高熵过渡金属碳化物陶瓷的研究进展

doi:10.15541/jim20200366

无机材料学报 ›› 2021, Vol. 36 ›› Issue (4): 355-364.DOI: 10.15541/jim20200366

所属专题：【结构材料】超高温结构陶瓷；【结构材料】高熵陶瓷

高熵过渡金属碳化物陶瓷的研究进展

王皓轩¹(), 刘巧沐², 王一光³()

1.西北工业大学超高温结构复合材料重点实验室, 西安710072
2.中国燃气涡轮研究院, 成都 610500
3.北京理工大学先进技术结构研究院, 北京 100081

收稿日期:2020-07-02 修回日期:2020-09-27 出版日期:2021-04-20 网络出版日期:2020-09-20
通讯作者: 王一光, 教授. E-mail: wangyiguang@bit.edu.cn
作者简介:王皓轩(1994-), 男, 博士研究生. E-mail: wanghaoxuan@mail.nwpu.edu.cn
基金资助:
国家自然科学基金(51972027)

Research Progress of High Entropy Transition Metal Carbide Ceramics

WANG Haoxuan¹(), LIU Qiaomu², WANG Yiguang³()

1. Science and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an 710072, China
2. China Gas Turbine Establishment, Chengdu 610500, China
3. Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China

Received:2020-07-02 Revised:2020-09-27 Published:2021-04-20 Online:2020-09-20
Contact: WANG Yiguang, professor. E-mail: wangyiguang@bit.edu.cn
About author:WANG Haoxuan(1994-), male, PhD candidate. E-mail: wanghaoxuan@mail.nwpu.edu.cn
Supported by:
Natural Science Foundation of China(51972027)

摘要/Abstract

摘要：

高熵陶瓷作为新型材料, 较大的构型熵赋予其独特的性能, 其中高熵过渡金属碳化物有望成为高超声速飞行器热防护系统的备选材料。相比于单组元碳化物陶瓷, 高熵化的单相陶瓷在综合性能上有较大地提高。目前, 高熵过渡金属碳化物陶瓷的研究还处于初始阶段, 关于高熵过渡金属碳化物的成分设计和理论分析还缺少足够的研究支撑。另外, 如何制备高纯度高熵过渡金属碳化物还需要进一步探索。在高熵过渡金属碳化物陶瓷的性能方面, 还缺少深入的研究。本文针对高熵陶瓷的理论设计和制备方法展开综述, 详细介绍了高熵过渡金属碳化物的力学、热导及抗氧化性能的研究进展, 并指出了高熵过渡金属碳化物陶瓷在超高温陶瓷领域存在的科学问题, 展望了高熵过渡金属碳化物陶瓷未来的发展方向。

关键词: 高熵过渡金属碳化物陶瓷, 构型熵, 力学性能, 热导性能, 抗氧化性能, 综述

Abstract:

As a new emergence material, high-entropy ceramics possess unique properties due to its high configurational entropy. Among these ceramics, high-entropy transition metal carbide ceramics (HETMCC) are expected to be the potential candidates for the thermal protection system of hypersonic aircraft. Compared with single-component ceramics, the comprehensive performance of single-phase HETMCC is greatly improved. At present, the research on HETMCC is still in the initial stage, and the composition design and theoretical analysis of HETMCC are lack of sufficient research support. In addition, it is necessary to further explore the preparation of high purity HETMCC. In terms of the properties of HETMCC, further in-depth research has been conducted. In this paper, the theoretical design and preparation methods of high-entropy ceramics are reviewed. Research progress of the mechanical properties, thermal conductivity, and oxidation resistance properties of HETMCC are introduced in detail. The concerned scientific issues of HETMCC are pointed out and their future development direction are also prospected.

Key words: high-entropy transition metal carbide, configurational entropy, mechanical property, thermal conductivity, oxidation-resistance, review

中图分类号:

TQ174

王皓轩, 刘巧沐, 王一光. 高熵过渡金属碳化物陶瓷的研究进展[J]. 无机材料学报, 2021, 36(4): 355-364.

