非晶LiSiON薄膜电解质的全固态薄膜锂电池性能

doi:10.15541/jim20210132

无机材料学报 ›› 2022, Vol. 37 ›› Issue (2): 230-236.DOI: 10.15541/jim20210132 CSTR: 32189.14.10.15541/jim20210132

所属专题：【能源环境】锂离子电池(202409)

• 研究快报 • 上一篇

非晶LiSiON薄膜电解质的全固态薄膜锂电池性能

夏求应, 孙硕, 昝峰, 徐璟, 夏晖

南京理工大学材料科学与工程学院, 南京 210094

收稿日期:2021-03-06 修回日期:2021-05-06 出版日期:2022-02-20 网络出版日期:2021-06-10
作者简介:夏求应(1991-), 男, 博士. E-mail: qiuyingxia@njust.edu.cn

Amorphous LiSiON Thin Film Electrolyte for All-solid-state Thin Film Lithium Battery

XIA Qiuying, SUN Shuo, ZAN Feng, XU Jing, XIA Hui

School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received:2021-03-06 Revised:2021-05-06 Published:2022-02-20 Online:2021-06-10
Contact: XIA Hui, professor. E-mail: xiahui@njust.edu.cn
About author:XIA Qiuying (1991-), male, PhD. E-mail: qiuyingxia@njust.edu.cn
Supported by:
National Key R&D Program of China (2020YFB2007400); National Natural Science Foundation of China (51802159, 51972174, 52002183)

摘要/Abstract

摘要： 全固态薄膜锂电池(TFLB)是理想的微电子系统电源。目前报道的固态非晶电解质存在离子电导率偏低的问题, 限制了TFLB性能的提升。本工作采用磁控溅射法制备了一种新型非晶锂硅氧氮(LiSiON)薄膜用作TFLB的固态电解质。结果表明, 优化制备条件后的LiSiON薄膜具有6.3×10^-6 S∙cm^-1的高离子电导率以及超过5 V的宽电压窗口, 适合作为TFLB的电解质。在LiSiON薄膜电解质的基础上, 本工作构建了MoO₃/LiSiON/Li TFLB并获得高的比容量(50 mA∙g^-1下282 mAh∙g^-1)、良好的倍率性能(800 mA∙g^-1下50 mAh∙g^-1)和可观的循环寿命(200次循环后容量保持率为78.1%), 验证了该电解质在薄膜电池中应用的可行性。

关键词: LiSiON, 薄膜电解质, 全固态锂电池, 薄膜电池

Abstract: All-solid-state thin film lithium battery (TFLB) is regarded as the ideal power source for microelectronic devices. However, the relatively low ionic conductivity of amorphous solid-state electrolyte limits the improvement of electrochemical performance for TFLB. In this work, amorphous lithium silicon oxynitride (LiSiON) thin films are prepared by magnetron sputtering as solid-state electrolyte for TFLB. With optimized deposition condition, the LiSiON thin film exhibits a high ionic conductivity of 6.3×10^-6 S∙cm^-1 at room temperature and a wide voltage window over 5 V, making it a suitable thin film electrolyte for TFLB. A MoO₃/LiSiON/Li TFLB is constructed based on the LiSiON thin film electrolyte with large specific capacity (282 mAh∙g^-1 at 50 mA∙g^-1), good rate capability (50 mAh∙g^-1 at 800 mA∙g^-1), and acceptable cycle life (78.1% capacity retention after 200 cycles), demonstrating the feasibility of this electrolyte for practical applications.

Key words: LiSiON, thin film electrolyte, all-solid-state lithium battery, thin film battery

中图分类号:

TQ174

夏求应, 孙硕, 昝峰, 徐璟, 夏晖. 非晶LiSiON薄膜电解质的全固态薄膜锂电池性能[J]. 无机材料学报, 2022, 37(2): 230-236.

XIA Qiuying, SUN Shuo, ZAN Feng, XU Jing, XIA Hui. Amorphous LiSiON Thin Film Electrolyte for All-solid-state Thin Film Lithium Battery[J]. Journal of Inorganic Materials, 2022, 37(2): 230-236.

