Sb掺杂Li7La3Zr2O12陶瓷的显微结构及离子导电性能研究

doi:10.3724/SP.J.1077.2013.13428

无机材料学报 ›› 2014, Vol. 29 ›› Issue (2): 220-224.DOI: 10.3724/SP.J.1077.2013.13428 CSTR: 32189.14.SP.J.1077.2013.13428

• 研究快报 • 上一篇

Sb掺杂Li₇La₃Zr₂O₁₂陶瓷的显微结构及离子导电性能研究

曹珍珠¹, 任伟¹, 刘进荣¹, 李国荣², 高艳芳¹, 房明浩³, 何伟艳¹

(1. 内蒙古工业大学化工学院, 呼和浩特010051; 2. 中国科学院上海硅酸盐研究所, 上海200050; 中国地质大学材料科学与工程学院, 北京100083)

收稿日期:2013-08-22 修回日期:2013-10-29 出版日期:2014-02-20 网络出版日期:2014-01-17
作者简介:曹珍珠. E-mail: czz03@163.com
基金资助:
National Natural Science Foundation of China (51102130); Program for Key Laboratory of Inorganic Function Material and Device, Chinese Academy of Sciences (KLIFMD-2011-01)

Microstructure and Ionic Conductivity of Sb-doped Li₇La₃Zr₂O₁₂ Ceramics

CAO Zhen-Zhu¹, REN Wei¹, LIU Jin-Rong¹, LI Guo-Rong², GAO Yan-Fang¹, FANG Ming-Hao³, HE Wei-Yan¹

(1. Chemical Engineering College of Inner Mongolia University of Technology, Hohhot 010051, China; 2. Key Laboratory of Inorganic Function Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; 3. School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China)

Received:2013-08-22 Revised:2013-10-29 Published:2014-02-20 Online:2014-01-17
About author:CAO Zhen-Zhu(1977–), male, associate professor. E-mail: czz03@163.com
Supported by:
National Natural Science Foundation of China (51102130); Program for Key Laboratory of Inorganic Function Material and Device, Chinese Academy of Sciences (KLIFMD-2011-01)

摘要/Abstract

摘要： 采用传统固相反应法制备了锑掺杂的锆镧酸锂固体电解质陶瓷。对陶瓷的晶体结构、显微结构及元素分布、离子电导率进行了研究。结果表明: 少量锑掺杂可明显提高锆镧酸锂固体电解质陶瓷的离子电导率。1160℃烧结的锑掺杂固体电解质中, 晶粒表面形成无定型的薄膜。此薄膜抑制了晶粒生长, 消除了晶界上的气孔, 提高了陶瓷致密度, 提高了陶瓷的离子导电率。1160℃烧结得到的Li_6.925La₃Zr_1.925Sb_0.075O₁₂陶瓷离子电导率高达3.40×10^-4 S/cm。

关键词: 固体电解质, 离子电导率, 显微结构, 掺杂

Abstract: The garnet-related oxides Li_7-xLa₃Zr_2-xSb_xO₁₂ (x = 0, 0.075) were prepared by solid-state reaction method. Crystal structure, microstructure, conductivity, and element distribution were characterized for the pure and Sb-doped Li₇La₃Zr₂O₁₂. Ionic conductivity of the Li₇La₃Zr₂O₁₂ is enhanced by Sb doping. An amorphous Li-La-Zr-Al-O thin film which is formed on the grain boundary of Sb-doped samples not only suppresses the abnormal grain growth but also eliminates the pores on the grain boundary. The ionic conductivity of Sb doped Li_7-xLa₃Zr_2-xSb_xO₁₂ ceramic with x = 0.075 sintered at 1160℃ reaches about 3.40×10^-4 S/cm.

Key words: solid electrolyte, ionic conductivity, microstructure, doping

中图分类号:

TM911

曹珍珠, 任伟, 刘进荣, 李国荣, 高艳芳, 房明浩, 何伟艳. Sb掺杂Li₇La₃Zr₂O₁₂陶瓷的显微结构及离子导电性能研究[J]. 无机材料学报, 2014, 29(2): 220-224.

CAO Zhen-Zhu, REN Wei, LIU Jin-Rong, LI Guo-Rong, GAO Yan-Fang, FANG Ming-Hao, HE Wei-Yan. Microstructure and Ionic Conductivity of Sb-doped Li₇La₃Zr₂O₁₂ Ceramics[J]. Journal of Inorganic Materials, 2014, 29(2): 220-224.

参考文献

[1] Goodenough J B, Kim Y. Challenges for rechargeable Li batteries. Chem. Mater. 2010, 22(3): 587–603.

[2] Jeffrey W F. Ceramic and polymeric solid electrolytes for lithium- ion batteries. J. Power Sour. 2010, 195(15): 4554–4569.

