钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展

doi:10.15541/jim20240333

无机材料学报 ›› 2025, Vol. 40 ›› Issue (7): 735-746.DOI: 10.15541/jim20240333 CSTR: 32189.14.10.15541/jim20240333

• 综述 • 下一篇

钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展

朱文杰¹^,²^,³(), 唐璐¹^,²^,³, 陆继长¹^,²^,³, 刘江平¹^,²^,³, 罗永明²^,³^,⁴

1.昆明理工大学环境科学与工程学院, 昆明 650500
2.云南省挥发性有机物污染物控制与资源化利用创新团队,昆明 650500
3.云南省高校恶臭挥发性有机物控制重点实验室, 昆明 650500
4.昆明理工大学化学工程学院, 昆明 650500

收稿日期:2024-07-16 修回日期:2024-09-13 出版日期:2025-07-20 网络出版日期:2024-09-27
作者简介:朱文杰(1979-), 男, 教授. E-mail: zhuwenjie17@163.com
基金资助:
国家自然科学基金(22166021);云南省科技厅科技计划(202302AG050002-1);云南省中青年学术与技术带头人后备人才(202405AC350026)

Research Progress on Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides

ZHU Wenjie¹^,²^,³(), TANG Lu¹^,²^,³, LU Jichang¹^,²^,³, LIU Jiangping¹^,²^,³, LUO Yongming²^,³^,⁴

1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2. Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, Kunming 650500, China
3. Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province, Kunming 650500, China
4. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China

Received:2024-07-16 Revised:2024-09-13 Published:2025-07-20 Online:2024-09-27
About author:ZHU Wenjie (1979-), male, professor. E-mail: zhuwenjie17@163.com
Supported by:
National Natural Science Foundation of China(22166021);Science and Technology Plan Project of Yunnan Provincial Science and Technology Department(202302AG050002-1);Yunnan Province Reserve Talent Project for Young and Middle-aged Academic and Technical Leaders(202405AC350026)

摘要/Abstract

摘要：

控制与去除挥发性有机化合物(VOCs)一直是环境领域的热点问题, 催化氧化法因其低温、高效以及副产物无毒害等特点成为去除VOCs最有前景的技术之一。钙钛矿型氧化物(ABO₃)是催化氧化VOCs的高效稳定催化剂。为了提高钙钛矿型催化剂的催化效率, 有必要针对性地分析钙钛矿型氧化物的设计, 以去除不同类型的VOCs。本文系统总结了近年来钙钛矿型氧化物催化氧化VOCs的研究进展。首先介绍了钙钛矿型氧化物在VOCs催化氧化中不同的设计策略, 包括形貌调控、A位和B位取代、缺陷工程和负载型钙钛矿催化剂, 阐明了钙钛矿型氧化物的催化性能与其材料组成、形貌、表面性质(氧物种、缺陷)和本身性质(氧空位浓度、晶格结构)之间的关系; 然后介绍了VOCs催化氧化的反应机制和降解途径, 并展望了钙钛矿型氧化物催化剂设计和反应机制研究的前景和挑战。

关键词: 挥发性有机化合物, 钙钛矿型氧化物, 结构设计, 催化氧化, 综述

Abstract:

Control and removal of volatile organic compounds (VOCs) have always been critical issues in the environmental field. Catalytic oxidation has emerged as one of the most promising technologies for VOCs removal due to its low operational temperature, high efficiency, and non-toxic by-products. Perovskite oxides (ABO₃) are recognized as efficient and stable catalysts for the catalytic oxidation of VOCs. To enhance the catalytic efficiency of perovskite-based catalysts, it is necessary to systematically analyze and optimize the design of perovskite oxides to meet the specific requirements for the removal of different VOCs. This paper comprehensively reviews recent advances in the catalytic oxidation of VOCs using perovskite oxides. Firstly, various design strategies for perovskite oxides in the catalytic oxidation of VOCs, including morphology control, A-site and B-site substitution, defect engineering, and supported perovskite catalysts, are introduced, giving a close link between the catalytic performance of perovskite oxides and their material composition, morphology, surface properties (oxygen species, defects), and intrinsic properties (oxygen vacancy concentration, lattice structure). The reaction mechanisms and degradation pathways involved in the catalytic oxidation of VOCs are analyzed, and the prospects and challenges in the rational design of perovskite oxide catalysts and the exploration of reaction mechanisms are outlined.

