含氮挥发性有机化合物催化氧化的研究进展

doi:10.15541/jim20240511

无机材料学报 ›› 2025, Vol. 40 ›› Issue (9): 933-943.DOI: 10.15541/jim20240511

• 综述 • 下一篇

含氮挥发性有机化合物催化氧化的研究进展

刘江平¹^,²^,³(), 管鑫¹^,²^,³, 唐振杰¹^,²^,³, 朱文杰¹^,²^,³, 罗永明²^,³^,⁴()

1.昆明理工大学环境科学与工程学院, 昆明 650500
2.云南省挥发性有机物污染物防治与资源化利用创新团队, 先进环境功能材料创新团队, 昆明 650500
3.云南省高校恶臭挥发性有机物控制重点实验室, 云南省含硫精细化学品合成重点实验室(筹), 昆明 650500
4.昆明理工大学化学工程学院, 昆明 650500

收稿日期:2024-12-10 修回日期:2025-03-22 出版日期:2025-09-20 网络出版日期:2025-04-02
通讯作者: 罗永明, 教授. E-mail: environcatalysis@kust.edu.cn
作者简介:刘江平(1991-), 男, 副教授. E-mail: liujiangping@kust.edu.cn
基金资助:
国家自然科学基金重点项目(42030712);云南省基础研究计划(202301AT070424);云南省基础研究计划(202101BE070001-027)

Research Progress on Catalytic Oxidation of Nitrogen-containing Volatile Organic Compounds

LIU Jiangping¹^,²^,³(), GUAN Xin¹^,²^,³, TANG Zhenjie¹^,²^,³, ZHU Wenjie¹^,²^,³, LUO Yongming²^,³^,⁴()

1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2. Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, Advanced Environmental Functional Materials Innovation Team, Kunming 650500, China
3. Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province, Key Laboratory for Synthesis of Fine Chemicals Containing Sulfur (Preparatory) of Yunnan Province, Kunming 650500, China
4. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China

Received:2024-12-10 Revised:2025-03-22 Published:2025-09-20 Online:2025-04-02
Contact: LUO Yongming, professor. E-mail: environcatalysis@kust.edu.cn
About author:LIU Jiangping (1991-), male, associate professor. E-mail: liujiangping@kust.edu.cn
Supported by:
Key Program of National Natural Science Foundation of China(42030712);Basic Research Program of Yunnan Province(202301AT070424);Basic Research Program of Yunnan Province(202101BE070001-027)

摘要/Abstract

摘要：

挥发性有机化合物(VOCs)及NO_x是PM_2.5和O₃的重要前体物, 其过量排放对环境质量及人类健康具有重要影响。与普通VOCs相比, 含氮挥发性有机化合物(N-VOCs)由于氮杂原子的存在使得其环境控制策略更为复杂。因此, 针对N-VOCs控制技术的开发及应用已成为当前的研究热点。为了实现N-VOCs催化氧化体系中低温高催化活性及高N₂选择性两个关键目标, 亟需设计高效、低成本的催化剂。本文系统总结了矿物材料、金属材料、单原子催化剂(SACs)、分子筛等在常见N-VOCs(N,N-二甲基甲酰胺、丙烯腈、乙腈、正丁胺、三乙胺等)催化氧化中的研究进展, 介绍了N-VOCs的来源及危害; 归纳总结了胺类、腈类等典型N-VOCs催化氧化研究中的关键影响因素, 主要包括催化活性、催化剂理化性质、催化构效关系及反应机理, 提出了N-VOCs催化氧化过程中应避免中间产物深度氧化产生二次污染物; 最后展望了N-VOCs催化氧化研究面临的前景和挑战, 以期为未来N-VOCs的治理提供一定的理论指导与最新信息。

关键词: 含氮挥发性有机化合物, 催化氧化, 催化剂, N₂选择性, 反应机理, 综述

Abstract:

Volatile organic compounds (VOCs) and NO_x are important precursors of PM_2.5 and O₃, and their excessive emissions have significant negative impacts on environmental quality and human health. Compared with ordinary VOCs, nitrogen-containing volatile organic compounds (N-VOCs) need more complex environmental control strategies due to their nitrogen heteroatoms. Therefore, development and application of control technologies for N-VOCs have become a current research hotspot. In order to achieve the two key objectives of low-temperature high catalytic activity and high N₂ selectivity in catalytic oxidation system of N-VOCs, there is an urgent need to design efficient and low-cost catalysts. This paper systematically summarizes the research progress of mineral materials, metal materials, single atom catalysts (SACs) and molecular sieves in catalytic oxidation of common N-VOCs (N,N-dimethylformamide, acrylonitrile, acetonitrile, n-butylamine, triethylamine, etc.), and describes the sources and hazards of N-VOCs. The key factors affecting catalytic oxidation of amines, nitriles and other typical N-VOCs are summarized, including catalytic activity, catalyst physicochemical properties, catalytic constitutive relationship and reaction mechanism. It is proposed that secondary pollutants should be avoided from deep oxidation of intermediate products in catalytic oxidation of N-VOCs. Finally, the prospects and challenges on catalytic oxidation of N-VOCs are discussed, aiming to provide theoretical guidance and practical cases for clearing N-VOCs in the future.

Key words: nitrogen-containing volatile organic compound, catalytic oxidation, catalyst, N₂ selectivity, reaction mechanism, review

中图分类号:

O643

刘江平, 管鑫, 唐振杰, 朱文杰, 罗永明. 含氮挥发性有机化合物催化氧化的研究进展[J]. 无机材料学报, 2025, 40(9): 933-943.

LIU Jiangping, GUAN Xin, TANG Zhenjie, ZHU Wenjie, LUO Yongming. Research Progress on Catalytic Oxidation of Nitrogen-containing Volatile Organic Compounds[J]. Journal of Inorganic Materials, 2025, 40(9): 933-943.

图/表 10

图1 N-VOCs来源示意图

Fig. 1 Schematic diagram of sources and pathways of N-VOCs

图2 4种典型催化剂的结构简图

Fig. 2 Structural sketchs of 4 typical catalysts

图3 三元水滑石催化氧化DMF的(a)活性和(b)N2选择性[8]

Fig. 3 (a) Activity and (b) N2 selectivity for catalytic oxidation of dimethylformamide (DMF) by ternary hydrotalcite[8]

图4 LaFe0.8Cu0.2O3的丙烯腈催化氧化性能[52]

Fig. 4 Catalytic oxidation performance of LaFe0.8Cu0.2O3 for acrylonitrile[52] (a) Acrylonitrile conversion and N2 selectivity; (b) Water resistance

图5 yCuCeOx-HZSM-5复合催化剂的(a) CH3CN转化率、(b) CO2产率、(c) NOx产率和(d) NH3产率[54]

Fig. 5 (a) CH3CN conversion, (b) CO2 yield, (c) NOx yield, and (d) NH3 yield of yCuCeOx-HZSM-5 composite catalysts[54]

表1

Table 1 Research status of N-VOCs catalytic oxidation in the last 5 years[40,49,54,59-67]

