无机材料学报 ›› 2021, Vol. 36 ›› Issue (2): 128-139.DOI: 10.15541/jim20200488 CSTR: 32189.14.10.15541/jim20200488
所属专题: 封面文章; 电致变色材料与器件; 功能材料论文精选(2021); 【虚拟专辑】电致变色与热致变色材料; 电致变色专栏2021
• 专栏: 电致变色材料与器件(特邀编辑:刁训刚, 王金敏) • 上一篇 下一篇
收稿日期:
2020-08-24
修回日期:
2020-09-23
出版日期:
2021-02-20
网络出版日期:
2020-11-05
通讯作者:
刁训刚, 教授. E-mail: diaoxg@buaa.edu.cn作者简介:
钟晓岚(1986-), 女, 副教授. Email: zhongxl@buaa.edu.cn
基金资助:
ZHONG Xiaolan1(), LIU Xueqing1, DIAO Xungang2()
Received:
2020-08-24
Revised:
2020-09-23
Published:
2021-02-20
Online:
2020-11-05
About author:
ZHONG Xiaolan(1986-), female, associate professor. E-mail: zhongxl@buaa.edu.cn
Supported by:
摘要:
电致变色器件(Electrochromic Devices, ECDs)是一种颜色变化受电压调控的智能装置, 具有工作温度范围宽、光学对比度高、可逆双稳态性能好、驱动电压低和能耗低等优点, 在智能动态调光窗、全彩色电子显示屏、防眩光护目镜、自适应双隐身伪装以及可视化储能等领域展现出了巨大的应用潜力。阴极着色材料氧化钨(WO3)和阳极着色材料氧化镍(NiO)是两种被广泛研究的无机电致变色材料, 由WO3和NiO薄膜组成的互补型电致变色器件在大规模智能窗的应用中具有极高的商业价值。改善电致变色器件的综合性能如光学调制范围、响应速度、循环寿命和耐候性等问题一直备受关注。本文围绕互补型电致变色器件的结构组成, 综述了基于WO3和NiO的电致变色全器件的近期研究进展。首先分别阐述了WO3和NiO薄膜的电致变色机理和衰退机制, 讨论了改进制备工艺、元素掺杂改性、设计纳米结构和引入复合材料这四种薄膜性能优化策略的作用和最新研究进展, 其次, 按照器件的组成成分和结构设计介绍了互补型电致变色全器件的分类体系, 总结了各组分材料的选择和器件结构对器件综合性能的影响, 最后对电致变色器件的应用前景和发展趋势进行了展望。
中图分类号:
钟晓岚, 刘雪晴, 刁训刚. 基于氧化钨和氧化镍的电致变色器件研究进展[J]. 无机材料学报, 2021, 36(2): 128-139.
ZHONG Xiaolan, LIU Xueqing, DIAO Xungang. Electrochromic Devices Based on Tungsten Oxide and Nickel Oxide: a Review[J]. Journal of Inorganic Materials, 2021, 36(2): 128-139.
