g-C3N4光催化性能的研究进展

doi:10.15541/jim20130633

摘要/Abstract

摘要：

利用光催化剂将太阳能转化为人类可以直接利用的能量, 并用其解决地球资源的枯竭和生存环境的恶化是可再生清洁能源研究的一个方向。g-C₃N₄的独特结构赋予其良好的光催化性能, 使之成为光催化领域的研究热点。目前在光催化领域, g-C₃N₄主要用于催化污染物分解、水解制氢制氧、有机合成及氧气还原。在实际应用中, 为进一步提高g-C₃N₄的光催化效果, 科研工作者开发了多种改进方法, 例如物理复合改性、化学掺杂改性、微观结构调整等。本文主要论述了g-C₃N₄在光催化领域的应用以及光催化性能的改进方法, 简要阐述了光催化和各种改进方法的机理, 分析了目前g-C₃N₄在光催化领域面临的问题和挑战, 展望了g-C₃N₄的应用前景。

关键词: g-C3N4, 光催化, 改进方法, 综述

Abstract:

Based on photocatalysts, solar energy can be converted into the energy that human can directly utilize, so as to solve the problems such as the depletion of the Earth’s resources and the deterioration of living environments. The unique structure of g-C₃N₄ gives it good photocatalytic performance. Its development and utilization have been a research hotspot recently. Generally, g-C₃N₄ can be used in the degradation of pollutions, hydrolysis to generate hydrogen and oxygen, organic synthesis and oxygen reduction. However, in practical, its performance is not satisfactory. Researchers have tried many new methods to improve its photocatalysis, which include physical coupling modification, chemical bonding modification and microstructural modification. The review summarizes its photocatalysis and improving methods, briefly illustrates the catalysis mechanism, and presents detailed discussions and analysis on the existing problems as well as potential applications.

Key words: g-C3N4, photocatalysis, improving methods, review

中图分类号:

TB321

楚增勇，原博，颜廷楠. g-C₃N₄光催化性能的研究进展[J]. 无机材料学报, 2014, 29(8): 785-794.

CHU Zeng-Yong, YUAN Bo, YAN Ting-Nan. Recent Progress in Photocatalysis of g-C₃N₄[J]. Journal of Inorganic Materials, 2014, 29(8): 785-794.