N-VOCs	Catalyst	Conversion rate, temperature	N₂ selectivity, temperature	Ref.
Triethylamine	CuO/Nb₂O₅-H	100%, 220 ℃	96%, 220 ℃	[61]
Diethylamine	CuO/CeO₂/ZSM-5	100%, 220 ℃	100%, 220 ℃	[62]
DMF	Cu-Ce/H-MOR	99%, 220 ℃	100%, 220 ℃	[63]
DMF	Ag/CeO₂	90%, 158 ℃	80%, 237 ℃	[40]
DMF	Cu-ZSM-5	100%, 300 ℃	95%, 300 ℃	[49]
Butylamine	Cu-Mn/ZSM-5	100%, 280 ℃	>82%, 280 ℃	[64]
Butylamine	CeCu10%ZrO_x	100%, 250 ℃	90%, 250 ℃	[59]
Butylamine	Cu-ZSM-5	100%, 300 ℃	>95%, 350 ℃	[60]
Butylamine	Cu-Mn/SAPO-34	90%, 279 ℃	99%, 279 ℃	[65]
Butylamine	CuO/Pd@SiO₂	100%, 260 ℃	98.3%, 260 ℃	[66]
Acetonitrile	CuCeO_x-HZSM-5	100%, 225 ℃	93%, 225 ℃	[54]
Acetonitrile	Cu-Ce/ZSM-5	100%, 300 ℃	90%, 300 ℃	[67]

表2 不同催化剂对比及其在N-VOCs催化氧化中的应用

Table 2 Comparison of different catalysts and their applications in catalytic oxidation of N-VOCs

Catalyst category	Vantage	Drawback	Representative substance
Precious metals	High catalytic activity and high stability	Scarce resources and high costs	Pt, Ag, Pd
Transition metals	High selectivity, reproducibility, and low costs	Inactivation issues and toxic by-products	Cu, Mn, Fe, Co, Al
Molecular sieves	High adsorption capacity, high selectivity, and high temperature resistance	Easy enrichment of NH₃ on the surface of pure molecular sieves	ZSM-5, SBA-15
Mineral materials	Unique structure, high adsorption capacity, and low costs	Many ingredients and impurities	Calcite, mullite, spinel
SACs	High atom utilization, high selectivity, and reproducibility	Being difficult to prepare	-

图6 单一[Cu]+、双[Cu]+和[Cu-O-Cu]2+三种不同活性中心Cu-BEA模型上路线I(HCN氧化成HNCO或NCO)的CT图[81]

Fig. 6 CT diagram of models included in route I (oxidation of HCN into HNCO or NCO) over Cu-BEA with different active center structures of single [Cu]+, double [Cu]+ and [Cu-O-Cu]2+[81]

图7 CuO/Pd@SiO2和Pd@SiO2催化燃烧正丁胺机理图[66]

Fig. 7 Mechanism diagram of catalytic combustion of n-butylamine by CuO/Pd@SiO2 and Pd@SiO2[66]

