V2O5 thin films prepared by evaporation and posttreated at different temperatures in air
so that LixV2O5 was obtained. Li+ storage properties, reversibiliy of Li+ intercalation/deintercalation in V2O5 thin films and influence of
Li+ insertion on their optical properties were investigated. The experimental results show that two factors, the V5+ concentration and the sum total of
sites in V2O5 thin films, control the capacity of Li+ insertion into V2O5 thin films, and that these thin films have a good Li+ storage characteristic,
stability and reversibility.

Key words: thin film, V2O5, electrochemistry, electrochromism