几种重金属氧化物和GeO2的加入对掺Yb3+氟磷玻璃的光谱和激光性能的影响

doi:10.15541/jim20130660

无机材料学报 ›› 2014, Vol. 29 ›› Issue (9): 961-966.DOI: 10.15541/jim20130660 CSTR: 32189.14.10.15541/jim20130660

几种重金属氧化物和GeO₂的加入对掺Yb³⁺氟磷玻璃
的光谱和激光性能的影响

杨斌华^1,2, 刘雪强^1,2, 张威^1,2, 李响潭^1,2, 张丽艳¹, 胡丽丽¹

(1. 中国科学院上海光学精密机械研究所, 上海201800; 2. 中国科学院大学, 北京100039)

收稿日期:2013-12-13 修回日期:2014-02-27 出版日期:2014-09-17 网络出版日期:2014-08-21
作者简介:杨斌华(1987–), 男, 硕士研究生. E-mail: yangbinhua07@163.com
基金资助:
国家自然科学基金(61177083) National Natural Science Foundation of China (61177083);感谢中国科学院对本项目的经费支持;本工作光谱测试和折射率测试分别得到了本所李夏同学和林莹老师的大力支持, 在此表示感谢;同时, 感谢赵影老师在样品加工上给予的帮助

Influences of the Dopants of Several Heavy Metal Oxides and GeO₂ on Spectroscopic and Lasing Properties of Yb³⁺-doped Fluorophosphate Glasses

YANG Bin-Hua^1,2, LIU Xue-Qiang^1,2, ZHANG Wei^1,2, LI Xiang-Tan^1,2, ZHANG Li-Yan¹, HU Li-Li¹

(1. Shanghai Institute Of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China; 2. Graduate University of Chinese Academy of Sciences, Beijing 100039, China)

Received:2013-12-13 Revised:2014-02-27 Published:2014-09-17 Online:2014-08-21
About author:YANG Bin-Hua. E-mail: yangbinhua07@163.com

摘要/Abstract

摘要：

实验对比研究了Ga₂O₅、TeO₂、GeO₂、WO₃、Nb₂O₅和Bi₂O₅金属氧化物的掺入对氟磷激光玻璃的光谱和激光性能的影响。结果表明, TeO₂、GeO₂和Ga₂O₅的加入增大了Yb³⁺的吸收和发射截面; 其中, 掺有TeO₂的氟磷玻璃的Yb³⁺吸收和发射截面最大, 分别达到了1.95 pm²和0.85 pm²。Ga₂O₅、Nb₂O₅和GeO₂的加入对玻璃激光性能的提高具有极大的帮助; 其中, 在掺有Ga₂O₅的氟磷玻璃中激光参数SFL值最大, 为1.237。同时发现, 在TeO₂和GeO₂掺杂氟磷玻璃中也存在严重的Yb³⁺荧光俘获现象, 大大减弱了其激光性能。

关键词: 氟磷玻璃, 金属氧化物, 吸收截面, 发射截面, 激光性能

Abstract:

Effects of the different metal oxides added with Ga₂O₅, TeO₂, GeO₂, WO₃, Nb₂O₅ and Bi₂O₅respectively on the spectroscopic and lasing properties of Yb³⁺-doped fluorophosphate glasses were comparatively investigated. Results show that the additions of TeO₂, GeO₂ and Ga₂O₅ can increase the absorption and emission cross sections of Yb³⁺-ions. Among the three glasses above, the TeO₂-doped glass has the largest parameters up to 1.95 pm²and 0.85 pm², respectively. Meanwhile, the dopants of Ga₂O₅, Nb₂O₅and GeO₂ are beneficial to the improvement of lasing properties in fluorophosphate glasses. Laser parameters (SFL) of fluorophosphate glass doped with Ga₂O₅ is 1.237, the largest of all the glasses. Moreover, serious fluorescence trapping of Yb³⁺ is found in fluorophosphate glasses doped with TeO₂and GeO₂, respectively, which strongly lessens the lasing properties.

Key words: fluorophosphate glasses, metal oxides, absorption cross section, emission cross section, lasing property

中图分类号:

TQ174

杨斌华, 刘雪强, 张威, 李响潭, 张丽艳, 胡丽丽. 几种重金属氧化物和GeO₂的加入对掺Yb³⁺氟磷玻璃
的光谱和激光性能的影响[J]. 无机材料学报, 2014, 29(9): 961-966.