图8 N-VOCs催化氧化生成N2的路径图

Fig. 8 Pathway diagram of N2 generation in catalytic oxidation of N-VOCs

参考文献 82

[1]	苏皓琳, 毕玉赞, 王一航. 空气中挥发性有机污染物的危害及处理工艺综述. 清洗世界, 2024, 40(8): 61.
[2]	曲家福, 李佐习. 空气中挥发性有机污染物的危害及处理工艺综述. 苏州科技大学学报(自然科学版), 2022, 39(3): 1.
[3]	赵飞, 潘帅, 张冲冲. 石油化工行业VOCs治理技术综述. 山东化工, 2024, 53(4): 274.
[4]	高鑫, 荆博宇, 吴琳, 等. 机动车尾气VOCs排放特征及影响因素研究进展. 环境科学与技术, 2023, 46(11): 69.
[5]	潘玉梅, 张敏. 化工企业VOCs治理技术及对策研究. 山东化工, 2024, 53(2): 223.
[6]	DUAN X X, ZHAO T, YANG Z W, et al. Oxygen activation- boosted manganese oxide with unique interface for chlorobenzene oxidation: unveiling the roles and dynamic variation of active oxygen species in heterogeneous catalytic oxidation process. Applied Catalysis B: Environmental, 2023, 331: 122719.
[7]	CHAI G T, ZHANG W D, LIOTTA L F, et al. Total oxidation of propane over Co₃O₄-based catalysts: elucidating the influence of Zr dopant. Applied Catalysis B: Environmental, 2021, 298: 120606.
[8]	XING X, LI N, CHENG J, et al. Hydrotalcite-derived Cu_xMg_3-_xAlO oxides for catalytic degradation of n-butylamine with low concentration NO and pollutant-destruction mechanism. Industrial & Engineering Chemistry Research, 2019, 58(22): 9362.
[9]	WU X Q, HAN R, LIU Q L, et al. A review of confined-structure catalysts in the catalytic oxidation of VOCs: synthesis, characterization, and applications. Catalysis Science & Technology, 2021, 11(16): 5374.
[10]	CUI W, CHEN H W, LIU D Q, et al. Mn/Co redox cycle promoted catalytic performance of mesoporous SiO₂-confined highly dispersed LaMn_xCo_1-_xO₃ perovskite oxides in n-butylamine combustion. ChemistrySelect, 2020, 5(28): 8504.
[11]	HE C, CHENG J, ZHANG X, et al. Recent advances in the catalytic oxidation of volatile organic compounds: a review based on pollutant sorts and sources. Chemical Reviews, 2019, 119(7): 4471. DOI PMID
[12]	WU P, JIN X J, QIU Y C, et al. Recent progress of thermocatalytic and photo/thermocatalytic oxidation for VOCs purification over manganese-based oxide catalysts. Environmental Science & Technology, 2021, 55(8): 4268.
[13]	王威. 化工行业VOCs废气治理措施分析. 石化技术, 2023, 30(9): 10.
[14]	杨成. 贵阳市机动车大气污染物排放清单的初步研究. 贵阳: 贵州大学硕士学位论文, 2021.
[15]	徐杏, 肖华, 周昕, 等. 畜禽场恶臭VOCs的产生及防控技术进展. 环境工程, 2020, 38(8): 180.
[16]	RAJ I, GUPTA A, BANSIWAL A, et al. A bench scale study on the startup, performance and optimization of the biological degradation of obnoxious air containing trimethylamine. Journal of Environmental Chemical Engineering, 2020, 8(1): 103529.
[17]	牛真真, 孔少飞, 严沁, 等. 薪柴和经济作物秸秆燃烧VOCs排放特征. 环境科学, 2020, 41(3): 1107.
[18]	张靳杰. 武汉市机动车尾气VOCs和颗粒物排放特征研究. 武汉: 华中科技大学硕士学位论文, 2019.
[19]	陈天增, 葛艳丽, 刘永春, 等. 我国机动车排放VOCs及其大气环境影响. 环境科学, 2018, 39(2): 478.
[20]	郭文凯, 刘镇, 刘文博, 等. 兰州生物质燃烧VOCs排放特征及其大气环境影响. 中国环境科学, 2019, 39(1): 40.
[21]	韩昕, 李相贤, 高闽光, 等. 基于SOF-FTIR的机场VOCs污染排放监测分析. 量子电子学报, 2019, 36(1): 101.
[22]	黄碧捷. 武汉市秸秆燃烧VOCs排放估算及管理对策. 环境科学, 2013, 34(12): 4543.
[23]	孙西勃, 廖程浩, 曾武涛, 等. 广东省秸秆燃烧大气污染物及VOCs物种排放清单. 环境科学, 2018, 39(9): 3995.