参考文献

[1] MOITZHEIM S, PUT B, VEREECKEN P M.Advances in 3D thin-film Li-ion batteries.Advanced Materials Interfaces, 2019, 6(15): 1900805.
[2] XIA Q, ZHANG Q, SUN S,et al. Tunnel intergrowth Li_xMnO₂ nanosheet arrays as 3D cathode for high-performance all-solid- state thin film lithium microbatteries. Advanced Materials, 2021, 33(5): 2003524.
[3] DENG Y, EAMES C, FLEUTOT B, et al. Enhancing the lithium ion conductivity in lithium superionic conductor (LISICON) solid electrolytes through a mixed polyanion effect. ACS Applied Materials & Interfaces, 2017, 9(8): 7050-7058.
[4] BATES J B, DUDNEY N J, GRUZALSKI G R,et al. Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries. Journal of Power Sources, 1993, 43(1/2/3): 103-110.
[5] BATES J.Electrical properties of amorphous lithium electrolyte thin films.Solid State Ionics, 1992, 53(56): 647-654.
[6] FAMPRIKIS T, GALIPAUD J, CLEMENS O,et al. Composition dependence of ionic conductivity in LiSiPO(N) thin-film electrolytes for solid-state batteries. ACS Applied Energy Materials, 2019, 2(7): 4782-4791.
[7] DENG Y, EAMES C, CHOTARD J N,et al. Structural and mechanistic insights into fast lithium-ion conduction in Li₄SiO₄- Li₃PO₄ solid electrolytes. Journal of the American Chemical Society, 2015, 137(28): 9136-9145.
[8] CHEN R, SONG X.The ionic conductivity of solid electrolytes for Li₄+_xM_xSi₁-_xO₄-_yLi₂O (M=Al, B) systems. Journal of the Chinese Chemical Society, 2002, 49: 7-10.
[9] ADNAN S, MOHAMED N S.Effects of Sn substitution on the properties of Li₄SiO₄ ceramic electrolyte.Solid State Ionics, 2014, 262: 559-562.
[10] SUN S, XIA Q, LIU J,et al. Self-standing oxygen-deficient α-MoO₃-_x nanoflake arrays as 3D cathode for advanced all-solid- state thin film lithium batteries. Journal of Materiomics, 2019, 5(2): 229-236.
[11] DING W, LU W, DENG X,et al. An XPS study on the structure of SiN_x film deposited by microwave ECR magnetron sputtering. Acta Physica Sinica, 2009, 58(6): 4109-4116.
[12] KIM H, KIM Y.Partial nitridation of Li₄SiO₄ and ionic conductivity of Li_4.1SiO_3.9N_0.1.Ceramics International, 2018, 44(8): 9058-9062.
[13] MARIKO M, HIDEMASA K,TOMOYUKI O,et al. Analysis of SiO anodes for lithium-ion batteries. Journal of The Electrochemical Society, 2005, 152(10): A2089.
[14] FINGERLE M, BUCHHEIT R, SICOLO S,et al. Reaction and space charge layer formation at the LiCoO₂-LiPON interface: insights on defect formation and ion energy level alignment by a combined surface science-simulation approach. Chemisty Materials, 2017, 29(18): 7675-7685.
[15] WEST W, HOOD Z, ADHIKARI S,et al. Reduction of charge- transfer resistance at the solid electrolyte-electrode interface by pulsed laser deposition of films from a crystalline Li₂PO₂N source. Journal of Power Sources, 2016, 312: 116-122.
[16] SICOLO S, FINGERLE M, HAUSBRAND R,et al. Interfacial instability of amorphous LiPON against lithium: a combined density functional theory and spectroscopic study. Journal of Power Sources, 2017, 354: 124-133.
[17] WU F, LIU Y, CHEN R,et al. Preparation and performance of novel Li-Ti-Si-P-O-N thin-film electrolyte for thin-film lithium batteries. Journal of Power Sources, 2009, 189(1): 467-470.
[18] PUT B, VEREECKEN M, MEERSSCHAUT J,et al. Electrical characterization of ultrathin RF-sputtered LiPON layers for nanoscale batteries. ACS Applied Materials & Interfaces, 2016, 8(11): 7060-7069.
[19] NIINOMI H, MOTOYAMA M, IRIYAMA Y.Li+ Conduction in Li-Nb-O films deposited by a Sol-Gel method.Solid State Ionics, 2016, 285: 13-18.
[20] SONG S, LEE K, PARK H.High-performance flexible all-solid-state microbatteries based on solid electrolyte of lithium boron oxynitride.Journal of Power Sources, 2016, 328: 311-317.
[21] OHTSUKA H, OKADA S, YAMAKI J. Solid state battery with Li₂O-V₂O₅-SiO₂ solid electrolyte thin film. Solid State Ionics, 1990, 40-41: 964-966.
[22] Kalita D, Lee S, Lee K,et al. Ionic conductivity properties of amorphous Li-La-Zr-O solid electrolyte for thin film batteries. Solid State Ionics, 2012, 229: 14-19.
[23] SAKURAI Y, SAKUDA A, HAYASHI A,et al. Preparation of amorphous Li₄SiO₄-Li₃PO₄ thin films by pulsed laser deposition for all-solid-state lithium secondary batteries. Solid State Ionics, 2011, 182: 59-63.
[24] TAN G, WU F, LI L,et al. Magnetron sputtering preparation of nitrogen-incorporated lithium-aluminum-titanium phosphate based thin film electrolytes for all-solid-state lithium ion batteries. The Journal of Physical Chemistry C, 2012, 116(5): 3817-3826.
[25] YU X, BATES J B, JELLISON G,et al. A stable thin-film lithium electrolyte: lithium phosphorus oxynitride. Journal of The Electrochemical Society, 1997, 144(2): 524.
[26] KIM H, COOK J, LIN H,et al. Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO₃-_x. Nature Materials, 2017, 16: 454-460.
[27] SONG H, WANG S, SONG X,et al. Solar-driven all-solid-state lithium-air batteries operating at extreme low temperatures. Energy & Environmental Science, 2020, 13(4): 1205-1211.
[28] WANG Z, LEE J, XIN H,et al. Effects of cathode electrolyte interfacial (CEI) layer on long term cycling of all-solid-state thin-film batteries. Journal of Power Sources, 2016, 324: 342-348.
[29] QIAO Y, DENG H, HE P, et al. A 500 Wh/kg lithium-metal cell based on anionic redox. Joule, 2020, 4(6): 1311-1323.