图/表 8

参考文献 99

[1]	TADA H, JIN Q, NISHIJIMA H, et al. Titanium(IV) dioxide surface-modified with iron oxide as a visible light photocatalyst. Angewandte Chemie International Edition, 2011, 50(15): 3501-3505.
[2]	XU T, ZHANG L, CHENG H, et al. Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study. Applied Catalysis B: Environmental, 2011, 101(3/4): 382-387.
[3]	HE K, LI M, GUO L. Preparation and photocatalytic activity of PANI-CdS composites for hydrogen evolution. International Journal of Hydrogen Energy, 2012, 37(1): 755-759.
[4]	MIAO Y, PAN G, HUO Y, et al. Aerosol-spraying preparation of Bi2MoO6: a visible photocatalyst in hollow microspheres with a porous outer shell and enhanced activity. Dyes and Pigments, 2013, 99(2): 382-389.
[5]	WANG Y, SHI Z, FAN C, et al. Synthesis, characterization, and photocatalytic properties of BiOBr catalyst . Journal of Solid State Chemistry, 2013, 199: 224-229.
[6]	BAI S, SHEN X, LV H, et al. Assembly of Ag3PO4 nanocrystals on graphene-based nanosheets with enhanced photocatalytic performance. Journal of Colloid and Interface Science, 2013, 405: 1-9.
[7]	WANG X, BLECHERT S, ANTONIETTI M. Polymeric graphitic carbon nitride for heterogeneous photocatalysis. ACS Catalysis, 2012, 2(8): 1596-1606.
[8]	WANG F, NG W K H, YU J C, et al. Red phosphorus: an elemental photocatalyst for hydrogen formation from water. Applied Catalysis B: Environmental, 2012, 111-112: 409-414.
[9]	LI C, CAO C B, ZHU H S. Graphitic carbon nitride thin films deposited by electrodeposition. Materials Letters, 2004, 58(12/13): 1903-1906.
[10]	LOTSCH B V, SCHNICK W. From triazines to heptazines: novel nonmetal tricyanomelaminates as precursors for graphitic carbon nitride materials. Chemistry of Materials, 2006, 18(7): 1891-1900.
[11]	WIRNHIER E, D BLINGER M, GUNZELMANN D, et al. Poly(triazine imide) with intercalation of lithium and chloride ions [(C3N3)2(NHxLi1-x)3•LiCl]: a crystalline 2D carbon nitride network. Chemistry - A European Journal, 2011, 17(11): 3213-3221.
[12]	ZHANG X, XIE X, WANG H, et al. Enhanced photoresponsive ultrathin graphitic-phase C3N4 nanosheets for bioimaging. Journal of the American Chemical Society, 2013, 135(1): 18-21.
[13]	BOJDYS M J,M LLER J O, ANTONIETTI M, et al. Ionothermal synthesis of crystalline, condensed, graphitic carbon nitride. Chemistry - A European Journal, 2008, 14(27): 8177-8182.
[14]	WU F, LIU Y, YU G, et al. Visible-light-absorption in graphitic C3N4 bilayer: enhanced by interlayer coupling. The Journal of Physical Chemistry Letters, 2012, 3(22): 3330-3334.
[15]	HUANG Z, LI F, CHEN B, et al. Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion. Applied Catalysis B: Environmental, 2013, 136-137: 269-277.
[16]	KROKE E, SCHWARZ M, HORATH-BORDON E, et al. Tri-s-triazine derivatives. Part I. From trichloro-tri-s-triazine to graphitic C3N4 structures. New Journal of Chemistry, 2002, 26(5): 508-512.
[17]	MA H A, JIA X P, CHEN L X, et al. High-pressure pyrolysis study of C3NH6: a route to preparing bulk C3N4. Journal of Physics: Condensed Matter, 2002, 14(44): 11269-11273.
[18]	GUO Q, XIE Y, WANG X, et al. Characterization of well-crystal-lized graphitic carbon nitride nanocrystallites via a benzene-thermal route at low temperatures. Chemical Physics Letters, 2003, 380(1/2): 84-87.
[19]	LI Y, ZHANG J, WANG Q, et al. Nitrogen-rich carbon nitride hollow vessels: synthesis, characterization, and their properties. The Journal of Physical Chemistry B, 2010, 114(29): 9429-9434.
[20]	DONG F, WANG Z, SUN Y, et al. Engineering the nanoarchitecture and texture of polymeric carbon nitride semiconductor for enhanced visible light photocatalytic activity. Journal of Colloid and Interface Science, 2013, 401: 70-79.
[21]	XIN G, MENG Y. Pyrolysis synthesized g-C3N4 for photocatalytic degradation of methylene blue. Journal of Chemistry, 2013, 2013: 1-5.
[22]	JI H, CHANG F, HU X, et al. Photocatalytic degradation of 2,4,6-trichlorophenol over g-C3N4 under visible light irradiation. Chemical Engineering Journal, 2013, 218: 183-190.
[23]	LI X H, ZHANG J, CHEN X, et al. Condensed graphitic carbon nitride nanorods by nanoconfinement: promotion of crystallinity on photocatalytic conversion. Chemistry of Materials, 2011, 23(19): 4344-4348.
[24]	JORGE A B, MARTIN D J,DHANOA M T S, et al. H2 and O2 evolution from water half-splitting reactions by graphitic carbon nitride materials. The Journal of Physical Chemistry C, 2013, 117(14): 7178-7185.
[25]	DING G, WANG W, JIANG T, et al. Highly selective synthesis of phenol from benzene over a vanadium-doped graphitic carbon nitride catalyst. ChemCatChem, 2013, 5(1): 192-200.
[26]	ZHAI H S, CAO L, XIA X H. Synthesis of graphitic carbon nitride through pyrolysis of melamine and its electrocatalysis for oxygen reduction reaction. Chinese Chemical Letters, 2013, 24(2): 103-106.
[27]	ZHOU X, JIN B, CHEN R, et al. Synthesis of porous Fe3O4/g- C3N4 nanospheres as highly efficient and recyclable photocatalysts. Materials Research Bulletin, 2013, 48(4): 1447-1452.
[28]	LIU W, WANG M, XU C, et al. Significantly enhanced visible-light photocatalytic activity of g-C3N4 via ZnO modification and the mechanism study. Journal of Molecular Catalysis A: Chemical, 2013, 368-369: 9-15.
[29]	LIU G, NIU P, SUN C, et al. Unique electronic structure induced high photoreactivity of sulfur-doped graphitic C3N4. Journal of the American Chemical Society, 2010, 132(33): 11642-11648.
[30]	ZHAO S, CHEN S, YU H, et al. g-C3N4/TiO2 hybrid photocatalyst with wide absorption wavelength range and effective photogenerated charge separation. Separation and Purification Technology, 2012, 99: 50-54.
[31]	MIRANDA C, MANSILLA H, Yan E Z J, et al. Improved photocatalytic activity of g-C3N4/TiO2 composites prepared by a simple impregnation method. Journal of Photochemistry and Photobiology A: Chemistry, 2013, 253: 16-21.
[32]	LIAO G, CHEN S, QUAN X, et al. Graphene oxide modified g-C3N4 hybrid with enhanced photocatalytic capability under visible light irradiation. Journal of Materials Chemistry, 2012, 22(6): 2721-2726.
[33]	SUN C, CHEN C, MA W, et al. Photocatalytic debromination of decabromodiphenyl ether by graphitic carbon nitride . Science ChinaChemistry, 2012, 55(12): 2532-2536.
[34]	KATSUMATA K I, MOTOYOSHI R, MATSUSHITA N, et al. Preparation of graphitic carbon nitride (g-C3N4)/WO3 composites and enhanced visible-light-driven photodegradation of acetaldehyde gas. Journal of Hazardous Materials, 2013, 260: 475-482.