[24]	张启钧, 吴琳, 刘明月, 等. 南京市机动车排放VOCs的污染特征与健康风险评价. 中国环境科学, 2016, 36(10): 3118.
[25]	ZHOU L L, MA C, HORLYCK J, et al. Development of pharmaceutical VOCs elimination by catalytic processes in China. Catalysts, 2020, 10(6): 668.
[26]	程东风, 史彦辉, 张明成, 等. 煤基甲醇中三甲胺类杂质生成机理及脱除方法. 中氮肥, 2017(4): 39.
[27]	胡丽雅. 苏码罐采样-气相色谱-质谱法测定环境空气中三甲胺的含量. 理化检验-化学分册, 2023, 59(4): 394.
[28]	杨睿颖, 朱秋劲, 白晶, 等. 三甲胺表面增强拉曼光谱的密度泛函理论研究. 化学研究与应用, 2021, 33(5): 920.
[29]	YAN C, ZHONG M F, HAN J Q, et al. Efficient degradation of trimethylamine in gas phase by petal-shaped Co-MoS₂ catalyst in the photo-electrochemical system. Chemical Engineering Journal, 2021, 405: 127034.
[30]	吕道飞, 林洁玲, 许锋, 等. 锌基金属有机框架材料对三甲胺的吸附性能研究. 南方水产科学, 2022, 18(6): 110.
[31]	QIU M, CHEN C, LI W. Rapid controllable synthesis of Al-MIL-96 and its adsorption of nitrogenous VOCs. Catalysis Today, 2015, 258: 132.
[32]	ZHANG K, DING H L, PAN W G, et al. Research progress of a composite metal oxide catalyst for VOC degradation. Environmental Science & Technology, 2022, 56(13): 9220.
[33]	郭菊花. 生物法在挥发性有机废气处理中的应用研究. 清洗世界, 2023, 39(12): 91.
[34]	李春生. 热力燃烧法处理电子元件厂VOCs研究. 广州化工, 2015, 43(3): 141.
[35]	潘智超. 多相吸收法处理VOCs气体技术研究. 青岛: 中国石油大学(华东)硕士学位论文, 2020.
[36]	帅启凡, 董小平, 魏桃, 等. 工业废气中VOCs燃烧处理方法及发展趋势. 2020中国环境科学学会科学技术年会, 南京, 2020: 4411.
[37]	张胜, 王忠海, 文旭, 等. 催化-醚化联合装置污水预处理站VOCs的处理. 化工技术与开发, 2023, 52(10): 91.
[38]	WANG F, HE G Z, ZHANG B, et al. Insights into the activation effect of H₂ pretreatment on Ag/Al₂O₃ catalyst for the selective oxidation of ammonia. ACS Catalysis, 2019, 9(2): 1437.
[39]	王嘉, 尤瑞, 千坤, 等. Cl^-改性对Ag/Al₂O₃催化剂结构及其催化C₃H₆-SCR和H₂/C₃H₆-SCR反应性能的影响. 催化学报, 2021, 42(12): 2242. DOI
[40]	GUO X H, DONG C X, GAO M, et al. Crystal-facet-dependent activity and N₂ yield of Ag/CeO₂ catalysts for catalytic oxidation of N,N-dimethylformamide. Applied Catalysis B: Environmental, 2024, 341: 123286.
[41]	HUANG F Y, YE D S, GUO X H, et al. Effect of ceria morphology on the performance of MnO_x/CeO₂ catalysts in catalytic combustion of N,N-dimethylformamide. Catalysis Science & Technology, 2020, 10(8): 2473.
[42]	ZHANG Y, LU J C, ZHANG L M, et al. Investigation into the catalytic roles of oxygen vacancies during gaseous styrene degradation process via CeO₂ catalysts with four different morphologies. Applied Catalysis B: Environmental, 2022, 309: 121249.
[43]	ZHANG Y Y, WANG Y X, LIU Y, et al. Insight into the role of cerium in the enhanced performances during catalytic combustion of acetonitrile over core-shell-like Cu-Ce/ZSM-5 catalysts. ACS ES&T Engineering, 2022, 2(9): 1709.
[44]	刘凯鹏, 卢文新. 单原子催化的工业化挑战及现状. 化肥设计, 2023, 61(1): 1.
[45]	刘佳程, 马廷灿. 单原子催化国际研究态势分析. 世界科技研究与发展, 2022, 44(5): 643.
[46]	庄嘉豪, 王定胜. 单原子催化的关键进展与未来挑战. 高等学校化学学报, 2022, 43(5): 31.
[47]	WANG Y W, ZHANG J, ZHANG Y F, et al. Single Fe atom- anchored manganese dioxide for efficient removal of volatile organic compounds in refrigerator. Nano Research, 2024, 17(5): 3927.