非晶LiSiON薄膜电解质的全固态薄膜锂电池性能

Amorphous LiSiON Thin Film Electrolyte for All-solid-state Thin Film Lithium Battery

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	晁少飞, 薛艳辉, 吴琼, 伍复发, MUHAMMAD Sufyan Javed, 张伟. MXene异质结Ti-O-H-O电子快速通道促进高效率储钾[J]. 无机材料学报, 2024, 39(11): 1212-1220.
[2]	任冠源, 李宜冠, 丁冬海, 梁瑞虹, 周志勇. CaBi₂Nb₂O₉铁电薄膜的生长取向调控和性能研究[J]. 无机材料学报, 2024, 39(11): 1228-1234.
[3]	谢天, 宋二红. 弹性应变对C、H、O在过渡金属氧化物表面吸附的影响[J]. 无机材料学报, 2024, 39(11): 1292-1300.
[4]	张哲, 孙婷婷, 王连军, 江莞. 不同维度Ag₂Se构筑柔性热电薄膜的性能优化与器件集成研究[J]. 无机材料学报, 2024, 39(11): 1221-1227.
[5]	陶顺衍, 杨加胜, 邵芳, 吴应辰, 赵华玉, 董绍明, 张翔宇, 熊瑛. 航机CMC热端部件用热喷涂涂层的机遇与挑战[J]. 无机材料学报, 2024, 39(10): 1077-1083.
[6]	江强, 施立志, 陈政燃, 周志勇, 梁瑞虹. 高于居里温度极化的硬性PZT压电陶瓷的制备及叠层驱动器性能研究[J]. 无机材料学报, 2024, 39(10): 1091-1099.
[7]	彭萍, 谭礼涛. CuO掺杂(Ba,Ca)(Ti,Sn)O₃陶瓷的结构与压电性能[J]. 无机材料学报, 2024, 39(10): 1100-1106.
[8]	王博, 蔡德龙, 朱启帅, 李达鑫, 杨治华, 段小明, 李雅楠, 王轩, 贾德昌, 周玉. SrAl₂Si₂O₈增强BN陶瓷的力学性能及抗热震性能[J]. 无机材料学报, 2024, 39(10): 1182-1188.
[9]	史瑞, 刘伟, 李林, 李欢, 张志军, 饶光辉, 赵景泰. BaSrGa₄O₈: Tb³⁺力致发光材料的制备及性能[J]. 无机材料学报, 2024, 39(10): 1107-1113.
[10]	陈梦杰, 王倩倩, 吴成铁, 黄健. 基于DFT的描述符预测生物陶瓷的降解性[J]. 无机材料学报, 2024, 39(10): 1175-1181.
[11]	瞿牡静, 张淑兰, 朱梦梦, 丁浩杰, 段嘉欣, 代恒龙, 周国红, 李会利. CsPbBr₃@MIL-53纳米复合荧光粉的合成、性能及其白光LEDs应用[J]. 无机材料学报, 2024, 39(9): 1035-1043.
[12]	杨佳霖, 王亮君, 阮丝园, 蒋秀林, 杨长. 基于CuI/Si单边异质结的微光高灵敏双波段可切换光电探测器[J]. 无机材料学报, 2024, 39(9): 1063-1069.
[13]	王旭, 李翔, 寇华敏, 方伟, 吴庆辉, 苏良碧. 不同浓度Y³⁺离子掺杂对CaF₂晶体性能的影响[J]. 无机材料学报, 2024, 39(9): 1029-1034.
[14]	荀道祥, 罗序维, 周明冉, 何佳乐, 冉茂进, 胡执一, 李昱. 锂硒电池ZIF-L衍生氮掺杂碳纳米片/碳布自支撑电极的电化学性能研究[J]. 无机材料学报, 2024, 39(9): 1013-1021.
[15]	陈甲, 范依然, 闫文馨, 韩颖超. 聚丙烯酸-钙(铈)纳米团簇荧光探针用于无机磷定量检测研究[J]. 无机材料学报, 2024, 39(9): 1053-1062.