[3] Philippe K. Inorganic solid Li ion conductors: An overview. Solid State Ionics, 2009, 180(14/15/16): 911–916.

[4] Tatsumisago M, Mizuno F, Hayashi A. All-solid-state lithium secondary batteries using sulfide-based glass–ceramic electrolytes. J. Power Source, 2006, 159(1): 193–199.

[5] Thangadurai V, Kaack H, Weppner W. Novel fast lithium ion conduction in garnet-type Li5La3M2O12 (M = Nb, Ta). J. Am. Ceram. Soc., 2003, 86(3): 437–440.

[6] Murugan R, Thangadurai V, Weppner W. Fast lithium ion conduction in garnet-type Li7La3Zr2O12. Angew. Chem. Int. Ed., 2007, 46(41): 7778–7781.

[7] Ohta S, Kobayashi T, Asaoka T. High lithium ionic conductivity in the garnet-type oxide Li7?xLa3(Zr2?x,Nbx)O12(x = 0 – 2). J. Power Source, 2011, 196(6): 3342–3345.

[8] Kumazaki S, Iriyama Y, Kim K, et al. High lithium ion conductive Li7La3Zr2O12 by inclusion of both Al and Si. Electrochem. Commun., 2011, 13(5): 509–512.

[9] Jin Y, McGinn P J. Al-doped Li7La3Zr2O12 synthesized by a polymerized complex method. J. Power Source, 2011, 196(20): 8683–8687.

[10] Allena J L, Wolfenstinea J, Rangasamyb E, et al. Effect of substitution (Ta, Al, Ga) on the conductivity of Li7La3Zr2O12. J. Power Source, 2012, 206: 315–319.

[11] Huang M, Dumon A, Nan C. Effect of Si, In and Ge doping on high ionic conductivity of Li7La3Zr2O12. Electrochem. Commun., 2012, 21: 62–64.

[12] Murugan R, Ramakumar S, Janani N. High conductive yttrium doped Li7La3Zr 2O12 cubic lithium garnet. Electrochem. Commun., 2011, 13(12): 1373–1375.

[13] Chantikul P, Bennison S J, Lawn B R. Role of grain size in the strength and R-curve properties of alumina. J. Am. Ceram. Soc., 1990, 73(8): 2419–2427.

[14] Fu J, Zuo R Z, Wang X H, et al. Polymorphic phase transition and enhanced piezoelectric properties of LiTaO3-modified (Na0.52K0.48)(Nb0.93Sb0.07)O3 lead-free ceramics. J. Phys. D: Appl. Phys., 2009, 42(1): 012006–1–4.

[15] Ming B Q, Wang J F, Zang G Z, et al. Piezoelectric properties of (Li, Sb, Ta) modified (Na,K)NbO3 lead-free ceramics. J. Appl. Phys., 2007, 101(5): 054103–1–4.

[16] Ramakumar S, Satyanarayana L, Manorama S V, et al. Structure and Li+ dynamics of Sb-doped Li7La3Zr2O fast lithium ion conductors. Phys. Chem. Chem. Phys., 2013, 15: 11327– 11338.

[17] Geiger C A, Alekseev E, Lazic B, et al. Crystal chemistry and stability of “Li7La3Zr2O12” garnet: a fast lithium-ion conductor. Inorg. Chem., 2011, 50(3): 1089–1097.

[18] Mei A, Wang X, Lan J, et al. Role of amorphous boundary layer in enhancing ionic conductivity of lithium-lanthanum-titanate electrolyte. Electrochim. Acta, 2010, 55(8): 2958–2963.

[19] Sata N, Eberman K, Eberl K, et al. Mesoscopic fast ion conduction in nanometre-scale planar heterostructures. Nature, 2000, 408: 946–949.

[20] Thangadurai V, Weppner W. Effect of sintering on the ionic conductivity of garnet-related structure Li5La3Nb2O12 and In- and K-doped Li5La3Nb2O12. J. Solid State Chem., 2006, 179(4): 974–984.

[21] Li Y T, Wang C A, Xie H, et al. High lithium ion conduction in garnet-type Li6La3ZrTaO12. Electrochem. Commun., 2011, 13(12): 1289–1292.

[22] Thangadurai V, Weppner W. Li6ALa2Nb2O12 (A = Ca, Sr, Ba): a new class of fast lithium ion conductors with garnet-like structure. J. Am. Ceram. Soc., 2005, 88(2): 411–418.

Sb掺杂Li₇La₃Zr₂O₁₂陶瓷的显微结构及离子导电性能研究

Microstructure and Ionic Conductivity of Sb-doped Li₇La₃Zr₂O₁₂ Ceramics

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