[48]	YE D S, CHENG L, GAO Y Z, et al. Modulating the Mn-O strength of OMS-2 by alkali metal doping for the catalytic oxidation of N,N-dimethylformamide. Separation and Purification Technology, 2024, 351: 128049.
[49]	XING X, LI N, LIU D D, et al. Effect of Cu-ZSM-5 catalysts with different CuO particle size on selective catalytic oxidation of N,N-dimethylformamide. Frontiers of Environmental Science & Engineering, 2022, 16(10): 125.
[50]	LU Y, HU C H, ZHANG W X, et al. Promoting the selective catalytic oxidation of diethylamine over MnO_x/ZSM-5 by surface acid centers. Applied Surface Science, 2020, 521: 146348.
[51]	HU C H, FANG C T, LU Y, et al. Selective oxidation of diethylamine on CuO/ZSM-5 catalysts: the role of cooperative catalysis of CuO and surface acid sites. Industrial & Engineering Chemistry Research, 2020, 59(20): 9432.
[52]	ZHANG R D, LI P X, XIAO R, et al. Insight into the mechanism of catalytic combustion of acrylonitrile over Cu-doped perovskites by an experimental and theoretical study. Applied Catalysis B: Environmental, 2016, 196: 142.
[53]	WANG Y X, YING Q J, ZHANG Y Y, et al. Reaction behaviors of CH₃CN catalytic combustion over CuCeO_x-HZSM-5 composite catalysts: the mechanism of enhanced N₂ selectivity. Applied Catalysis A: General, 2020, 590: 117373.
[54]	ZHANG Y Y, WANG Y X, LIU Y, et al. Catalytic combustion of acetonitrile over CuCeO_x-HZSM-5 composite catalysts with different mass ratios: the synergism between oxidation and hydrolysis reactions. Journal of Colloid and Interface Science, 2021, 584: 193.
[55]	文红. 单原子掺杂过渡金属基催化剂上NO选择性还原的第一性原理研究. 长春: 吉林大学博士学位论文, 2021.
[56]	柳鑫淼. 单/双原子锚定二维C₂N材料降解N₂O的理论研究. 哈尔滨: 哈尔滨工业大学博士学位论文, 2023.
[57]	ZHANG R D, SHI D J, LIU N, et al. Catalytic purification of acrylonitrile-containing exhaust gases from petrochemical industry by metal-doped mesoporous zeolites. Catalysis Today, 2015, 258: 17.
[58]	ZHANG R D, SHI D J, LIU N, et al. Mesoporous SBA-15 promoted by 3d-transition and noble metals for catalytic combustion of acetonitrile. Applied Catalysis B: Environmental, 2014, 146: 79.
[59]	XING X, ZHAO T, CHENG J, et al. Promotional effect of Cu additive for the selective catalytic oxidation of n-butylamine over CeZrO_x catalyst. Chinese Chemical Letters, 2022, 33(6): 3065.
[60]	XING X, LI N, SUN Y G, et al. Selective catalytic oxidation of n-butylamine over Cu-zeolite catalysts. Catalysis Today, 2020, 339: 192.
[61]	MENG L W, MA W H, ZHANG S L, et al. Isolated CuO and medium strong acid on CuO/Nb₂O₅-H catalyst for efficient enhancement of triethylamine selective catalytic oxidation. Journal of Environmental Chemical Engineering, 2023, 11(4): 110258.
[62]	HE L C, XU H H, LENG X Y, et al. Boosting diethylamine selective oxidation over CuO/ZSM-5 catalyst by CeO₂ modification. Fuel, 2023, 342: 127792.
[63]	XU H H, XIAN W Y, ZHAO X, et al. Selective catalytic oxidation of DMF over Cu-Ce/H-MOR by modulating the surface active sites. Journal of Hazardous Materials, 2024, 474: 134829.