[35]	KONDO K, MURAKAMI N, YE C, et al. Development of highly efficient sulfur-doped TiO2 photocatalysts hybridized with graphitic carbon nitride. Applied Catalysis B: Environmental, 2013, 142-143: 362-367.
[36]	LIU W, WANG M, XU C, et al. Facile synthesis of g-C3N4/ZnO composite with enhanced visible light photooxidation and photoreduction properties. Chemical Engineering Journal, 2012, 209: 386-393.
[37]	DONG G, ZHANG L. Synthesis and enhanced Cr(VI) photoreduction property of formate anion containing graphitic carbon nitride. The Journal of Physical Chemistry C, 2013, 117(8): 4062-4068.
[38]	SANO T, TSUTSUI S, KOIKE K, et al. Activation of graphitic carbon nitride (g-C3N4) by alkaline hydrothermal treatment for photocatalytic NO oxidation in gas phase. Journal of Materials Chemistry A, 2013, 1(21): 6489-6496.
[39]	YANG S, GONG Y, ZHANG J, et al. Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light. Advanced Materials, 2013, 25(17): 2452-2456.
[40]	SHAO-WEN C, YU-PENG Y, JUN F, et al. In-situ growth of CdS quantum dots on g-C3N4 nanosheets for highly efficient photocatalytic hydrogen generation under visible light irradiation .International Journal of Hydrogen Energy, 2013, 38(3): 1258-1266.
[41]	GE L, HAN C, XIAO X, et al. Synthesis and characterization of composite visible light active photocatalysts MoS2-g-C3N4 with enhanced hydrogen evolution activity. International Journal of Hydrogen Energy, 2013, 38(17): 6960-6969.
[42]	WANG X, MAEDA K, THOMAS A, et al. A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater., 2009, 8(1): 76-80.
[43]	HONG J, WANG Y, WANG Y, et al. Noble-metal-free NiS/C3N4 for efficient photocatalytic hydrogen evolution from water. ChemSusChem, 2013: 1-7.
[44]	CHU S, WANG Y, GUO Y, et al. Band structure engineering of carbon nitride: in search of a polymer photocatalyst with high photooxidation property. ACS Catalysis, 2013, 3(5): 912-919.
[45]	SU F, MATHEW S C, LIPNER G, et al. mpg-C3N4-catalyzed selective oxidation of alcohols using O2 and visible light. Journal of the American Chemical Society, 2010, 132(46): 16299-16301.
[46]	LI X H, CHEN J S, WANG X, et al. Metal-free activation of dioxygen by graphene/g-C3N4 nanocomposites: functional dyads for selective oxidation of saturated hydrocarbons. Journal of the American Chemical Society, 2011, 133(21): 8074-8077.
[47]	LI X H, WANG X, ANTONIETTI M. Solvent-free and metal-free oxidation of toluene using O2 and g-C3N4 with nanopores: nanostructure boosts the catalytic selectivity. ACS Catalysis, 2012, 2(10): 2082-2086.
[48]	ZHANG P, WANG Y, YAO J, et al. Visible-light-induced metal-free allylic oxidation utilizing a coupled photocatalytic system of g-C3N4 and N-Hydroxy compounds. Advanced Synthesis & Catalysis, 2011, 353(9): 1447-1451.
[49]	YUAN Y P, CAO S W, LIAO Y S, et al. Red phosphor/g-C3N4 heterojunction with enhanced photocatalytic activities for solar fuels production. Applied Catalysis B: Environmental, 2013, 140-141: 164-168.
[50]	TAN B, XU J, XUE B, et al. Mesoporous graphitic carbon nitride: synthesis and application towards knoevenagel condensation reactions. Chemistry, 2013, 76(2): 150-156.
[51]	NIU P, ZHANG L, LIU G, et al. Graphene-like carbon nitride nanosheets for improved photocatalytic activities. Advanced Functional Materials, 2012, 22(22): 4763-4770.
[52]	JIN X, BALASUBRAMANIAN V V, SELVAN S T, et al. Highly ordered mesoporous carbon nitride nanoparticles with high nitrogen content: a metal-free basic catalyst. Angewandte Chemie, 2009, 121(42): 8024-8027.
[53]	GOETTMANN F, FISCHER A, ANTONIETTI M, et al. Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for friedel-crafts reaction of benzene. Angewandte Chemie International Edition, 2006, 45(27): 4467-4471.
[54]	SONG L, ZHANG S, WU X, et al. Graphitic C3N4 photocatalyst for esterification of benzaldehyde and alcohol under visible light radiation. Industrial & Engineering Chemistry Research, 2012, 51(28): 9510-9514.
[55]	SU F, MATHEW S C, M HLMANN L, et al. Aerobic oxidative coupling of amines by carbon nitride photocatalysis with visible light. Angewandte Chemie International Edition, 2011, 50(3): 657-660.
[56]	IKEDA T, BOERO M, HUANG S F, et al. Carbon alloy catalysts: active sites for oxygen reduction reaction. The Journal of Physical Chemistry C, 2008, 112(38): 14706-14709.
[57]	ZHENG Y, LIU J, LIANG J, et al. Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis. Energy & Environmental Science, 2012, 5(5): 6717-6731.
[58]	ASPERA S M, KASAI H, KAWAI H. Density functional theory-based analysis on O2 molecular interaction with the tri-s- triazine-based graphitic carbon nitride. Surface Science, 2012, 606(11-12): 892-901.
[59]	ZHENG Y, JIAO Y, JARONIEC M, et al. Nanostructured metal-free electrochemical catalysts for highly efficient oxygen reduction. Small, 2012, 8(23): 3550-3566.
[60]	JIN J, FU X, LIU Q, et al. A highly active and stable electrocatalyst for the oxygen reduction reaction based on a graphene-supported g-C3N4@cobalt oxide core-shell hybrid in alkaline solution. Journal of Materials Chemistry A, 2013, 1(35): 10538-10545.
[61]	LIU Q, ZHANG J. Graphene supported Co-g-C3N4 as a novel metal-macrocyclic electrocatalyst for the oxygen reduction reaction in fuel cells. Langmuir, 2013, 29(11): 3821-3828.
[62]	ZHENG Y, JIAO Y, CHEN J, et al. Nanoporous graphitic- C3 N4@carbon metal-free electrocatalysts for highly efficient oxygen reduction. Journal of the American Chemical Society, 2011, 133(50): 20116-20119.
[63]	LI S, WANG J T, CHEN X Y, et al. Catalytic performance of heat-treated Fe-melamine/C and Fe-g-C3N4/C electrocatalysts for oxygen reduction reaction. Acta Phys. -Chim. Sin., 2013, 29(4): 792-798.
[64]	BU Y, CHEN Z, YU J, et al. A novel application of g-C3N4 thin film in photoelectrochemical anticorrosion. Electrochimica Acta, 2013, 88: 294-300.
[65]	LI X H, KURASCH S, KAISER U, et al. Synthesis of monolayer- patched graphene from glucose. Angewandte Chemie International Edition, 2012, 51(38): 9689-9692.
[66]	ZHANG Y, ANTONIETTI M. Phosphorus-doped carbon nitride solid enhanced electrical conductivity and photocurrent generation . Chemistry - An Asian Journal, 2010, 132(18): 6294-6295.
[67]	XU L, XIA J, XU H, et al. Reactable ionic liquid assisted solvothermal synthesis of graphite-like C3N4 hybridized α-Fe2O3 hollow microspheres with enhanced supercapacitive performance. Journal of Power Sources, 2014, 245: 866-874.