Key words: volatile organic compound, perovskite oxide, structure design, catalytic oxidation, review

中图分类号:

O643

朱文杰, 唐璐, 陆继长, 刘江平, 罗永明. 钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展[J]. 无机材料学报, 2025, 40(7): 735-746.

ZHU Wenjie, TANG Lu, LU Jichang, LIU Jiangping, LUO Yongming. Research Progress on Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides[J]. Journal of Inorganic Materials, 2025, 40(7): 735-746.

图/表 11

图1 钙钛矿型氧化物调控策略

Fig. 1 Design strategies for perovskite oxides

图2 中空多壳球形PrMnO3钙钛矿应用于催化CO和甲苯氧化[20]

Fig. 2 Catalytic oxidation of CO and toluene by multi-shelled spherical PrMnO3 perovskite[20]

图3 在100~600 ℃范围内LaFe0.8Cu0.2O3的抗水抗硫性能[25]

Fig. 3 Water and sulfur resistance over LaFe0.8Cu0.2O3 in the temperature range of 100-600 ℃[25] (a) C3H3N conversion; (b) CO2 yield; (c) CO yield; (d) N2 yield; (e) NH3 yield; (f) N2O yield; (g) NOx yield

表1 A、B位掺杂改性的钙钛矿型催化剂及其在催化氧化VOCs中的应用

Table 1 A- and B-sites doped perovskite catalysts and their application in catalytic oxidation of VOCs

Catalyst	VOCs	ρ_VOCs/ (mg·L^-1)	^aGHSV/ (mL·g^-1·h^-1)	Preparation method	^bT₅₀/℃	^cT₉₀/℃	^dR/(mol·g^-1·s^-1)	Ref.
La_0.95Ce_0.05CoO₃	Chlorobenzene	4605	60000	Reactive grinding method	377	434	1.083×10^-3 (200 ℃)	[31]
La_0.95Ce_0.05CoO₃	Chlorobenzene	4605	60000	Sol-Gel method	313	425	6.775×10^-9 (200 ℃)	[31]
La_0.9Ce_0.1MnO₃	Styrene	12780	25000	Sol-Gel method	306	328	-	[38]
LaFe_0.8Cu_0.2O₃	Acrylonitrile	6512	120000	Sol-Gel method	-	250	-	[25]
LaFe_0.8Co_0.2O₃	Propylene	1722	60000	Sol-Gel method	293	345	-	[24]
LaMn_0.8Cu_0.2O₃	Formaldehyde	368	12000	Sol-Gel method	138	168	-	[39]
LaMn_0.8Ni_0.2O₃					143	200
LaMn_0.8Zn_0.2O₃					146	200
LaMn_0.7Mg_0.3O₃	Methane	328	50000	Sol-Gel method	450	495	6.90×10^-7 (400 ℃)	[40]
La_0.5Sr_0.5Co_0.8Fe_0.2O₃	Toluene	3770	30000	Sol-Gel method	251	270	8.43×10^-8 (230 ℃)	[36]
La_0.8Ce_0.2Mn_0.8Ni_0.2O₃	Trichloroethylene	806	10000	Sol-Gel method	310	379	-	[35]
La_0.8Ce_0.2Mn_0.8Ni_0.2O₃	Toluene	3770	18000	Sol-Gel method	260	295	-	[34]
La_0.9Sr_0.1Co_0.9Mn_0.1O₃	Benzene	6390	30000	PMMA template method	272	328	-	[18]

图4 选择性溶解技术配合Cu掺杂改性LaMnO3催化剂[37]

Fig. 4 Selective dissolution technique combined with Cu-doping modified LaMnO3 catalyst[37] (a) Synergistically modulating the A- and B-sites of perovskite; (b) XRD patterns of the synthesized catalysts; (c1-c4) Catalytic activities of the synthesized catalysts under different conditions