[64]	YAN D J, CHEN Z H, MA M D, et al. Hierarchical Cu-Mn/ZSM-5 with boosted activity and selectivity for n-butylamine destruction: synergy of pore structure and surface acidity. Applied Catalysis A: General, 2022, 636: 118579.
[65]	XU J W, LIU Q Y, CHEN Z H, et al. Efficient selective combustion of n-butylamine on hierarchical Cu-Mn/SAPO-34 catalysts: the effect of mesoporosity and acidity. Applied Catalysis A: General, 2023, 665: 119354.
[66]	MA M D, XU S, LIU Q Y, et al. Rationally engineering a CuO/ Pd@SiO₂ core-shell catalyst with isolated bifunctional Pd and Cu active sites for n-butylamine controllable decomposition. Environmental Science & Technology, 2022, 56(22): 16189.
[67]	ZHANG Y Y, WANG Y X, LIU Y, et al. The reaction behaviors of acetonitrile and ethyl acetate simultaneous degradation over Cu-Ce/ ZSM-5 catalyst. Applied Surface Science, 2023, 609: 155190.
[68]	PENG H G, DONG T, YANG S Y, et al. Intra-crystalline mesoporous zeolite encapsulation-derived thermally robust metal nanocatalyst in deep oxidation of light alkanes. Nature Communications, 2022, 13: 295.
[69]	ZHANG Y K, WANG Y H, SU K B, et al. The influence of the oxygen vacancies on the Pt/TiO₂ single-atom catalyst—a DFT study. Journal of Molecular Modeling, 2022, 28(6): 175.
[70]	CHEN X Y, YANG S, REN B P, et al. Copper porphyrin-catalyzed cross dehydrogenative coupling of alkanes with carboxylic acids: esterification and decarboxylation dual pathway. Tetrahedron, 2021, 96: 132377.
[71]	沈宏宇. MFI沸石分子筛的高效合成及其催化性能研究. 大连: 大连理工大学硕士学位论文, 2021.
[72]	孙晶晶. 2-甲基萘酰化反应中改性Hβ分子筛催化性能的研究. 北京: 北京石油化工学院硕士学位论文, 2022.
[73]	王伟都. 沸石分子筛封装Ag纳米粒子的制备、结构分析及催化性能的研究. 沈阳: 沈阳师范大学硕士学位论文, 2021.
[74]	韩文鹏, 王淑娟, 耿付江, 等. 介孔分子筛的合成、改性及催化应用进展. 广州化工, 2025, 53(1): 4.
[75]	MONGUEN C K F, DANIEL S, TIAN Z Y. Low-temperature deep oxidation of N,N-dimethylformamide (DMF) over CeCu binary oxides. Catalysis Science & Technology, 2023, 13(12): 3517.
[76]	ZHU W J, TANG L, LU J C, et al. Research progress in catalytic oxidation of volatile organic compounds by perovskite oxides. Journal of Inorganic Materials, 2025, 40(7): 735.
[77]	沈方燮, 万翔, 王卫超. 基于锰基YMn₂O₅催化剂室温降解挥发性有机化合污染物. 应用化学, 2023, 40(6): 888. DOI
[78]	HU B T, SUN K A, ZHUANG Z W, et al. Distinct crystal-facet- dependent behaviors for single-atom palladium-on-ceria catalysts: enhanced stabilization and catalytic properties. Advanced Materials, 2022, 34(16): 2107721.
[79]	王愉雄. ZnO基催化剂光催化选择性氧化甲烷制备高值化学品研究. 杭州: 浙江大学博士学位论文, 2024.
[80]	刘璐. 基于单原子铁修饰氮化碳光催化—自Fenton协同体系的构建及其去除NO性能研究. 武汉: 华中农业大学硕士学位论文, 2024.
[81]	LIU N, YUAN X N, ZHANG R D, et al. Mechanistic insight into selective catalytic combustion of HCN over Cu-BEA: influence of different active center structures. Physical Chemistry Chemical Physics, 2017, 19(35): 23960. DOI PMID
[82]	CHEN D, SHI J, SHEN H Y. High-dispersed catalysts of core- shell structured Au@SiO₂ for formaldehyde catalytic oxidation. Chemical Engineering Journal, 2020, 385: 123887.