[68]	TIAN J, LIU Q, ASIRI A M, et al. Ultrathin graphitic carbon nitride nanosheet: a highly efficient fluorosensor for rapid, ultrasensitive detection of Cu2+. Analytical Chemistry, 2013, 85(11): 5595-5599.
[69]	CHENG C, HUANG Y, TIAN X, et al. Electrogenerated chemiluminescence behavior of graphite-like carbon nitride and its application in selective sensing Cu2+. Analytical Chemistry, 2012, 84(11): 4754-4759.
[70]	XU H, YAN J, XU Y, et al. Novel visible-light-driven AgX/graphite-like C3N4 (X=Br, I) hybrid materials with synergistic photocatalytic activity. Applied Catalysis B: Environmental, 2013, 129: 182-193.
[71]	YU J, WANG S, LOW J, et al. Enhanced photocatalytic performance of direct Z-scheme g-C3N4-TiO2 photocatalysts for the decomposition of formaldehyde in air. Physical Chemistry Chemical Physics, 2013, 15(39): 16883-16890.
[72]	LI T, ZHAO L, HE Y, et al. Synthesis of g-C3N4/SmVO4 composite photocatalyst with improved visible light photocatalytic activities in RhB degradation. Applied Catalysis B: Environmental, 2013, 129: 255-263.
[73]	GUI M S, WANG P F, YUAN D, et al. Synthesis and visible-light photocatalytic activity of Bi2WO6/g-C3N4 composite photocatalysts. Chinese Journal of Inorganic Chemistry, 2013, 29(10): 2057-2064.
[74]	XIANG Q, YU J, JARONIEC M. Preparation and enhanced visible-light photocatalytic H2-production activity of graphene /C3N4 composites. The Journal of Physical Chemistry C, 2011, 115(15): 7355-7363.
[75]	SURYAWANSHI A, DHANASEKARAN P, MHAMANE D, et al. Doubling of photocatalytic H2 evolution from g-C3N4 via its nanocomposite formation with multiwall carbon nanotubes: electronic and morphological effects. International Journal of Hydrogen Energy, 2012, 37(12): 9584-9589.
[76]	YAN H, HUANG Y. Polymer composites of carbon nitride and poly(3-hexylthiophene) to achieve enhanced hydrogen production from water under visible light. Chemical Communications, 2011, 47(14): 4168-4170.
[77]	GE L, HAN C, LIU J. In situ synthesis and enhanced visible light photocatalytic activities of novel PANI-g-C3N4 composite photocatalysts. Journal of Materials Chemistry, 2012, 22(23): 11843-11850.
[78]	MIN S, LU G. Enhanced electron transfer from the excited eosin Y to mpg-C3N4 for highly efficient hydrogen evolution under 550 nm irradiation. The Journal of Physical Chemistry C, 2012, 116(37): 19644-19652.
[79]	SUN A W, CHEN H, SONG C Y, et al. Synthesis of Bi25FeO40- g-C3N4 magnetic catalyst and its photocatalytic performance.Environmental Chemistry, 2013, 32(5): 748-754.
[80]	HE Y, CAI J, LI T, et al. Efficient degradation of RhB over GdVO4/g-C3N4 composites under visible-light irradiation. Chemical Engineering Journal, 2013, 215-216: 721-730.
[81]	HE Y, CAI J, LI T, et al. Synthesis, characterization, and activity evaluation of DyVO4/g-C3N4 composites under visible-light irradiation. Industrial & Engineering Chemistry Research, 2012, 51(45): 14729-14737.
[82]	HOU Y, WEN Z, CUI S, et al. Constructing 2D porous graphitic C3N4 nanosheets/nitrogen-doped graphene/layered MoS2 ternary nanojunction with enhanced photoelectrochemical activity. Advanced Materials, 2013, 25(43): 1-7.
[83]	ZHANG J, ZHANG G, CHEN X, et al. Co-monomer control of carbon nitride semiconductors to optimize hydrogen evolution with visible light. Angewandte Chemie International Edition, 2012, 51(13): 3183-3187.
[84]	ZHANG J, CHEN X, TAKANABE K, et al. Synthesis of a carbon nitride structure for visible-light catalysis by copolymerization. Angewandte Chemie International Edition, 2010, 49(2): 441-444.
[85]	ZHENG H R, ZHANG J S, WANG X C, et al. Modification of carbon nitride phtocatalysts by copolymerization with diaminomaleonitrile. Acta Phys. Chim. Sin., 2012, 28(10): 2336-2342.
[86]	YAN S C, LI Z S, ZOU Z G. Photodegradation of rhodamine B and methyl orange over boron-doped g-C3N4 under visible light irradiation. Langmuir, 2010, 26(6): 3894-3901.
[87]	WANG Y, DI Y, ANTONIETTI M, et al. Excellent visible-light photocatalysis of fluorinated polymeric carbon nitride solids. Chemistry of Materials, 2010, 22(18): 5119-5121.
[88]	GE L, HAN C, XIAO X, et al. Enhanced visible light photocatalytic hydrogen evolution of sulfur-doped polymeric g-C3N4 photocatalysts. Materials Research Bulletin, 2013, 48(10): 3919-3925.
[89]	CHEN G, GAO S P. Structure and electronic structure of S-doped graphitic C3N4 investigated by density functional theory. Chinese Physics B, 2012, 21(10): 384-390.
[90]	DONG G, ZHAO K, ZHANG L. Carbon self-doping induced high electronic conductivity and photoreactivity of g-C3N4. Chemical Communications, 2012, 48(49): 6178-6180.
[91]	WANG Y, ZHANG J, WANG X, et al. Boron- and fluorine- containing mesoporous carbon nitride polymers: metal-free catalysts for cyclohexane oxidation. Angewandte Chemie International Edition, 2010, 49(19): 3356-3359.
[92]	VINU A, ARIGA K, MORI T, et al. Preparation and characterization of well-ordered hexagonal mesoporous carbon nitride. Advanced Materials, 2005, 17(13): 1648-1652.
[93]	CHEN X, JUN Y S, TAKANABE K, et al. Ordered mesoporous SBA-15 type graphitic carbon nitride: a semiconductor host structure for photocatalytic hydrogen evolution with visible light. Chemistry of Materials, 2009, 21(18): 4093-4095.
[94]	DONG G, ZHANG L. Porous structure dependent photoreactivity of graphitic carbon nitride under visible light. Journal of Materials Chemistry, 2012, 22(3): 1160-1166.
[95]	XU J, WANG Y, ZHU Y. Nanoporous graphitic carbon nitride with enhanced photocatalytic performance. Langmuir, 2013, 29(33): 10566-10572.
[96]	GROENEWOLT M, ANTONIETTI M. Synthesis of g-C3N4 nanoparticles in mesoporous silica host matrices. Advanced Materials, 2005, 17(14): 1789-1792.
[97]	BAI X, WANG L, ZONG R, et al. Photocatalytic activity enhanced via g-C3N4 nanoplates to nanorods. The Journal of Physical Chemistry C, 2013, 117(19): 9952-9961.
[98]	CHANG F, XIE Y, LI C, et al. A facile modification of g-C3N4 with enhanced photocatalytic activity for degradation of methylene blue. Applied Surface Science, 2013, 280: 967-974.
[99]	CHENG N, TIAN J, LIU Q, et al. Au-nanoparticle-loaded graphitic carbon nitride nanosheets: green photocatalytic synthesis and application toward the degradation of organic pollutants. ACS Applied Materials & Interfaces, 2013, 5(15): 6815-6819.