WANG Haoxuan, LIU Qiaomu, WANG Yiguang. Research Progress of High Entropy Transition Metal Carbide Ceramics[J]. Journal of Inorganic Materials, 2021, 36(4): 355-364.

图/表 5

图1 晶体结构示意图[19,20,21,22,23,24,25,26,27,28,29,30]

Fig. 1 Schematic diagrams of crystal structure[19,20,21,22,23,24,25,26,27,28,29,30]

图2 (a)不同碳含量高熵CrNbSiTiZrCx薄膜硬度[84], (b)不同碳化物硬度-深度曲线[87]

Fig. 2 (a) Hardness of the CrNbSiTiZrCx with different carbon contents[84], and (b) hardness depth-profles of the individual, binary and high-entropy carbide[87]

表1 部分碳化物陶瓷硬度[31,74,88-90]

Table 1 Hardness of some carbide ceramics[31,74,88-90]

HEC	Hardness/GPa	Average/GPa
HfC^[31]	25	—
TaC^[31]	14	—
ZrC^[31]	24	—
TiC^[31]	31	—
NbC^[31]	17	—
WC^[88]	14	—
VC^[31]	29	—
Mo₂C^[31]	27	—
(ZrNbTiV)C^[74]	30	25
(HfTaZrNb)C^[87]	36	20
(TiVNbTaW)C^[31]	28	21
(TiHfTaWZr)C^[31]	33	22
(TiHfNbTaMo)C^[89]	27	23
(TiZrNbTaMo)C^[90]	32	23
(VNbTaMoW)C^[31]	27	20
(HfTaZrTiNb)C^[31]	32	28
(TiZrHfTaW)C^[89]	24	22
(TiHfNbTaW)C^[31]	31	20
(TiHfVNbTa)C^[31]	29	23

图3 高熵陶瓷热导性能[93]

Fig. 3 Thermal conductivities for high-entropy ceramics[93]

图4 (a) (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C在800~1200 ℃氧化增重曲线[95], 和(b)不同体系碳化物在1500 ℃氧化增重曲线[33,97,99]

Fig. 4 (a) Square of the specific weight change as a function of oxidation time at 800-1200 ℃ for (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C[95], (b) square of the specific weight change as a function of oxidation time at 1500 ℃ for high-entropy carbide in different systems[33,97,99]