含氮挥发性有机化合物催化氧化的研究进展

Research Progress on Catalytic Oxidation of Nitrogen-containing Volatile Organic Compounds

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 82

相关文章 15

编辑推荐

Metrics

本文评价

[1]	余升阳, 苏海军, 姜浩, 余明辉, 姚佳彤, 杨培鑫. 激光增材制造超高温氧化物陶瓷孔隙缺陷形成及抑制研究进展[J]. 无机材料学报, 2025, 40(9): 944-956.
[2]	肖晓琳, 王玉祥, 谷佩洋, 朱圳荣, 孙勇. 二维无机材料调控病损皮肤组织再生的研究进展[J]. 无机材料学报, 2025, 40(8): 860-870.
[3]	马景阁, 吴成铁. 无机生物材料用于毛囊和毛发再生的研究[J]. 无机材料学报, 2025, 40(8): 901-910.
[4]	张洪健, 赵梓壹, 吴成铁. 无机生物材料调控神经细胞功能及神经化组织再生的研究进展[J]. 无机材料学报, 2025, 40(8): 849-859.
[5]	艾敏慧, 雷波. 微纳米生物活性玻璃: 功能化设计与血管化皮肤再生[J]. 无机材料学报, 2025, 40(8): 921-932.
[6]	王宇彤, 常江, 徐合, 吴成铁. 硅酸盐生物陶瓷/玻璃促创面修复的研究进展:作用、机制和应用方式[J]. 无机材料学报, 2025, 40(8): 911-920.
[7]	马文平, 韩雅卉, 吴成铁, 吕宏旭. 无机活性材料在类器官研究领域的应用[J]. 无机材料学报, 2025, 40(8): 888-900.
[8]	罗晓民, 乔志龙, 刘颍, 杨晨, 常江. 无机生物活性材料调控心肌再生的研究进展[J]. 无机材料学报, 2025, 40(8): 871-887.
[9]	朱文杰, 唐璐, 陆继长, 刘江平, 罗永明. 钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展[J]. 无机材料学报, 2025, 40(7): 735-746.
[10]	胡智超, 杨鸿宇, 杨鸿程, 孙成礼, 杨俊, 李恩竹. P-V-L键理论在微波介质陶瓷性能调控中的应用[J]. 无机材料学报, 2025, 40(6): 609-626.
[11]	吴琼, 沈炳林, 张茂华, 姚方周, 邢志鹏, 王轲. 铅基织构压电陶瓷研究进展[J]. 无机材料学报, 2025, 40(6): 563-574.
[12]	张碧辉, 刘小强, 陈湘明. Ruddlesden-Popper结构杂化非常规铁电体的研究进展[J]. 无机材料学报, 2025, 40(6): 587-608.
[13]	吴杰, 杨帅, 王明文, 李景雷, 李纯纯, 李飞. 铅基织构压电陶瓷的发展历程、现状与挑战[J]. 无机材料学报, 2025, 40(6): 575-586.
[14]	姜昆, 李乐天, 郑木鹏, 胡永明, 潘勤学, 吴超峰, 王轲. PZT陶瓷的低温烧结研究进展[J]. 无机材料学报, 2025, 40(6): 627-638.
[15]	郭子玉, 朱云洲, 王力, 陈健, 李红, 黄政仁. Zn²⁺催化剂对酚醛树脂/乙二醇制备多孔碳微观孔结构的影响[J]. 无机材料学报, 2025, 40(5): 466-472.