Photocatalyt	Application	Photocatalytic performance <br/>of pure g-C₃N₄^[a]/ <br/>(min^-1 or μmol•g•h^-1)	photocatalytic performance <br/>of modified g-C₃N₄^[a]/ <br/>(min^-1 or μmol•g•h^-1)	Reference
Fe₂O₃/g-C₃N₄	Degradation of MO	0.0030	0.0163	[27]
AgX/g-C₃N₄(X=Br, I)	Degradation of MO	0.0006	0.1900^[b]<br/>0.0068^[c]	[70]
ZnO/g-C₃N₄	Degradation of RhB	0.0078	0.0239	[28]
SmVO₄/g-C₃N₄	Degradation of RhB	0.0143	0.0338	[72]
GdVO₄/g-C₃N₄	Degradation of RhB	0.0142	0.0434	[80]
DyVO₄/g-C₃N₄	Degradation of RhB	0.0142	0.0365	[81]
Formate anion/g-C₃N₄	Reduction of Cr(Ⅵ)	0.0010	0.0033	[37]
MoS₂/g-C₃N₄	Hydrogen generation by hydrolysis	0.15	23.10	[41]
CdS QDs/g-C₃N₄	Hydrogen generation by hydrolysis	38	4494	[40]
Gr/g-C₃N₄	Hydrogen generation by hydrolysis	147	451	[74]
P3HT/g-C₃N₄	Hydrogen generation by hydrolysis	1.8	555.0	[76]
TiO₂/g-C₃N₄	Degradation of phenol	0.022	0.053	[30]
g-C₃N₄/rGO/MoS₂	Degradation of MB	0.0054	0.0338	[82]
g-C₃N₄/rGO/MoS₂	Reduction of Cr(Ⅵ)	0.0028	0.0157	[82]
GO/g-C₃N₄	Degradation of RhB	0.0041	0.0156	[32]
GO/g-C₃N₄	Degradation of 2,4-DCP	0.0037	0.0077	[32]