图2 WO3薄膜的制备过程、晶体结构和氩/氧气氛退火引起的氧空位变化[18]
Fig. 2 Illustration of WO3 thin films fabrication process, crystal structure and oxygen vacancy change induced by Ar/O2 atmosphere annealing[18]
Year | Device structure | tc/s | tb/s | CE/(cm2·C-1) | ΔT/% | Cycles | Ref. |
---|---|---|---|---|---|---|---|
2016 | ITO/NiOx/ZrO2:H/WO3/ITO | 116 | 108 | - | 65.2 | 2000 | [72] |
2016 | ITO/NiOx/Ta2O5:H/WO3/ITO | - | - | - | 60 | - | [76] |
2016 | ITO/WO3/LiClO4-PC-PMMA/NiOx/ITO | 4.5 | 1.7 | - | 51.7 | 50000 | [77] |
2016 | Glass/ITO/WO3/LiNbO3/NiOx/ITO | 45 | 25 | - | 65 | - | [78] |
2016 | ITO/NiOx:Ti/PVB(Li+)/WO3/ITO | 4.4 | 3.2 | 96 | 60 | - | [79] |
2017 | Glass/ITO/WO3/PVB-GPEF/Ni1-xO/ITO/Glass | 9.5 | 16 | 175.34 | 65.8 | 3000 | [80] |
2017 | Glass /ITO/NiOx/electrolyte/WO3/ITO | 7 | 2 | - | 70 | 300 | [81] |
2017 | Glass /ITO/NiO/Si3N4/LiNbO3/Si3N4/WO3/ITO | - | - | - | 43 | - | [82] |
2017 | ITO/NiO/Ta2O5/LiNbO3/WO3/ITO | - | - | - | 34 | - | [83] |
2018 | Glass/ITO/NiO/Si3N4/LixMgyN/WO3/ITO | - | - | 77 | 40 | 1000 | [84] |
2018 | Glass/ITO/WO3/Li2.5TaOx/NiO/ITO | 30 | 30 | 63 | 40 | 300 | [71] |
2018 | FTO/WO3/gel polymer electrolyte/NiO/FTO | 1.2 | 2.6 | - | 43.81 | 20000 | [85] |
2018 | Glass/ITO/WO3:H/Ta2O5/NiOx/ITO | - | - | 24.3 | 42 | 300 | [86] |
2018 | Glass/ITO/WO3/LiPON/NiO/ITO | - | - | - | 40 | - | [74] |
2018 | Glass/ITO/LixNiOy/LiTaO3/WO3/ITO | 13 | 3.5 | 42 | 40 | 7000 | [87] |
2018 | ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO | - | - | 98 | 52.5 | 10000 | [88] |
2018 | ITO/NiO/ZrO2/LiNbO3/WO3/ITO | - | - | 24.3 | 53 | - | [89] |
2018 | ITO/NiO/Ta2O5/LiNbO3/WO3/ITO/Glass | 10 | 7 | - | 71.7 | - | [90] |
2019 | Glass/IAI/NiOx/LiClO4-PC-PMMA/WO3/IAI/Glass | 2.25 | 2.02 | 31.7 | 55 | - | [62] |
2019 | ITO/NiOx/LixAlOz/WO3/ITO | 5.7 | 2.2 | 76.45 | 74.4 | 10000 | [75] |
2019 | ITO/WO3-Nb2O5/Nb2O5/NiVOx/ITO | 7 | 0.7 | - | 33 | 30000 | [91] |
2019 | ITO/WO3/LiClO4-PC-PMMA/NiO/ITO | 3.2 | 1.1 | 130.8 | 45 | 1000 | [92] |
2019 | ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO | 18.4 | 9.5 | - | 55.2 | 2500 | [93] |
2019 | ITO/NiOx/Ta2O5/WO3/ITO | 13 | 2 | - | 70.9 | - | [94] |
2020 | Glass /ITO/WO3/LiF/NiO/ITO | 9.6 | 4 | 88.5 | 58.9 | 450 | [73] |
2020 | ITO/WO3/Gelatin/NiO/ITO | 10 | 50 | 60.38 | 43.35 | - | [70] |
2020 | ITO/Li-NiO/Li-WO3/ITO | 8.6 | 1.7 | 87.5 | 32 | 1000 | [95] |
2020 | ITO/WO3/LiClO4-PC-PMMA-ACN/NiO/ITO | 1.2 | 1.5 | 243 | 51.27 | 20000 | [96] |
2020 | ITO/WO3/LiNbO3/Al-LiNiOx/ITO | 17.9 | 4.1 | - | 44 | 5000 | [97] |