图5 含有A位阳离子缺陷的LaFeO3(LxFO)在甲苯催化氧化中的活性以及稳定性测试[46]

Fig. 5 Activity and stability tests of LaFeO3 (LxFO) with A-site cation deficiency in catalytic oxidation of toluene[46] (a) Toluene conversion as a function of reaction temperature over LxFO samples (0.80≤x≤1.00) and commercial Fe2O3; (b) Effect of GHSV on the catalytic performance of L0.90FO sample; (c) Arrhenius plots of toluene oxidation over LxFO samples (0.80≤x≤1.00) under the conditions of toluene mass concentration 1000 mg·L−1 and GHSV 20000 mL·g−1·h−1; (d) Thermal stability test of toluene catalytic oxidation over L0.90FO sample at 300 ℃ (toluene mass concentration 1000 mg·L−1 and GHSV 20000 mL·g−1·h−1)

图6 LaxFeO3 (x=1.03, 1, 0.97)钙钛矿的结构及表征[47]

Fig. 6 Structure and characterization of LaxFeO3 (x=1.03, 1, 0.97) perovskite[47] (a) Unit cell of perovskite oxide (ABO3) with an ideal cubic structure (left), corresponding coordination state of bulk (middle) and surface (right) lattice oxygen (perovskite surface terminated with Fe cations); (b-d) EDS mappings and (e-g) corresponding HRTEM images of (b, e) La1.03FeO3, (c, f) LaFeO3, and (d, g) La0.97FeO3; (h) H2-TPR profiles of LaxFeO3 (x=1.03, 1, 0.97) oxides

表2 负载型钙钛矿催化剂及其在催化氧化VOCs中的应用

Table 2 Perovskite-based supported catalysts and their application in catalytic oxidation of VOCs

Catalyst	VOCs	ρ_VOCs/ (mg·L⁻¹)	^aGHSV/ (mL·g⁻¹·h⁻¹)	^bT₅₀/℃	^cT₉₀/℃	^dR	Ref.
Ag/LaCoO₃-250	Toluene	3770	30000	231	239	4.19×10⁻⁹ mol·m⁻²·s⁻¹ (225 ℃)	[53]
Ag/LaCoO₃-450				260	278	3.09×10⁻⁹ mol·m⁻²·s⁻¹ (225 ℃)
Ag/LaCoO₃-700				252	267	3.44×10⁻⁹ mol·m⁻²·s⁻¹ (225 ℃)
LaMnO₃/CeO₂	1,2-Dichloropropane	4622	15000	171	260	-	[54]
LaMnO₃/Al₂O₃				178	243
LaMnO₃/TiO₂				183	249
LaMnO₃/YSZ				189	243
2%(in mass)Pd@N-L_0.8S_0.2MO	Toluene	188	36000	-	166	9.61×10⁻⁹ mol·g⁻¹·s⁻¹ (105 ℃)	[56]
20%(in mass)LaCoO₃/Ce_0.9Zr_0.1O₂	Toluene	6406	60000	200	-	1.6×10⁻⁶ mol·g⁻¹·s⁻¹ (300 ℃)	[58]
NiMnO₃/Ce_xZr_1-_xO₂/cordierite	Benzene	1834	15000	-	275 (^eT₉₅)	-	[59]
CeO₂-LaCo_0.25Fe_0.75O₃	Toluene	3770	18000	150	205	-	[60]
CeO₂-LaMn_0.25Fe_0.75O₃	Toluene	3770	18000	155	215	-	[60]

图7 (a) MvK机制、(b) L-H机制和(c) E-R机制示意图[62]

Fig. 7 Schematic diagrams of (a) MvK mechanism, (b) L-H mechanism and (c) E-R mechanism[62]

图8 C16O在钙钛矿催化剂上的等温氧化反应(同位素标记18O2)[67]

Fig. 8 Isothermal C16O oxidation reaction on perovskite with time-resolved isotopic 18O2[67]

图9 LH-OS-ND模型的实验和模拟数据之间的比较[69]

Fig. 9 Comparison between experimental and simulated data for the LH-OS-ND model[69]