参考文献 101

[1]	MIRACLE D B, SENKOV O N. A critical review of high entropy alloys and related concepts. Acta Mater., 2017,122:448-511.
[2]	YEH J W, CHEN S K, LIN S J, et al. Nanostructured high- entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater., 2004,6(5):299-303.
[3]	KUCZA W, DABROWA J, CIESLAK G, et al. Studies of “sluggish diffusion” effect in Co-Cr-Fe-Mn-Ni, Co-Cr-Fe-Ni and Co-Fe-Mn-Ni high entropy alloys; determination of tracer diffusivities by combinatorial approach. J. Alloys Compd., 2018,731:920-928. DOI URL
[4]	UTT D, STUKOWSKI A, ALBE K. Grain boundary structure and mobility in high-entropy alloys: a comparative molecular dynamics study on a 11 symmetrical tilt grain boundary in face-centered cubic CuNiCoFe. Acta Mater., 2020,186:11-19.
[5]	GLUDOVATZ B, HOHENWARTER A, CATOOR D, et al. A fracture-resistant high-entropy alloy for cryogenic applications. Science, 2014,345(6201):1153-1158. URL PMID
[6]	LI Z M, PRADEEP K G, DENG Y, et al. Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off. Nature, 2016,534(7606):227-230. URL PMID
[7]	ZHANG R Z, REECE M J. Review of high entropy ceramics: design, synthesis, structure and properties. J. Mater. Chem. A, 2019,7(39):22148-22162.
[8]	MURTY B S, YEH J W, RANGANATHAN S, et al. High-entropy Alloys. United Kingdom: Butterworth-Heinemann, 2019: 165-176.
[9]	OSES C, TOHER C, CURTAROLO S. High-entropy ceramics. Nat. Rev. Mater., 2020,5(4):295-309.
[10]	LAL M S, SUNDARA R. High entropy oxides-a cost-effective catalyst for the growth of high yield carbon nanotubes and their energy applications. ACS Appl. Mater. Inter., 2019,11(34):30846-30857.
[11]	SARKAR A, VELASCO L, WANG D, et al. High entropy oxides for reversible energy storage. Nat. Commun., 2018,9(1):3400. URL PMID
[12]	BERARDAN D, FRANGER S, DRAGOE D, et al. Colossal dielectric constant in high entropy oxides. Phys. Status Solidi-R, 2016,10(4):328-333.
[13]	BIESUZ M, SPIRIDIGLIOZZI L, DELLAGLI G, et al. Synthesis and sintering of (Mg,Co,Ni,Cu,Zn)O entropy-stabilized oxides obtained by wet chemical methods. J. Mater. Sci., 2018,53(11):8074-8085.
[14]	OKEJIRI F, ZHANG Z H, LIU J X, et al. Room-temperature synthesis of high-entropy perovskite oxide nanoparticle catalysts via ultrasonication-based method. ChemSusChem, 2020,13(1):111-115. DOI URL PMID
[15]	DEMIRSKYI D, BORODIANSKA H, SUZUKI T S, et al. High- temperature flexural strength performance of ternary high-entropy carbide consolidated via spark plasma sintering of TaC, ZrC and NbC. Scripta Mater., 2019,164:12-16.
[16]	LI F, BAO W C, SUN S K, et al. Synthesis of single-phase metal oxycarbonitride ceramics. Scripta Mater., 2020,176:17-22.
[17]	KUMAR A, GUPTA M. An insight into evolution of light weight high entropy alloys: a review. Metals Basel, 2016,6(9):199.
[18]	ROST C M, SACHET E, BORMAN T, et al. Entropy-stabilized oxides. Nat. Commun., 2015,6(1):8485.
[19]	WEI X F, QIN Y, LIU J X, et al. Gradient microstructure development and grain growth inhibition in high-entropy carbide ceramics prepared by reactive spark plasma sintering . J. Eur. Ceram. Soc., 2020,40(4):935-941.
[20]	LI F, LU Y, WANG X G, et al. Liquid precursor-derived high- entropy carbide nanopowders. Ceram. Int., 2019,45(7):22437-22441.
[21]	WEI X F, LIU J X, LI F, et al. High entropy carbide ceramics from different starting materials. J. Eur. Ceram. Soc., 2019,39(10):2989-2994.