YANG Bin-Hua, LIU Xue-Qiang, ZHANG Wei, LI Xiang-Tan, ZHANG Li-Yan, HU Li-Li. Influences of the Dopants of Several Heavy Metal Oxides and GeO₂ on Spectroscopic and Lasing Properties of Yb³⁺-doped Fluorophosphate Glasses[J]. Journal of Inorganic Materials, 2014, 29(9): 961-966.

图/表 7

参考文献 17

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Glass	Composition / mol%
FP-N	23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃-1YbF₃
FP-Ge	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5GeO₂-1YbF₃
FP-Te	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5TeO₂-1YbF₃
FP-Bi	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5Bi₂O₃-1YbF₃
FP-W	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5WO₃-1YbF₃
FP-Ga	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5Ga₂O₃-1YbF₃
FP-Nb	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5Nb₂O₅-1YbF₃

Glass	Composition / mol%
FP-N	23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃-1YbF₃
FP-Ge	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5GeO₂-1YbF₃
FP-Te	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5TeO₂-1YbF₃
FP-Bi	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5Bi₂O₃-1YbF₃
FP-W	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5WO₃-1YbF₃
FP-Ga	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5Ga₂O₃-1YbF₃
FP-Nb	95[23Al(PO₃)₃-10MgF₂-10CaF₂-17SrF₂-35BaF₂-5AlF₃]- 5Nb₂O₅-1YbF₃

Glass	Density/ (g•cm^-3)	n_d	Yb³⁺concentration/ (10²⁰ions•cm^-3)
FP-N	3.811	1.541	1.400
FP-Ge	3.813	1.546	1.426
FP-Te	3.807	1.544	1.400
FP-Bi	4.081	1.578	1.372
FP-W	3.909	1.553	1.406
FP-Ga	3.842	1.543	1.400
FP-Nb	3.811	1.566	1.357

Glass	Density/ (g•cm^-3)	n_d	Yb³⁺concentration/ (10²⁰ions•cm^-3)
FP-N	3.811	1.541	1.400
FP-Ge	3.813	1.546	1.426
FP-Te	3.807	1.544	1.400
FP-Bi	4.081	1.578	1.372
FP-W	3.909	1.553	1.406
FP-Ga	3.842	1.543	1.400
FP-Nb	3.811	1.566	1.357

Glass	Σ_abs (pm²•nm)	A_rad /s^-1	Δλ_eff /nm	τ_f·σ_emi /(pm²•ms)	I_sat /( kW•cm^-2)	β_min	I_min /( kW•cm^-2)	SFL
FP-N	36.011	947	45.708	0.886	9.801	0.17	1.703	0.520
FP-Ge	47.102	1247	49.172	1.227	7.521	0.15	1.147	1.070
FP-Te	49.178	1298	55.674	1.298	6.961	0.18	1.258	1.032
FP-Bi	39.651	1093	46.775	0.985	9.227	0.16	1.471	0.669
FP-W	42.205	1127	50.853	1.109	8.006	0.16	1.280	0.867
FP-Ga	44.629	1177	46.502	1.155	7.904	0.12	0.934	1.237
FP-Nb	41.924	1138	49.776	1.047	8.452	0.12	1.189	1.072

几种重金属氧化物和GeO₂的加入对掺Yb³⁺氟磷玻璃
的光谱和激光性能的影响

Influences of the Dopants of Several Heavy Metal Oxides and GeO₂ on Spectroscopic and Lasing Properties of Yb³⁺-doped Fluorophosphate Glasses

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参考文献 17

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Glass	λ_s/nm	λ_p/nm	I_λ_s/ I_λ_p	τ_rad/ms	τ_f/ms	(τ_f-τ_rad)/τ_rad
FP-N	1002	976	0.582	1.056	1.433	0.36
FP-Ge	1005	976	0.634	0.802	1.463	0.82
FP-Te	1003	976	0.713	0.770	1.499	0.95
FP-Bi	1004	976	0.590	0.915	1.405	0.54
FP-W	1004	976	0.647	0.887	1.507	0.70
FP-Ga	1005	976	0.581	0.85	1.460	0.72
FP-Nb	1004	976	0.619	0.878	1.464	0.67

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