基于氧化钨和氧化镍的电致变色器件研究进展

doi:10.15541/jim20200488

无机材料学报 ›› 2021, Vol. 36 ›› Issue (2): 128-139.DOI: 10.15541/jim20200488 CSTR: 32189.14.10.15541/jim20200488

所属专题：封面文章；电致变色材料与器件；功能材料论文精选(2021)；【虚拟专辑】电致变色与热致变色材料；电致变色专栏2021

• 专栏: 电致变色材料与器件(特邀编辑:刁训刚, 王金敏) • 上一篇下一篇

基于氧化钨和氧化镍的电致变色器件研究进展

钟晓岚¹(), 刘雪晴¹, 刁训刚²()

1.物理学院，北京航空航天大学北京 100191
2.能源与动力工程学院, 北京航空航天大学北京 100191

收稿日期:2020-08-24 修回日期:2020-09-23 出版日期:2021-02-20 网络出版日期:2020-11-05
通讯作者: 刁训刚, 教授. E-mail: diaoxg@buaa.edu.cn
作者简介:钟晓岚(1986-), 女, 副教授. Email: zhongxl@buaa.edu.cn
基金资助:
国家自然科学基金(61875005);国家自然科学基金(11804018)

Electrochromic Devices Based on Tungsten Oxide and Nickel Oxide: a Review

ZHONG Xiaolan¹(), LIU Xueqing¹, DIAO Xungang²()

1. School of Physics, Beihang University, Beijing 100191, China
2. School of Energy and Power Engineering, Beihang University, Beijing 100191, China

Received:2020-08-24 Revised:2020-09-23 Published:2021-02-20 Online:2020-11-05
About author:ZHONG Xiaolan(1986-), female, associate professor. E-mail: zhongxl@buaa.edu.cn
Supported by:
National Natural Science Foundation of China(61875005);National Natural Science Foundation of China(11804018)

摘要/Abstract

摘要：

电致变色器件(Electrochromic Devices, ECDs)是一种颜色变化受电压调控的智能装置, 具有工作温度范围宽、光学对比度高、可逆双稳态性能好、驱动电压低和能耗低等优点, 在智能动态调光窗、全彩色电子显示屏、防眩光护目镜、自适应双隐身伪装以及可视化储能等领域展现出了巨大的应用潜力。阴极着色材料氧化钨(WO₃)和阳极着色材料氧化镍(NiO)是两种被广泛研究的无机电致变色材料, 由WO₃和NiO薄膜组成的互补型电致变色器件在大规模智能窗的应用中具有极高的商业价值。改善电致变色器件的综合性能如光学调制范围、响应速度、循环寿命和耐候性等问题一直备受关注。本文围绕互补型电致变色器件的结构组成, 综述了基于WO₃和NiO的电致变色全器件的近期研究进展。首先分别阐述了WO₃和NiO薄膜的电致变色机理和衰退机制, 讨论了改进制备工艺、元素掺杂改性、设计纳米结构和引入复合材料这四种薄膜性能优化策略的作用和最新研究进展, 其次, 按照器件的组成成分和结构设计介绍了互补型电致变色全器件的分类体系, 总结了各组分材料的选择和器件结构对器件综合性能的影响, 最后对电致变色器件的应用前景和发展趋势进行了展望。

关键词: 电致变色器件, 氧化钨, 氧化镍, 综述

Abstract:

Electrochromic devices (ECDs) are the intelligent devices change color by applying electric potential, with the advantages of wide working temperature, high optical contrast, good reversible bistability, low driving voltage, and low energy consumption, which show great application potential in the field of dynamic smart windows, full-color electronic screens, anti-glare goggles, adaptive dual-stealth camouflage, and energy storage status visualization. Cathodically coloring material tungsten oxide and anodically coloring material nickel oxide are two widely studied inorganic electrochromic materials, and complementary electrochromic devices based on WO₃ and NiO films have high commercial values in the application of large scale smart windows. Improving the performance of the complementary ECDs such as optical modulation range, response rate, cycle life and weather fastness has attracted much attention. This review focuses on the structural composition of complementary electrochromic devices and summarizes the recent research progress of the electrochromic full devices based on WO₃ and NiO. Firstly, the electrochromic mechanism and decay mechanism of WO₃ and NiO films are clarified, the effects and latest research progress of four strategies for film performance optimization that include optimizing preparation conditions, element doping modification, designing nanostructure, and introducing composite materials are discussed in detail. Secondly, according to the composition and structure design of the device, the classification system of the complementary electrochromic full device is introduced, and the influence of selection for each component material and the device structure on device overall performance are summarized. Finally, the application of the electrochromic device prospects and development trends are forecasted.