Photocatalyt	Application	Photocatalytic performance <br/>of pure g-C₃N₄^[a]/ <br/>(min^-1 or μmol•g•h^-1)	photocatalytic performance <br/>of modified g-C₃N₄^[a]/ <br/>(min^-1 or μmol•g•h^-1)	Reference
Fe₂O₃/g-C₃N₄	Degradation of MO	0.0030	0.0163	[27]
AgX/g-C₃N₄(X=Br, I)	Degradation of MO	0.0006	0.1900^[b]<br/>0.0068^[c]	[70]
ZnO/g-C₃N₄	Degradation of RhB	0.0078	0.0239	[28]
SmVO₄/g-C₃N₄	Degradation of RhB	0.0143	0.0338	[72]
GdVO₄/g-C₃N₄	Degradation of RhB	0.0142	0.0434	[80]
DyVO₄/g-C₃N₄	Degradation of RhB	0.0142	0.0365	[81]
Formate anion/g-C₃N₄	Reduction of Cr(Ⅵ)	0.0010	0.0033	[37]
MoS₂/g-C₃N₄	Hydrogen generation by hydrolysis	0.15	23.10	[41]
CdS QDs/g-C₃N₄	Hydrogen generation by hydrolysis	38	4494	[40]
Gr/g-C₃N₄	Hydrogen generation by hydrolysis	147	451	[74]
P3HT/g-C₃N₄	Hydrogen generation by hydrolysis	1.8	555.0	[76]
TiO₂/g-C₃N₄	Degradation of phenol	0.022	0.053	[30]
g-C₃N₄/rGO/MoS₂	Degradation of MB	0.0054	0.0338	[82]
g-C₃N₄/rGO/MoS₂	Reduction of Cr(Ⅵ)	0.0028	0.0157	[82]
GO/g-C₃N₄	Degradation of RhB	0.0041	0.0156	[32]
GO/g-C₃N₄	Degradation of 2,4-DCP	0.0037	0.0077	[32]