参考文献 72

[1]	GUO Y, WEN M, LI G, et al. Recent advances in VOC elimination by catalytic oxidation technology onto various nanoparticles catalysts: a critical review. Applied Catalysis B: Environmental, 2021, 281: 119447.
[2]	ALMAIE S, VATANPOUR V, RASOULIFARD M H, et al. Volatile organic compounds (VOCs) removal by photocatalysts: a review. Chemosphere, 2022, 306: 135655.
[3]	ZHAO Z, MA S, GAO B, et al. A systematic review of intermediates and their characterization methods in VOCs degradation by different catalytic technologies. Separation and Purification Technology, 2023, 314: 123510.
[4]	ZHANG Y, LU J, ZHANG L, et al. Investigation into the catalytic roles of oxygen vacancies during gaseous styrene degradation process via CeO₂ catalysts with four different morphologies. Applied Catalysis B: Environmental, 2022, 309: 121249.
[5]	ZHAO R, WANG H, ZHAO D, et al. Review on catalytic oxidation of VOCs at ambient temperature. International Journal of Molecular Sciences, 2022, 23(22): 13739.
[6]	ZHANG Y, ZHU W, LU J, et al. Induced synthesis of CeO₂ with abundant crystal boundary for promoting catalytic oxidation of gaseous styrene. Applied Catalysis B: Environmental, 2024, 342: 123461.
[7]	LIAO W, ZHU W, LU J, et al. Revealing the equilibrium relationship between lattice oxygen mobility and styrene removal: sources of adsorption and activation by in situ experiments. Applied Surface Science, 2023, 629: 157434.
[8]	SU Y, FU K, PANG C, et al. Recent advances of chlorinated volatile organic compounds' oxidation catalyzed by multiple catalysts: reasonable adjustment of acidity and redox properties. Environmental Science & Technology, 2022, 56(14): 9854.
[9]	PEÑA M A, FIERRO J L. Chemical structures and performance of perovskite oxides. Chemical Reviews, 2001, 101(7): 1981. PMID
[10]	GRABOWSKA E. Selected perovskite oxides: characterization, preparation and photocatalytic properties—a review. Applied Catalysis B: Environmental, 2016, 186: 97.
[11]	WANG K, HAN C, SHAO Z, et al. Perovskite oxide catalysts for advanced oxidation reactions. Advanced Functional Materials, 2021, 31(30): 2102089.
[12]	YANG L, LI Y, SUN Y, et al. Perovskite oxides in catalytic combustion of volatile organic compounds: recent advances and future prospects. Energy & Environmental Materials, 2022, 5(3): 751.
[13]	HUMAYUN M, ULLAH H, USMAN M, et al. Perovskite-type lanthanum ferrite based photocatalysts: preparation, properties, and applications. Journal of Energy Chemistry, 2022, 66: 314. DOI
[14]	ARANDIYAN H, WANG Y, SUN H, et al. Ordered meso- and macroporous perovskite oxide catalysts for emerging applications. Chemical Communications, 2018, 54(50): 6484. DOI PMID
[15]	WEI Y, LENG Y, WANG R, et al. Peroxydisulfate activation by LaNiO₃ nanoparticles with different morphologies for the degradation of organic pollutants. Water Science and Technology, 2022, 85(1): 39.
[16]	WU M, LI H, MA S, et al. Boosting the surface oxygen activity for high performance iron-based perovskite oxide. Science of the Total Environment, 2021, 795: 148904.
[17]	郭晓青.钙钛矿催化剂的结构优化与掺杂改性及其对含甲烷废气的催化氧化性能研究. 青岛: 青岛科技大学硕士学位论文, 2022.
[18]	SHI Z, DONG F, TANG Z, et al. Design Sr, Mn-doped 3DOM LaCoO₃ perovskite catalysts with excellent SO₂ resistance for benzene catalytic combustion. Chemical Engineering Journal, 2023, 473: 145476.