Key words: electrochromic device, tungsten oxide, nickel oxide, review

中图分类号:

O439
O484

钟晓岚, 刘雪晴, 刁训刚. 基于氧化钨和氧化镍的电致变色器件研究进展[J]. 无机材料学报, 2021, 36(2): 128-139.

ZHONG Xiaolan, LIU Xueqing, DIAO Xungang. Electrochromic Devices Based on Tungsten Oxide and Nickel Oxide: a Review[J]. Journal of Inorganic Materials, 2021, 36(2): 128-139.

图/表 10

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基于氧化钨和氧化镍的电致变色器件研究进展

Electrochromic Devices Based on Tungsten Oxide and Nickel Oxide: a Review

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Year	Device structure	t_c/s	t_b/s	CE/(cm²·C^-1)	ΔT/%	Cycles	Ref.
2016	ITO/NiO_x/ZrO₂:H/WO₃/ITO	116	108	-	65.2	2000	[72]
2016	ITO/NiO_x/Ta₂O₅:H/WO₃/ITO	-	-	-	60	-	[76]
2016	ITO/WO₃/LiClO₄-PC-PMMA/NiO_x/ITO	4.5	1.7	-	51.7	50000	[77]
2016	Glass/ITO/WO₃/LiNbO₃/NiO_x/ITO	45	25	-	65	-	[78]
2016	ITO/NiO_x:Ti/PVB(Li⁺)/WO₃/ITO	4.4	3.2	96	60	-	[79]
2017	Glass/ITO/WO₃/PVB-GPEF/Ni_1-_xO/ITO/Glass	9.5	16	175.34	65.8	3000	[80]
2017	Glass /ITO/NiO_x/electrolyte/WO₃/ITO	7	2	-	70	300	[81]
2017	Glass /ITO/NiO/Si₃N₄/LiNbO₃/Si₃N₄/WO₃/ITO	-	-	-	43	-	[82]
2017	ITO/NiO/Ta₂O₅/LiNbO₃/WO₃/ITO	-	-	-	34	-	[83]
2018	Glass/ITO/NiO/Si₃N₄/Li_xMg_yN/WO₃/ITO	-	-	77	40	1000	[84]
2018	Glass/ITO/WO₃/Li_2.5TaO_x/NiO/ITO	30	30	63	40	300	[71]
2018	FTO/WO₃/gel polymer electrolyte/NiO/FTO	1.2	2.6	-	43.81	20000	[85]
2018	Glass/ITO/WO₃:H/Ta₂O₅/NiO_x/ITO	-	-	24.3	42	300	[86]
2018	Glass/ITO/WO₃/LiPON/NiO/ITO	-	-	-	40	-	[74]
2018	Glass/ITO/Li_xNiO_y/LiTaO₃/WO₃/ITO	13	3.5	42	40	7000	[87]
2018	ITO/NiO_x/Ta₂O₅/LiNbO₃/Ta₂O₅/WO₃/ITO	-	-	98	52.5	10000	[88]
2018	ITO/NiO/ZrO₂/LiNbO₃/WO₃/ITO	-	-	24.3	53	-	[89]
2018	ITO/NiO/Ta₂O₅/LiNbO₃/WO₃/ITO/Glass	10	7	-	71.7	-	[90]
2019	Glass/IAI/NiO_x/LiClO₄-PC-PMMA/WO₃/IAI/Glass	2.25	2.02	31.7	55	-	[62]
2019	ITO/NiO_x/Li_xAlO_z/WO₃/ITO	5.7	2.2	76.45	74.4	10000	[75]
2019	ITO/WO₃-Nb₂O₅/Nb₂O₅/NiVO_x/ITO	7	0.7	-	33	30000	[91]
2019	ITO/WO₃/LiClO₄-PC-PMMA/NiO/ITO	3.2	1.1	130.8	45	1000	[92]
2019	ITO/NiO_x/Ta₂O₅/LiNbO₃/Ta₂O₅/WO₃/ITO	18.4	9.5	-	55.2	2500	[93]
2019	ITO/NiO_x/Ta₂O₅/WO₃/ITO	13	2	-	70.9	-	[94]
2020	Glass /ITO/WO₃/LiF/NiO/ITO	9.6	4	88.5	58.9	450	[73]
2020	ITO/WO₃/Gelatin/NiO/ITO	10	50	60.38	43.35	-	[70]
2020	ITO/Li-NiO/Li-WO₃/ITO	8.6	1.7	87.5	32	1000	[95]
2020	ITO/WO₃/LiClO₄-PC-PMMA-ACN/NiO/ITO	1.2	1.5	243	51.27	20000	[96]
2020	ITO/WO₃/LiNbO₃/Al-LiNiO_x/ITO	17.9	4.1	-	44	5000	[97]

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