新型La2Mo2O9基氧离子导体的研究进展

摘要/Abstract

摘要： 自2000年Lacorre等人报道La₂Mo₂O₉具有较高的氧离子电导率以来,La₂Mo₂O₉ 基氧离子导体由于具有优异的性能而受到人们的关注．本文综述了新型氧离子导体La₂Mo₂O₉ 的研究现状．重点介绍了纯La₂Mo₂O₉及其掺杂体系的结构与相变、氧离子电导率、氧空位扩散机理、化学稳定性和热膨胀系数等性能．已有的研究结果表明,基于La₂Mo₂O₉的氧离子导体可望在固体氧化物燃料电池、氧传感器、透氧膜等方面得到应用．

关键词: 氧离子导体, La₂Mo₂O₉, 固体氧化物燃料电池

Abstract:

La₂Mo₂O₉-based oxide-ion conductors have attracted more and more attention since they were reported having high ionic conductivity in 2000 by Lacorre et. al. In this paper the recent investigation
on the novel La₂Mo₂O₉-based oxide-ion conductors is reviewed. It is focused on the structure and phase transition, oxide-ion conductivity, mechanism of oxygen vacancy diffusion, chemical stability,
and thermal expansion coefficient in the pure and doped La₂Mo₂O₉ samples. It is pointed out that the La₂Mo₂O₉-based oxide-ion conductors could be possibly applied in the field
such as solid oxide fuel cells, oxygen sensors, oxygen permeable membrane.

Key words: oxide-ion conductor, La₂Mo₂O₉, SOFC

中图分类号:

TM911

方前锋,王先平,程帜军,张国光. 新型La₂Mo₂O₉基氧离子导体的研究进展[J]. 无机材料学报.

FANG Qian-Feng,WANG Xian-Ping,Cheng Zhi-Jun,ZHANG Guo-Guang. Research Status of the Novel La₂Mo₂O₉-based Oxide-ion Conductors[J]. Journal of Inorganic Materials.

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新型La₂Mo₂O₉基氧离子导体的研究进展

Research Status of the Novel La₂Mo₂O₉-based Oxide-ion Conductors

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