[19]	LIU L, JIA J, SUN T, et al. A facile method for scalable preparation of mesoporous structured SmMnO₃ perovskites sheets for efficient catalytic oxidation of toluene. Materials Letters, 2018, 212: 107.
[20]	CHEN S, HAO Y, CHEN R, et al. Hollow multishelled spherical PrMnO₃ perovskite catalyst for efficient catalytic oxidation of CO and toluene. Journal of Alloys and Compounds, 2021, 861: 158584.
[21]	LIU J, WANG J, ZHAO Z, et al. Synthesis of La_xK_1-_xCoO₃ nanorod and their catalytic performances for CO oxidation. Journal of Rare Earths, 2014, 32(2): 170.
[22]	ŞAHIN R Z Y, DUPLANČIĆ M, TOMAŠIĆ V, et al. Essential role of B metal species in perovskite type catalyst structure and activity on toluene oxidation. International Journal of Environmental Science and Technology, 2022, 19(1): 553.
[23]	TARJOMANNEJAD A, FARZI A, NIAEI A, et al. An experimental and kinetic study of toluene oxidation over LaMn_1-_xB_xO₃ and La_0.8A_0.2Mn_0.3B_0.7O₃ (A=Sr, Ce and B=Cu, Fe) nano-perovskite catalysts. Korean Journal of Chemical Engineering, 2016, 33(9): 2628.
[24]	PAN F, ZHANG W, FERRONATO C, et al. Boosting propene oxidation activity over LaFeO₃ perovskite catalysts by cobalt substitution. Applied Catalysis A: General, 2022, 643: 118779.
[25]	ZHANG R, LI P, XIAO R, et al. Insight into the mechanism of catalytic combustion of acrylonitrile over Cu-doped perovskites by an experimental and theoretical study. Applied Catalysis B: Environmental, 2016, 196: 142.
[26]	CAO X, LU J, ZHENG X, et al. Regulation of the reaction pathway to design the high sulfur/coke-tolerant Ce-based catalysts for decomposing sulfur-containing VOCs. Chemical Engineering Journal, 2022, 429: 132473.
[27]	LI X, ZHAO H, LIANG J, et al. A-site perovskite oxides: an emerging functional material for electrocatalysis and photocatalysis. Journal of Materials Chemistry A, 2021, 9(11): 6650.
[28]	CHANG H, BJØRGUM E, MIHAI O, et al. Effects of oxygen mobility in La-Fe-based perovskites on the catalytic activity and selectivity of methane oxidation. ACS Catalysis, 2020, 10(6): 3707.
[29]	ANSARI A A, AHMAD N, ALAM M, et al. Physico-chemical properties stalytic activity of the Sol-Gel prepared Ce-ion doped LaMnO₃ perovskites. Scientific Reports, 2019, 9: 7747.
[30]	ANSARI A A, ADIL S F, ALAM M, et al. Catalytic performance of the Ce-doped LaCoO₃ perovskite nanoparticles. Scientific Reports, 2020, 10: 15012.
[31]	PÉREZ H A, LÓPEZ C A, CADÚS L E, et al. Catalytic feasibility of Ce-doped LaCoO₃ systems for chlorobenzene oxidation: an analysis of synthesis method. Journal of Rare Earths, 2022, 40(6): 897.
[32]	SHIN H, BAEK M, KIM D H. Sulfur resistance of Ca-substituted LaCoO₃ catalysts in CO oxidation. Molecular Catalysis, 2019, 468: 148.
[33]	LI X, LI M, MA X, et al. Nonstoichiometric perovskite for enhanced catalytic oxidation through excess A-site cation. Chemical Engineering Science, 2020, 219: 115596.
[34]	YUAN B, TAO Y, QI S, et al. Effect of A, B-site cation on the catalytic activity of La_1-_xA_xMn_1-_yB_yO₃ (A=Ce, B=Ni) perovskite-type oxides for toluene oxidation. Environmental Science and Pollution Research International, 2023, 30(13): 36993.
[35]	HE C B, PAN K L, CHANG M B. Catalytic oxidation of trichloroethylene from gas streams by perovskite-type catalysts. Environmental Science and Pollution Research International, 2018, 25(12): 11584. DOI PMID