Introduced<br/>component	Application	Photocatalytic performance of unmodified g-C₃N₄^[a]<br/>/(μmol•h^-1, min^-1 or %)	Photocatalytic performance<br/>of modified g-C₃N₄^[a]/<br/>(μmol•h^-1, min^-1 or %)	Reference
PMDA<br/>	Hydrogen generation by hydrolysis	7.0	20.6	[44]
	Oxygen generation by hydrolysis	0.8	7.7
	Degradation of MO	0.0050	0.0557
ABN<br/>	Hydrogen generation by hydrolysis	18^[b]	147^[b]	[83]
ABN<br/>	Hydrogen generation by hydrolysis	127^[c]	229^[c]	[83]
BA<br/>	Hydrogen generation by hydrolysis	148.2^[d]	253.1^[d]	[84]
BA<br/>	Hydrogen generation by hydrolysis	6.5^[e]	29.4^[e]	[84]
B, F	Oxidation of cyclohexane	1.6^[f]	5.3^[f]	[91]
F	Hydrogen generation by hydrolysis	4.9	13.0	[87]
F	Oxidation of benzene	0.0001	0.0021	[87]
S	Hydrogen generation by hydrolysis	20^[d]	160^[d]	[29]
S	Hydrogen generation by hydrolysis	10^[e]	75^[e]	[29]
B	Degradation of RhB	0.055	0.199	[86]
C	Degradation of RhB	0.0081	0.0362	[90]
	Reduction of Cr(Ⅵ)	0.0010	0.0017
	Hydrogen generation by hydrolysis	17.8	25.3

