无机材料学报

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铁、铬离子掺杂对TiO2薄膜光催化活性的影响

于向阳; 程继健   

  1. 华东理工大学无机材料研究所, 上海 200237
  • 收稿日期:2000-07-20 修回日期:2000-08-08 出版日期:2001-07-20 网络出版日期:2001-07-20

Photocatalytic Activities of Iron and Chromium Ion Doped TiO2 Films

YU Xiang-Yang; CHENG Ji-Jian   

  1. Institute of Inorganic material; East China University of Science & Technology; Shanghai 200237; China
  • Received:2000-07-20 Revised:2000-08-08 Published:2001-07-20 Online:2001-07-20

摘要: 采用溶胶-凝胶法在釉面砖表面制备了均匀的TiO薄膜,并研究了铁、铬离子掺杂对TiO光催化性能影响.对罗丹明B的光降解实验表明,适量的铁、铬离子掺杂均可提高TiO薄膜的光催化活性,铁离子的掺杂效果明显高于铬离子,而铬离子的掺杂方式影响TiO薄膜的光催化活性,这主要基于它们不同的掺杂机理

关键词: 二氧化钛, 掺杂, 光催化性能

Abstract: Iron ion and chromium ion doped TiO2 films were prepared on the surface of glazed brick by the sol-gel
process, and the effect of iron ion and chromium ion doping on photocatalytic activities of TiO2 films was investigated. The results
of photodecomposing Rhodamine B show that an appropriate doping amount of iron and chromium ion can improve the photocatalytic
activities of TiO2 films, however, the photocatalytic activities of iron ion doped samples are remarkably higher than those of
chromium ion doped samples, while the doping ways of chromium ion affect the photocatalytic activities of TiO2 films, because of their different
doping mechanisms.

Key words: titania, doping, photocatalytic activities

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