[36]	LI Y, LIU S, YIN K, et al. Understanding the mechanisms of catalytic enhancement of La-Sr-Co-Fe-O perovskite-type oxides for efficient toluene combustion. Journal of Environmental Chemical Engineering, 2023, 11(1): 109050.
[37]	WANG D, LUO K, TIAN H, et al. Transforming plain LaMnO₃ perovskite into a powerful ozonation catalyst: elucidating the mechanisms of simultaneous A and B sites modulation for enhanced toluene degradation. Environmental Science & Technology, 2024, 58(27): 12167.
[38]	辛松.改性钙钛矿催化燃烧苯乙烯的稳定性与耐久性研究. 武汉: 华中科技大学硕士学位论文, 2020.
[39]	丁俊彦.镧锰钙钛矿掺杂改性对甲醛催化氧化脱除的实验与机理研究. 武汉: 华中科技大学博士学位论文, 2022.
[40]	FENG M, LIN J, LI J, et al. Magnesium-enhanced redox property and surface acidity-basicity of LaMnO₃ perovskites for efficient methane purification. Separation and Purification Technology, 2024, 330: 125391.
[41]	WEXLER R B, GAUTAM G S, STECHEL E B, et al. Factors governing oxygen vacancy formation in oxide perovskites. Journal of the American Chemical Society, 2021, 143(33): 13212. DOI PMID
[42]	LI S F, ZHENG J, YAN D. Cationic defect engineering in perovskite La₂CoMnO₆ for enhanced electrocatalytic oxygen evolution. Inorganic Chemistry, 2023, 62(28): 11009.
[43]	LUO Y, WU Y. Defect engineering of nanomaterials for catalysis. Nanomaterials, 2023, 13(6): 1116.
[44]	FENG C, GAO Q, XIONG G, et al. Defect engineering technique for the fabrication of LaCoO₃ perovskite catalyst via urea treatment for total oxidation of propane. Applied Catalysis B: Environmental, 2022, 304: 121005.
[45]	XU Y, DHAINAUT J, DACQUIN J P, et al. On the role of cationic defects over the surface reactivity of manganite-based perovskites for low temperature catalytic oxidation of formaldehyde. Applied Catalysis B: Environmental, 2024, 342: 123400.
[46]	WU M, CHEN S, XIANG W. Oxygen vacancy induced performance enhancement of toluene catalytic oxidation using LaFeO₃ perovskite oxides. Chemical Engineering Journal, 2020, 387: 124101.
[47]	HE J, WANG T, BI X, et al. Subsurface A-site vacancy activates lattice oxygen in perovskite ferrites for methane anaerobic oxidation to syngas. Nature Communications, 2024, 15: 5422. DOI PMID
[48]	YANG J, SHI L, LI L, et al. Surface modification of macroporous La_0.8Sr_0.2CoO₃ perovskite oxides integrated monolithic catalysts for improved propane oxidation. Catalysis Today, 2021, 376: 168.
[49]	DAI L, LU X B, CHU G H, et al. Surface tuning of LaCoO₃ perovskite by acid etching to enhance its catalytic performance. Rare Metals, 2021, 40(3): 555.
[50]	BAI S, ZHANG N, GAO C, et al. Defect engineering in photocatalytic materials. Nano Energy, 2018, 53: 296.
[51]	FANG Z, BUEKEN B, DE VOS D E, et al. Defect-engineered metal-organic frameworks. Angewandte Chemie International Edition, 2015, 54(25): 7234.
[52]	ARANDIYAN H, MOFARAH S S, SORRELL C C, et al. Defect engineering of oxide perovskites for catalysis and energy storage: synthesis of chemistry and materials science. Chemical Society Reviews, 2021, 50(18): 10116. DOI PMID
[53]	CHEN H, WEI G, LIANG X, et al. The distinct effects of substitution and deposition of Ag in perovskite LaCoO₃ on the thermally catalytic oxidation of toluene. Applied Surface Science, 2019, 489: 905.
[54]	ZHANG C H, WANG C, GIL S, et al. Catalytic oxidation of 1,2-dichloropropane over supported LaMnO_x oxides catalysts. Applied Catalysis B: Environmental, 2017, 201: 552.