Introduced<br/>component	Application	Photocatalytic performance of unmodified g-C₃N₄^[a]<br/>/(μmol•h^-1, min^-1 or %)	Photocatalytic performance<br/>of modified g-C₃N₄^[a]/<br/>(μmol•h^-1, min^-1 or %)	Reference
PMDA<br/>	Hydrogen generation by hydrolysis	7.0	20.6	[44]
	Oxygen generation by hydrolysis	0.8	7.7
	Degradation of MO	0.0050	0.0557
ABN<br/>	Hydrogen generation by hydrolysis	18^[b]	147^[b]	[83]
ABN<br/>	Hydrogen generation by hydrolysis	127^[c]	229^[c]	[83]
BA<br/>	Hydrogen generation by hydrolysis	148.2^[d]	253.1^[d]	[84]
BA<br/>	Hydrogen generation by hydrolysis	6.5^[e]	29.4^[e]	[84]
B, F	Oxidation of cyclohexane	1.6^[f]	5.3^[f]	[91]
F	Hydrogen generation by hydrolysis	4.9	13.0	[87]
F	Oxidation of benzene	0.0001	0.0021	[87]
S	Hydrogen generation by hydrolysis	20^[d]	160^[d]	[29]
S	Hydrogen generation by hydrolysis	10^[e]	75^[e]	[29]
B	Degradation of RhB	0.055	0.199	[86]
C	Degradation of RhB	0.0081	0.0362	[90]
	Reduction of Cr(Ⅵ)	0.0010	0.0017
	Hydrogen generation by hydrolysis	17.8	25.3

Microstructure	Application	Photocatalytic performance of bulk g-C₃N₄^[a] <br/>/(μmol•h^-1, min^-1 or %)	Photocatalytic performance<br/>of modified g-C₃N₄^[a]/<br/>(μmol•h^-1, min^-1 or %)	Reference
Porous structure	Degradation of RhB	0.014	0.131	[94]
Porous structure	Oxidation of toluene	24^[b]	>99^[b]	[47]
Porous structure	Friedel-Crafts reaction of benzene	0^[c]	90^[c]	[53]
Nanosheet	Degradation of RhB	0.0012	0.0163	[20]
Nanorod	Hydrogen generation by hydrolysis	28	84	[23]
Nanorod	Hydrogen generation by hydrolysis	3.9	7	[23]
Nanorod	Degradation of MB	0.0017^[d]	0.0025^[d]	[97]
Nanorod	Degradation of MB	0.0021^[e]	0.0029^[e]	[97]
Nanosheet	Hydrogen generation by hydrolysis	31.0^[f]	169.7^[f]	[51]
Nanosheet	Hydrogen generation by hydrolysis	10.7^[g]	31.8^[g]	[51]
Nanosheet	Hydrogen generation by hydrolysis	10.4	93.1	[39]

g-C₃N₄光催化性能的研究进展

Recent Progress in Photocatalysis of g-C₃N₄

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