Journal of Inorganic Materials ›› 2022, Vol. 37 ›› Issue (3): 289-296.DOI: 10.15541/jim20210518
Special Issue: 增材制造专题(2022); 【虚拟专辑】增材制造及3D打印(2021-2022)
• RESEARCH ARTICLE • Previous Articles Next Articles
LI Qi1(), HUANG Yi1, QIAN Bin2, XU Beibei1, CHEN Liying1, XIAO Wenge1(), QIU Jianrong1()
Received:
2021-08-23
Revised:
2021-09-24
Published:
2022-03-20
Online:
2021-11-01
Contact:
XIAO Wenge, lecturer. E-mail: wengsee@zju.edu.cn; QIU Jianrong, professor. Email: qjr@zju.edu.cn
About author:
LI Qi (1998-), female, Master candidate. E-mail: 22030030@zju.edu.cn
Supported by:
CLC Number:
LI Qi, HUANG Yi, QIAN Bin, XU Beibei, CHEN Liying, XIAO Wenge, QIU Jianrong. Photo Curing and Pressureless Sintering of Orange-emitting Glass-ceramics[J]. Journal of Inorganic Materials, 2022, 37(3): 289-296.
Fig. 1 Photographs, transmittance spectra, and XRD patterns of (Gd,Y)AG:Ce-PiG (a) (Gd,Y)AG:Ce-PiG (0.5 mm in thickness) with different doping concentrations under daylight and blue light (using a 480 nm filter to filter out blue light when taking pictures); (b) Transmittance spectra of (Gd,Y)AG:Ce-PiG samples; (c) XRD patterns of silica glass, (Gd,Y)AG:Ce phosphors and (Gd,Y)AG:Ce-PiG Colorful figures are availuable on the website
Fig. 2 Optical photos and EDS images of 3% (mass fraction) (Gd,Y)AG:Ce-PiG (a) Fluorescence microscope image; (b, c) 2D and 3D confocal laser scanning microscope images; (d) SEM image; (e, f) EDS spectra of Si and Al
Fig. 3 Luminous performance of (Gd,Y)AG:Ce-PiG (a) Excitation and emission spectra of 5% (mass fraction) (Gd,Y)AG:Ce-PiG; (b) Values of internal quantum efficiency (IQE), absorption efficiency (AE) and external quantum efficiency (EQE) of (Gd,Y)AG:Ce-PiG with different doping concentrations; (c) Temperature-dependent emission spectrum of 5% (mass fraction) (Gd,Y)AG:Ce-PiG PiG; (d) Temperature dependences of integrated emission intensity of (Gd,Y)AG:Ce-PiG and (Gd,Y)AG:Ce phosphor
Fig. 4 Electroluminescence spectra and their corresponding CIE color coordinates of white LEDs (a) Electroluminescence spectra; (b) Corresponding CIE color coordinates. White LEDs fabricated by using (Gd,Y)AG:Ce-PiG (0.8 mm in thickness) with different doping concentrations under the current of 100 mA; The inset shows the picture of LED device
Concentration (mass fraction) | Luminous efficiency/(lm·W-1) | CCT/K | CRI |
---|---|---|---|
3% | 70.7 | 5717 | 84.1 |
5% | 74.2 | 4444 | 78.4 |
7% | 81.9 | 3398 | 67.7 |
9% | 72.9 | 2907 | 60.5 |
Table 1 Optical performance of the packaged white LED devices
Concentration (mass fraction) | Luminous efficiency/(lm·W-1) | CCT/K | CRI |
---|---|---|---|
3% | 70.7 | 5717 | 84.1 |
5% | 74.2 | 4444 | 78.4 |
7% | 81.9 | 3398 | 67.7 |
9% | 72.9 | 2907 | 60.5 |
Fig. 5 Optical performance of (Gd,Y) AG:Ce-PiG under high power (a) Schematic of reflective LD device; (b) Luminous flux of (Gd,Y)AG:Ce-PiG (0.8 mm in thickness) with different doping concentrations as a function of the laser power density; (c) Emission spectra of 5% (mass fraction) (Gd,Y)AG:Ce-PiG under different laser powers densities; (d) Values of CCT, CRI and luminous efficacy of radiation (LER) of 5% (mass fraction) (Gd,Y)AG:Ce-PiG under different laser power densities Colorful figures are availuable on the website
Fig. 6 3D printed fluorescence converter (a) Photos of 5% (mass fraction) doped 3D printed precursor; (b) Photos of sintered (Gd,Y)AG:Ce-PiG; (c) Sintered (Gd,Y)AG:Ce-PiG under 450 nm blue light irradiation; (d) Device demonstration of white LED when combined with blue LED chip
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