表1 2016~2020年基于WO3和NiO薄膜的电致变色器件结构与性能对比
Table 1 Comparison of structure and performance of ECDs based on WO3 and NiO films researched from 2016 to 2020
Year | Device structure | tc/s | tb/s | CE/(cm2·C-1) | ΔT/% | Cycles | Ref. |
---|---|---|---|---|---|---|---|
2016 | ITO/NiOx/ZrO2:H/WO3/ITO | 116 | 108 | - | 65.2 | 2000 | [72] |
2016 | ITO/NiOx/Ta2O5:H/WO3/ITO | - | - | - | 60 | - | [76] |
2016 | ITO/WO3/LiClO4-PC-PMMA/NiOx/ITO | 4.5 | 1.7 | - | 51.7 | 50000 | [77] |
2016 | Glass/ITO/WO3/LiNbO3/NiOx/ITO | 45 | 25 | - | 65 | - | [78] |
2016 | ITO/NiOx:Ti/PVB(Li+)/WO3/ITO | 4.4 | 3.2 | 96 | 60 | - | [79] |
2017 | Glass/ITO/WO3/PVB-GPEF/Ni1-xO/ITO/Glass | 9.5 | 16 | 175.34 | 65.8 | 3000 | [80] |
2017 | Glass /ITO/NiOx/electrolyte/WO3/ITO | 7 | 2 | - | 70 | 300 | [81] |
2017 | Glass /ITO/NiO/Si3N4/LiNbO3/Si3N4/WO3/ITO | - | - | - | 43 | - | [82] |
2017 | ITO/NiO/Ta2O5/LiNbO3/WO3/ITO | - | - | - | 34 | - | [83] |
2018 | Glass/ITO/NiO/Si3N4/LixMgyN/WO3/ITO | - | - | 77 | 40 | 1000 | [84] |
2018 | Glass/ITO/WO3/Li2.5TaOx/NiO/ITO | 30 | 30 | 63 | 40 | 300 | [71] |
2018 | FTO/WO3/gel polymer electrolyte/NiO/FTO | 1.2 | 2.6 | - | 43.81 | 20000 | [85] |
2018 | Glass/ITO/WO3:H/Ta2O5/NiOx/ITO | - | - | 24.3 | 42 | 300 | [86] |
2018 | Glass/ITO/WO3/LiPON/NiO/ITO | - | - | - | 40 | - | [74] |
2018 | Glass/ITO/LixNiOy/LiTaO3/WO3/ITO | 13 | 3.5 | 42 | 40 | 7000 | [87] |
2018 | ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO | - | - | 98 | 52.5 | 10000 | [88] |
2018 | ITO/NiO/ZrO2/LiNbO3/WO3/ITO | - | - | 24.3 | 53 | - | [89] |
2018 | ITO/NiO/Ta2O5/LiNbO3/WO3/ITO/Glass | 10 | 7 | - | 71.7 | - | [90] |
2019 | Glass/IAI/NiOx/LiClO4-PC-PMMA/WO3/IAI/Glass | 2.25 | 2.02 | 31.7 | 55 | - | [62] |
2019 | ITO/NiOx/LixAlOz/WO3/ITO | 5.7 | 2.2 | 76.45 | 74.4 | 10000 | [75] |
2019 | ITO/WO3-Nb2O5/Nb2O5/NiVOx/ITO | 7 | 0.7 | - | 33 | 30000 | [91] |
2019 | ITO/WO3/LiClO4-PC-PMMA/NiO/ITO | 3.2 | 1.1 | 130.8 | 45 | 1000 | [92] |
2019 | ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO | 18.4 | 9.5 | - | 55.2 | 2500 | [93] |
2019 | ITO/NiOx/Ta2O5/WO3/ITO | 13 | 2 | - | 70.9 | - | [94] |
2020 | Glass /ITO/WO3/LiF/NiO/ITO | 9.6 | 4 | 88.5 | 58.9 | 450 | [73] |
2020 | ITO/WO3/Gelatin/NiO/ITO | 10 | 50 | 60.38 | 43.35 | - | [70] |
2020 | ITO/Li-NiO/Li-WO3/ITO | 8.6 | 1.7 | 87.5 | 32 | 1000 | [95] |
2020 | ITO/WO3/LiClO4-PC-PMMA-ACN/NiO/ITO | 1.2 | 1.5 | 243 | 51.27 | 20000 | [96] |
2020 | ITO/WO3/LiNbO3/Al-LiNiOx/ITO | 17.9 | 4.1 | - | 44 | 5000 | [97] |
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