[22]	DUSZA J, SVEC P, GIRMAN V, et al. Microstructure of (Hf-Ta-Zr-Nb)C high-entropy carbide at micro and nano/atomic level. J. Eur. Ceram. Soc., 2018,38(12):4303-4307.
[23]	ZHOU J Y, ZHANG J Y, ZHANG F, et al. High-entropy carbide: a novel class of multicomponent ceramics. Ceram. Int., 2018,44(17):22014-22018.
[24]	JIANG S C, HU T, GILD J, et al. A new class of high-entropy perovskite oxides. Scripta Mater., 2018,142:116-120.
[25]	ZHAO Z F, CHEN H, XIANG H M, et al. (Y_0.25Yb_0.25Er_0.25Lu_0.25)₂(Zr_0.5Hf_0.5)₂O₇: a defective fluorite structured high entropy ceramic with low thermal conductivity and close thermal expansion coefficient to Al₂O₃. J. Mater. Sci. Technol., 2020,39:167-172.
[26]	DABROWA J, STYGAR M, MIKULA A, et al. Synthesis and microstructure of the (Co,Cr,Fe,Mn,Ni)₃O₄ high entropy oxide characterized by spinel structure. Mater. Lett., 2018,216:32-36.
[27]	ZHAO Z F, CHEN H, XIANG H M, et al. (La_0.2Ce_0.2Nd_0.2Sm_0.2Eu_0.2)PO₄: a high-entropy rare-earth phosphate monazite ceramic with low thermal conductivity and good compatibility with Al₂O₃. J. Mater. Sci. Technol., 2020,38:80-85.
[28]	GILD J, KAUFMANN K, Vecchio K, et al. Reactive flash spark plasma sintering of high-entropy ultrahigh temperature ceramics. Scripta. Mater., 2019,170:106-110.
[29]	YAN J L, LIU F S, MA G H, et al. Suppression of the lattice thermal conductivity in NbFeSb-based half-Heusler thermoelectric materials through high entropy effects. Scripta Mater., 2018,157:129-134.
[30]	GILD J, BRAUN J L, KAUFMANN K, et al. A high-entropy silicide: (Mo_0.2Nb_0.2Ta_0.2Ti_0.2W_0.2)Si₂. J. Mater., 2019,5(3):337-343.
[31]	SARKER P, HARRINGTON T, TOHER C, et al. High-entropy high-hardness metal carbides discovered by entropy descriptors. Nat. Commun., 2018,9(1):4980. URL PMID
[32]	SARKAR A, VELASCO L, WANG D, et al. High entropy oxides for reversible energy storage. Nat. Commun., 2018,9(1):3400. URL PMID
[33]	WANG H X, CAO Y J, LIU W, et al. Oxidation behavior of (Hf_0.2Ta_0.2Zr_0.2Ti_0.2Nb_0.2)C-xSiC ceramics at high temperature. Ceram. Int., 2020,46(8):11160-11168. DOI URL
[34]	TAN Y Q, CHEN C, Li S G, et al. Oxidation behaviours of high-entropy transition metal carbides in 1200 ℃ water vapor. J. Alloys Compd., 2020,816:152523.
[35]	REN K, WANG Q K, SHAO G, et al. Multicomponent high- entropy zirconates with comprehensive properties for advanced thermal barrier coating. Scripta Mater., 2020,178:382-386.
[36]	DONG Y, REN K, LU Y H, et al. High-entropy environmental barrier coating for the ceramic matrix composites. J. Eur. Ceram. Soc., 2018,39(7):2574-2579.
[37]	TENG Z, ZHU L N, TAN Y Q, et al. Synjournal and structures of high-entropy pyrochlore oxides. J. Eur. Ceram. Soc., 2020,40(4):1639-1643.
[38]	ZHAO Z F, XIANG H M, DAI F Z, et al. (La_0.2Ce_0.2Nd_0.2Sm_0.2Eu_0.2)₂Zr₂O₇: A novel high-entropy ceramic with low thermal conductivity and sluggish grain growth rate. J. Mater. Sci. Technol., 2019,35(11):2647-2651.
[39]	SAVINO R, FUMO M D S, PATERNA D, et al. Aerothermodynamic study of UHTC-based thermal protection systems. Aerosp. Sci. Technol., 2005,9(2):151-160.
[40]	OPRKA M M, TALMY I G, ZAYKOSKI J A. Oxidation-based materials selection for 2000 ℃ + hypersonic aerosurfaces: theoretical considerations and historical experience. J. Mater. Sci., 2004,39(19):5887-5904.