[55]	CHEN B, WEN Y, GAO S, et al. Mechanistic insights into the role of acidity to activity and anti-poisoning over Nb based catalysts for CVOCs combustion. Applied Catalysis A: General, 2022, 636: 118581.
[56]	LI X, CHEN D, LI N, et al. Highly efficient Pd catalysts loaded on La_1-_xSr_xMnO₃ perovskite nanotube support for low-temperature toluene oxidation. Journal of Alloys and Compounds, 2021, 871: 159575.
[57]	GIROIR-FENDLER A, ALVES-FORTUNATO M, RICHARD M, et al. Synthesis of oxide supported LaMnO₃ perovskites to enhance yields in toluene combustion. Applied Catalysis B: Environmental, 2016, 180: 29.
[58]	ALIFANTI M, FLOREA M, SOMACESCU S, et al. Supported perovskites for total oxidation of toluene. Applied Catalysis B: Environmental, 2005, 60(1/2): 33.
[59]	DENG L, HUANG C, KAN J, et al. Effect of coating modification of cordierite carrier on catalytic performance of supported NiMnO₃ catalysts for VOCs combustion. Journal of Rare Earths, 2018, 36(3): 265.
[60]	QI S, TAO Y, JIANG S, et al. CeO₂ supported MOFs derived LaB_xFe_yO₃ (B=Mn, Co) perovskite catalysts for degradation of toluene. Environmental Science and Pollution Research, 2023, 30(15): 45414.
[61]	耿俊, 柯权力, 周文茜, 等. 催化燃烧催化剂抗硫性的研究进展. 燃料化学学报, 2022, 50(5): 564.
[62]	YANG C, MIAO G, PI Y, et al. Abatement of various types of VOCs by adsorption/catalytic oxidation: a review. Chemical Engineeing Journal, 2019, 370: 1128.
[63]	HE C, LI P, CHENG J, et al. A comprehensive study of deep catalytic oxidation of benzene, toluene, ethyl acetate, and their mixtures over Pd/ZSM-5 catalyst: mutual effects and kinetics. Water, Air, & Soil Pollution, 2010, 209: 365.
[64]	MARS P, VAN KREVELEN D W. Oxidations carried out by means of vanadium oxide catalysts. Chemical Engineering Science, 1954, 3: 41.
[65]	BEHAR S, GÓMEZ-MENDOZA N A, GÓMEZ-GARCÍA M Á, et al. Study and modelling of kinetics of the oxidation of VOC catalyzed by nanosized Cu-Mn spinels prepared via an alginate route. Applied Catalysis A: General, 2015, 504: 203.
[66]	LENG Y, CAO X, SUN X, et al. Catalytic oxidation mechanism of toluene on the Ce_0.875Zr_0.125O₂ (110) surface. Catalysts, 2023, 14(1): 22.
[67]	LI X, WANG X, DING J, et al. Engineering active surface oxygen sites of cubic perovskite cobalt oxides toward catalytic oxidation reactions. ACS Catalysis, 2023, 13(9): 6338.
[68]	ZHANG Z, JIANG Z, SHANGGUAN W. Low-temperature catalysis for VOCs removal in technology and application: a state-of-the-art review. Catalysis Today, 2016, 264: 270.
[69]	ZONOUZ P R, NIAEI A, TARJOMANNEJAD A. Kinetic modeling of CO oxidation over La_1-_xA_xMn_0.6Cu_0.4O₃ (A=Sr and Ce) nanoperovskite-type mixed oxides. International Journal of Environmental Science and Technology, 2016, 13(7): 1665.
[70]	ZABIHI M, KHORASHEH F, SHAYEGAN J. Studies on the catalyst preparation methods and kinetic behavior of supported cobalt catalysts for the complete oxidation of cyclohexane. Reaction Kinetics, Mechanisms and Catalysis, 2015, 114(2): 611.
[71]	ARANZABAL A, AYASTUY-ARIZTI J L, GONZÁLEZ- MARCOS J A, et al. The reaction pathway and kinetic mechanism of the catalytic oxidation of gaseous lean TCE on Pd/alumina catalysts. Journal of Catalysis, 2003, 214(1): 130.
[72]	AO R, MA L, GUO Z, et al. NO oxidation performance and kinetics analysis of BaMO₃ (M=Mn, Co) perovskite catalysts. Environmental Science and Pollution Research International, 2021, 28(6): 6929.

钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展

Research Progress on Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 72

相关文章 15

编辑推荐

Metrics

本文评价

[1]	江宗玉, 黄红花, 清江, 王红宁, 姚超, 陈若愚. 铝离子掺杂MIL-101(Cr)的制备及其VOCs吸附性能研究[J]. 无机材料学报, 2025, 40(7): 747-753.
[2]	胡智超, 杨鸿宇, 杨鸿程, 孙成礼, 杨俊, 李恩竹. P-V-L键理论在微波介质陶瓷性能调控中的应用[J]. 无机材料学报, 2025, 40(6): 609-626.
[3]	吴琼, 沈炳林, 张茂华, 姚方周, 邢志鹏, 王轲. 铅基织构压电陶瓷研究进展[J]. 无机材料学报, 2025, 40(6): 563-574.
[4]	张碧辉, 刘小强, 陈湘明. Ruddlesden-Popper结构杂化非常规铁电体的研究进展[J]. 无机材料学报, 2025, 40(6): 587-608.
[5]	吴杰, 杨帅, 王明文, 李景雷, 李纯纯, 李飞. 铅基织构压电陶瓷的发展历程、现状与挑战[J]. 无机材料学报, 2025, 40(6): 575-586.
[6]	姜昆, 李乐天, 郑木鹏, 胡永明, 潘勤学, 吴超峰, 王轲. PZT陶瓷的低温烧结研究进展[J]. 无机材料学报, 2025, 40(6): 627-638.
[7]	田睿智, 兰正义, 殷杰, 郝南京, 陈航榕, 马明. 基于微流控技术的纳米无机生物材料制备: 原理及其研究进展[J]. 无机材料学报, 2025, 40(4): 337-347.
[8]	张继国, 吴田, 赵旭, 杨钒, 夏天, 孙士恩. 钠离子电池正极材料循环稳定性提升策略及产业化进程[J]. 无机材料学报, 2025, 40(4): 348-362.
[9]	殷杰, 耿佳毅, 王康龙, 陈忠明, 刘学建, 黄政仁. SiC陶瓷的3D打印成形与致密化新进展[J]. 无机材料学报, 2025, 40(3): 245-255.
[10]	谌广昌, 段小明, 朱金荣, 龚情, 蔡德龙, 李宇航, 杨东雷, 陈彪, 李新民, 邓旭东, 余瑾, 刘博雅, 何培刚, 贾德昌, 周玉. 直升机特定结构先进陶瓷材料研究进展与应用展望[J]. 无机材料学报, 2025, 40(3): 225-244.
[11]	范晓波, 祖梅, 杨向飞, 宋策, 陈晨, 王子, 罗文华, 程海峰. 质子调控型电化学离子突触研究进展[J]. 无机材料学报, 2025, 40(3): 256-270.
[12]	海热古·吐逊, 郭乐, 丁嘉仪, 周嘉琪, 张学良, 努尔尼沙·阿力甫. 上转换荧光探针辅助的光学成像技术在肿瘤显影中的应用研究进展[J]. 无机材料学报, 2025, 40(2): 145-158.
[13]	孙树娟, 郑南南, 潘昊坤, 马猛, 陈俊, 黄秀兵. 单原子催化剂制备方法的研究进展[J]. 无机材料学报, 2025, 40(2): 113-127.
[14]	陶桂龙, 支国伟, 罗添友, 欧阳佩东, 衣新燕, 李国强. 空腔型薄膜体声波滤波器的关键技术进展[J]. 无机材料学报, 2025, 40(2): 128-144.
[15]	周帆, 田志林, 李斌. 热防护系统用碳化物超高温陶瓷抗烧蚀涂层研究进展[J]. 无机材料学报, 2025, 40(1): 1-16.