多功能MXene油墨：面向印刷能源及电子器件的新视角

doi:10.15541/jim20230437

无机材料学报 ›› 2024, Vol. 39 ›› Issue (2): 195-203.DOI: 10.15541/jim20230437 CSTR: 32189.14.10.15541/jim20230437

所属专题：【信息功能】敏感陶瓷（202409）；【制备方法】3D打印(202409)；【信息功能】MAX层状材料、MXene及其他二维材料(202409)

多功能MXene油墨：面向印刷能源及电子器件的新视角

邓顺桂¹^,²(), 张传芳¹()

1.四川大学材料科学与工程学院, 成都 610065
2.瑞士联邦理工学院联邦材料科学与技术研究所, 杜本多夫CH-8600, 瑞士

收稿日期:2023-09-24 修回日期:2023-10-15 出版日期:2023-11-10 网络出版日期:2023-11-10
通讯作者: 张传芳, 教授. E-mail: chuanfang.zhang@scu.edu.cn
作者简介:邓顺桂(1996-), 男, 博士研究生. E-mail: shungui.deng@empa.ch
基金资助:
国家自然科学基金(22209118);国家自然科学基金(00301054A1073);国家自然科学基金(20826044D3083);国家自然科学基金(20822041G4080);国家自然科学基金(1082204112A26)

MXene Multifunctional Inks: a New Perspective toward Printable Energy-related Electronic Devices

DENG Shungui¹^,²(), ZHANG Chuanfang¹()

1. College of Materials Science & Engineering, Sichuan University, Chengdu 610065, China
2. Laboratory for Functional Polymers, Swiss Federal Laboratories for Materials Science and Technology, Dübendorf CH-8600, Switzerland

Received:2023-09-24 Revised:2023-10-15 Published:2023-11-10 Online:2023-11-10
Contact: ZHANG Chuanfang, professor. E-mail: chuanfang.zhang@scu.edu.cn
About author:DENG Shungui (1996-), male, PhD candidate. E-mail: shungui.deng@empa.ch
Supported by:
National Natural Science Foundation of China(22209118);National Natural Science Foundation of China(00301054A1073);National Natural Science Foundation of China(20826044D3083);National Natural Science Foundation of China(20822041G4080);National Natural Science Foundation of China(1082204112A26)

摘要/Abstract

摘要：

基于功能油墨的先进印刷技术(打印、涂布), 能够突破传统制造手段的瓶颈, 实现具有复杂结构和特定功能的个性化薄膜及电子器件的快速成型, 在可穿戴智能识别、能源存储、电磁屏蔽及吸波、触摸显示等领域展现出巨大的应用前景。印刷先进能源及电子器件的关键在于, 开发先进功能油墨材料和与之相匹配的先进印刷技术。2011年发现的MXene材料, 是一类由过渡金属碳化物、氮化物或碳氮化物所组成的二维大家族的总称, 因其卓越的物理和化学性质(如高电导率、出色的亲水性和丰富的表面化学)而受到广泛关注, 特别适合作为印刷电子器件的油墨材料。探索MXene油墨的印刷行为特征并厘清MXene油墨在印刷关键环节中的机理, 不仅有助于获得高精度的MXene油墨印刷图案, 而且可以为印刷多尺度、多材料的多功能薄膜和电子器件打下了坚实基础。本文首先介绍了MXene的制备及其片层胶体的化学稳定性, 并对其流变学特性、可打印油墨的形成、油墨印刷行为以及与之适配的打印方法进行了讨论, 着眼于MXene油墨在能源、健康监测和传感应用方面的最新进展, 分析了该领域面临的挑战和未来的发展方向, 为该领域的研究者提供新的视角和启示。

关键词: 印刷电子, 功能油墨, MXene, 增材制造, 健康监测, 专题评述

Abstract:

Advanced ink printing techniques, such as printing and coating, have overcome the limitations of traditional manufacturing methods, allowing for rapid prototyping of films and electronic devices with sophisticated structures and specific functions. These techniques hold enormous potential in wearable smart identification, energy storage, electromagnetic shielding and absorption, touch display, and so on. The key to printing advanced energy and electronic devices lies in the development of cutting-edge functional inks and their corresponding printing technologies. MXene, a family of two-dimensional compounds composed of transition metal carbides, nitrides, or carbonitrides, was discovered in 2011. MXene exhibits remarkable physical and chemical properties, including high conductivity, pronounced hydrophilicity, and diverse surface chemistry, which has garnered significant attention within the research community and made it particularly suitable as inks in printing applications. Conducting research on the printing behavior and mechanisms of MXene inks is crucial not only for achieving high-precision patterns but also for establishing a solid foundation for manufacturing techniques that can precisely create multiscale, multimaterial and multifunctional films, and electronic devices. This article begins with a brief discussion of MXene flakes’ synthesis and colloidal stability, followed by a detailed examination of its rheological characteristics, printable ink formulation, and printing methods. Additional, special attention is given to the latest advances of MXene ink in energy, health, and sensing applications. The perspective concludes with a summary of current research challenges and future directions in this area, offering new perspectives and insights for researchers.

Key words: printing, functional ink, MXene, additive manufacturing, health monitoring, perspective

中图分类号:

TB34

邓顺桂, 张传芳. 多功能MXene油墨：面向印刷能源及电子器件的新视角[J]. 无机材料学报, 2024, 39(2): 195-203.

DENG Shungui, ZHANG Chuanfang. MXene Multifunctional Inks: a New Perspective toward Printable Energy-related Electronic Devices[J]. Journal of Inorganic Materials, 2024, 39(2): 195-203.

图/表 6

图1 新鲜MXene片层存放(a, c) 7 d和(b, d) 30 d后的透射电子显微镜(TEM)照片[29]

Fig. 1 TEM images of MXene flakes aged for (a, c) 7 d and (b, d) 30 d[29]

图2 MXene油墨的四种主要印刷技术的示意图

Fig. 2 Diagram of the four main printing technologies for MXene ink Screen printing[37], inkjet printing[38], transfer printing[39] and extrusion printing[40]

图3 四种主要印刷技术的通量、所需油墨黏度和打印分辨率之间的对比

Fig. 3 Relationship between throughput, ink viscosity and resolution provided for the four major printing methods

图4 MXene油墨打印示意图[38]

Fig. 4 Schematic illustration of direct MXene ink printing[38] Aqueous Ti3C2Tx inks are designed for extrusion printing while the Ti3C2Tx organic inks are used for inkjet printing

图5 MXene油墨的发展时间线路图[29,37⇓ -39,52]

Fig. 5 Milestone of the origin and development of MXene ink[29,37⇓ -39,52]

图6 (a)用于柔性无线电子的室温直接打印的MXene油墨; (b)MXene RFID传感器及(c)其照片; (d)MXene RFID传感器监测表面温度示例; (e)MXene NFC的制作及(f)应用示例[53]

Fig. 6 (a) Schematic illustration of room-temperature direct printing of additive-free MXene inks for flexible wireless electronics; (b) Mechanism and (c) optical image of flexible MXene RFID temperature tag; (d) MXene RFID sensors to monitor surface temperature; (e) Fabrication of MXene NFC tags and (f) examples of application[53]

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多功能MXene油墨：面向印刷能源及电子器件的新视角

MXene Multifunctional Inks: a New Perspective toward Printable Energy-related Electronic Devices

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