[41]	KUBOTA Y, YANO M, INOUE R, et al. Oxidation behavior of ZrB₂-SiC-ZrC in oxygen-hydrogen torch environment. J. Eur. Ceram. Soc., 2017,38(4):1095-1102.
[42]	RAMA RAO G A, VENUGOPAL V. Kinetics and mechanism of the oxidation of ZrC. J. Alloys Compd., 1994,206(2):237-242.
[43]	VOITOVICH R F, PUGACH E A. High-temperature oxidation of ZrC and HfC. Powder Metall. Met. C, 1973,12(11):916-921.
[44]	CHEN L Y, GU Y L, SHI L, et al. Synjournal and oxidation of nanocrystalline HfB₂. J. Alloys Compd., 2004,368(1):353-356.
[45]	SHIMADA S. Interfacial reaction on oxidation of carbides with formation of carbon. Solid State Ionics, 2001,141:99-104.
[46]	PARTHASARATHY T A, RAPP R A, OPEKA M M, et al. A model for the oxidation of ZrB₂, HfB₂ and TiB₂. Acta Mater., 2007,55(17):5999-6010.
[47]	PARTHASARATHY T A, RAPP R A, OPEKA M M, et al. Effect of phase change and oxygen permeability in oxide scales on oxidation kinetics of ZrB₂ and HfB₂. J. Am. Ceram. Soc., 2009,92(5):1079-1086.
[48]	JING Y, YUAN H B, LIAN Z S. Microstructure and mechanical properties of ZrB₂-HfC ceramics influenced by HfC addition. Materials, 2018,11(10):2046.
[49]	MALLIK M, RAY K K, MITRA R. Oxidation behavior of hot pressed ZrB₂-SiC and HfB₂-SiC composites. J. Eur. Ceram. Soc., 2011,31(1):199-215.
[50]	TRIPP W C, GRAHAM H C. Thermogravimetric study of oxidation of ZrB₂ in temperature range of 800 ℃ to 1500 ℃. J. Electrochem. Soc., 1971,118(7):1195-1199.
[51]	FAHRENHOLTZ W G. The ZrB₂ volatility diagram. J. Am. Ceram. Soc., 2005,88(12):3509-3512.
[52]	FAHRENHOLTZ W G. Thermodynamic analysis of ZrB₂-SiC oxidation: formation of a SiC-depleted region . J. Am. Ceram. Soc., 2007,90(1):143-148.
[53]	HU P, GUOLIN W, WANG Z. Oxidation mechanism and resistance of ZrB₂-SiC composites. Corros. Sci., 2009,51(11):2724-2732.
[54]	JACOBSON N S, MYERS D L. Active oxidation of SiC. Oxid. Met., 2011,75(1):1-25.
[55]	JACOBSON N S, HARDER B, MYERS D L, et al. Oxidation transitions for SiC. Part I. Active-to-passive transitions. J. Am. Ceram. Soc., 2013,96(3):838-844.
[56]	WANG Y G, LUO L, SUN J, et al. ZrB₂-SiC(Al) ceramics with high resistance to oxidation at 1500 ℃. Corros. Sci., 2013,74:154-158.
[57]	HE J B, WANG Y G, LUO L, et al. Oxidation behaviour of ZrB₂-SiC (Al/Y) ceramics at 1700 ℃. J. Eur. Ceram. Soc., 2016,36(15):3769-3774.
[58]	WANG Y G, MA B S, LI L L, et al. Oxidation behavior of ZrB₂-SiC-TaC ceramics . J. Am. Ceram. Soc., 2012,95(1):374-378.
[59]	TONG Z W, HE R J, CHENG T B, et al. High temperature oxidation behavior of ZrB₂-SiC added MoSi₂ ceramics. Ceram. Int., 2018,44(17):21076-21082. DOI URL
[60]	ZAPATASOLVAS E, JAYASEELAN D D, BROWN P, et al. Effect of La₂O₃ addition on long-term oxidation kinetics of ZrB₂-SiC and HfB₂-SiC ultra-high temperature ceramics . J. Eur. Ceram. Soc., 2014,34(15):3535-3548.
[61]	GILD J, ZHANG Y Y, HARRINGTON T, et al. High-entropy metal diborides: a new class of high-entropy materials and a new type of ultrahigh temperature ceramics. Sci. Rep-UK, 2016,6(1):37946-37946.
[62]	YE B L, WEN T Q, HUANG K H, et al. First-principles study, fabrication, and characterization of (Hf_0.2Zr_0.2Ta_0.2Nb_0.2Ti_0.2)C high- entropy ceramic. J. Am. Ceram. Soc., 2019,102(7):4344-4352.
[63]	HOSKING F M. Sodium compatibility of refractory-metal alloy- type 304l stainless-steel joints. Int. J. Refract. Met. H., 1985,64(7):S181-S190.
[64]	WERNER E A. Introduction to the thermodynamics of materials. Mat. Sci. Eng., 2008,494(1/2):464.
[65]	CAR R, PARRINELLO M. Unified approach for molecular dynamics and density-functional theory. Phys. Rev. Lett., 1985,55(22):2471-2474. URL PMID
[66]	LIU X J, WANG C P, GAO F, et al. Thermodynamic calculation of phase equilibria in the Sn-Ag-Cu-Ni-Au System . J. Electron. Mater., 2007,36(11):1429-1441.
[67]	WANG C P, WANG J, GUO S H, et al. Experimental investigation and thermodynamic calculation of the phase equilibria in the Co-Mo-W system. Intermetallics, 2009,17(8):642-650.
[68]	FENG R, GAO M C, LEE C, et al. Design of light-weight high- entropy alloys. Entropy Switz., 2016,18(9):333-353.
[69]	KIM J. Applicability of special quasi-random structure models in thermodynamic calculations using semi-empirical Debye-Grüneisen theory . J. Alloys Compd., 2015,650:564-571.
[70]	VOAS B K, USHER T M, LIU X M, et al. Special quasirandom structures to study the (K_0.5Na_0.5)NbO₃ random alloy. Phys. Rev. B, 2014,90(2):024105-1-6.
[71]	SAHARA R, EMURA S, LI S, et al. First-principles study of electronic structures and stability of body-centered cubic Ti-Mo alloys by special quasirandom structures. Sci. Technol. Adv. Mat., 2014,15(3):035014-1-10.
[72]	VITOS L, ABRIKOSOV I A, JOHANSSON B. Anisotropic lattice distortions in random alloys from first-principles theory. Phys. Rev. Lett., 2001,87(15):156401-1-4. URL PMID
[73]	ABRIKOSOV I A, JOHANSSON B. Applicability of the coherent- potential approximation in the theory of random alloys. Phys. Rev. B, 1998,57(22):14164-14173.
[74]	YE B L, WEN T Q, NGUYEN M C, et al. First-principles study, fabrication and characterization of (Zr_0.25Nb_0.25Ti_0.25V_0.25)C high- entropy ceramics. Acta Mater., 2019,170:15-23.
[75]	BRAIC V, VLADESCU A, BALACEANU M, et al. Nanostructured multi-element (TiZrNbHfTa)N and (TiZrNbHfTa)C hard coatings. Surf. Coat. Tech., 2012,211:117-121. DOI URL
[76]	LIN S Y, CHANG S Y, HUANG Y C, et al. Mechanical performance and nanoindenting deformation of (AlCrTaTiZr)NC_y multi-component coatings co-sputtered with bias. Surf. Coat. Tech., 2012,206(24):5096-5102. DOI URL
[77]	ZHOU J Y, ZHANG J Y, ZHANG F, et al. high-entropy carbide: a novel class of multicomponent ceramics. Ceram. Int., 2018,44(17):22014-22018. DOI URL
[78]	FENG L, FAHRENHOLTZ W G, HILMAS G E, et al. Synthesis of single-phase high-entropy carbide powders. Scripta Mater., 2019,162(12):90-93. DOI URL
[79]	YE B L, NING S S, LIU D, et al. One-step synthesis of coral-like high-entropy metal carbide powders. J.Am. Ceram. Soc., 102(10):6372-6378.
[80]	DU B, LIU H H, CHU Y H. Fabrication and characterization of polymer-derived high-entropy carbide ceramic powders . J. Am. Ceram. Soc., 2020,103:4063-4068. DOI URL
[81]	NING S S, WEN T Q, YE B L, et al. Low-temperature molten salt synjournal of high-entropy carbide nanopowders . J. Am. Ceram. Soc., 2020,103(3):2244-2251.
[82]	JAGADEESH S, VISHNU D S M, KIM H K, et al. Facile electrochemical synthesis of nanoscale (TiNbTaZrHf)C high-entropy carbide powder. Angew. Chem. Int. Ed., 2020 59(29):11830-11835.
[83]	BRAIC M, BRAIC V, BALACEANU M, et al. Characteristics of (TiAlCrNbY)C films deposited by reactive magnetron sputtering. Surf. Coat. Tech., 2010,204(12):2010-2014.
[84]	JHONG Y S, HUANG C W, LIN S J, et al. Effects of CH₄ flow ratio on the structure and properties of reactively sputtered (CrNbSiTiZr)C_x coatings. Mater. Chem. Phys., 2017,210:348-352.
[85]	BRAIC M, BALACEANU M, VLADESCU A, et al. Deposition and characterization of multi-principal-element (CuSiTiYZr)C coatings. Appl. Surf. Sci., 2013 284:671-678.
[86]	BRAIC V, PARAU A C, PANA I, et al. Effects of substrate temperature and carbon content on the structure and properties of (CrCuNbTiY)C multicomponent coatings. Surf. Coat. Tech., 2014 258:996-1005.
[87]	CSANADI T, CASTLE E G, REECE M J, et al. Strength enhancement and slip behaviour of high-entropy carbide grains during micro-compression. Sci. Rep-UK, 2019,9(1):10200.
[88]	WANG C, YE Y, GUAN X, et al. An analysis of tribological performance on Cr/GLC film coupling with Si₃N₄, SiC, WC, Al₂O₃ and ZrO₂ in seawater. Tribol. Int., 2016 96:77-86.
[89]	HARRINGTON T J, GILD J, SARKER P, et al. Phase stability and mechanical properties of novel high entropy transition metal carbides. Acta Mater., 2019 166:271-280.
[90]	WANG K, CHEN L, XU C G, et al. Microstructure and mechanical properties of (TiZrNbTaMo)C high-entropy ceramic. J. Mater. Sci. Technol., 2020,39:99-105.
[91]	HAN X X, VLADIMIR G, RICHARD S, et al. Improved creep resistance of high entropy transition metal carbides . J. Eur. Ceram. Soc., 2020,40(7):2709-2715.
[92]	YAN X L, CONSTANTIN L, LU Y F, et al. (Hf_0.2Zr_0.2Ta_0.2Nb_0.2Ti_0.2)C high-entropy ceramics with low thermal conductivity. J. Am. Ceram. Soc., 2018,101(10):4486-4491.
[93]	CHEN H, XIANG H M, DAI F Z, et al. Porous high entropy (Zr_0.2Hf_0.2Ti_0.2Nb_0.2Ta_0.2)B₂: a novel strategy towards making ultrahigh temperature ceramics thermal insulating. J. Mater. Sci. Technol., 2019,35(10):2404-2408.
[94]	CHEN H, XIANG H M, DAI F Z, et al. High porosity and low thermal conductivity high entropy (Zr_0.2Hf_0.2Ti_0.2Nb_0.2Ta_0.2)C. J. Mater. Sci. Technol., 2019,35(8):1700-1705.
[95]	YE B L, WEN T Q, LIU D, et al. Oxidation behavior of (Hf_0.2Zr_0.2Ta_0.2Nb_0.2Ti_0.2)C high-entropy ceramics at 1073-1473 K in air. Corros. Sci., 2019,153:327-332. DOI URL
[96]	YE B L, WEN T Q, CHU Y H. High-temperature oxidation behavior of (Hf_0.2Zr_0.2Ta_0.2Nb_0.2Ti_0.2)C high-entropy ceramics in air. J. Am. Ceram. Soc., 2019,103(1):500-507.
[97]	WANG H X, HAN X, LIU W, et al. Oxidation behavior of high-entropy carbide (Hf_0.2Ta_0.2Er_0.2Ti_0.2Nb_0.2)C at 1400-1600 ℃. DOI: 10.1016/j.ceramint.2020.12.201.
[98]	BACKMAN L, GILD J, LUO J, et al. Theoretical predictions of preferential oxidation in refractory high entropy materials. Acta Mater., 2020,197:20-27.
[99]	WANG H X, WANG S Y, CAO Y J, et al. Oxidation behaviors of (Hf_0.25Zr_0.25Ta_0.25Nb_0.25)C and (Hf_0.25Zr_0.25Ta_0.25Nb_0.25)C-SiC at 1300-1500 ℃. J. Mater. Sci. Technol., 2021,60:147-155.
[100]	BRAIC V, BALACEANU M, BRAIC M, et al. Characterization of multi-principal-element (TiZrNbHfTa)N and (TiZrNbHfTa)C coatings for biomedical applications. J. Mech. Behav. Biomed., 2019,10:197-205. DOI URL
[101]	WANG F, YAN X L, WANG T Y, et al. Irradiation damage in (Zr_0.25Ta_0.25Nb_0.25Ti_0.25)C high-entropy carbide ceramics. Acta Mater., 2020,195:739-749.

高熵过渡金属碳化物陶瓷的研究进展

Research Progress of High Entropy Transition Metal Carbide Ceramics

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