过渡金属非氧化物高熵陶瓷的研究进展

doi:10.15541/jim20190408

无机材料学报 ›› 2020, Vol. 35 ›› Issue (7): 748-758.DOI: 10.15541/jim20190408

所属专题：结构陶瓷论文精选(2020)；优秀作者论文集锦； 2019~2020年度优秀作者作品欣赏(六)；【结构材料】高熵陶瓷

过渡金属非氧化物高熵陶瓷的研究进展

陈磊^1,²,王恺^1,²,苏文韬^1,²,张文^1,²,徐晨光^1,²,王玉金^1,²(),周玉^1,²

1. 哈尔滨工业大学材料科学与工程学院特种陶瓷研究所
2. 哈尔滨工业大学先进结构功能一体化材料与绿色制造技术工信部重点实验室, 哈尔滨 150001

收稿日期:2019-08-12 修回日期:2019-10-23 出版日期:2020-07-20 网络出版日期:2019-12-04
作者简介:陈磊(1983-), 男, 助理研究员. E-mail: chenleihit@hit.edu.cn
CHEN Lei(1983-), male, lecturer. E-mail: chenleihit@hit.edu.cn
基金资助:
国家自然科学基金(51972081);国家自然科学基金(51602074);国家自然科学基金(51872061);国家自然科学基金(51621091);黑龙江省自然科学基金(E2016026)

Research Progress of Transition Metal Non-oxide High-entropy Ceramics

CHEN Lei^1,²,WANG Kai^1,²,SU Wentao^1,²,ZHANG Wen^1,²,XU Chenguang^1,²,WANG Yujin^1,²(),ZHOU Yu^1,²

1. Institute for Advanced Ceramics, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
2. Key Laboratory of Advanced Structure-functional Integration Materials & Green Manufacturing Technology, Harbin Institute of Technology, Harbin 150001, China

Received:2019-08-12 Revised:2019-10-23 Published:2020-07-20 Online:2019-12-04
Supported by:
National Natural Science Foundation of China(51972081);National Natural Science Foundation of China(51602074);National Natural Science Foundation of China(51872061);National Natural Science Foundation of China(51621091);Natural Science Foundation of Heilongjiang Province(E2016026)

摘要/Abstract

摘要：

高熵陶瓷是一种新兴的近等摩尔多组元单相固溶体陶瓷材料, 特别是过渡金属碳化物、过渡金属硼化物等过渡金属非氧化物高熵陶瓷体系, 其具有超高硬度、低热导和抗腐蚀等优异的理化性能, 在航空航天、核能和高速切削加工等极端环境有着广阔的应用前景。目前, 高熵陶瓷材料研究尚处于起步阶段, 主要集中在成分设计、制备方法、单相形成能力和力学性能评价等方面, 设计依据和理论方面的研究还相对较少。本文从高熵效应和高熵合金出发, 综述了过渡金属非氧化物高熵陶瓷的制备、表征和理论研究进展, 同时介绍了部分相关的高熵陶瓷涂层研究现状, 总结并展望了非氧化物高熵陶瓷的未来前景和发展方向。

关键词: 高熵陶瓷, 非氧化物, 制备工艺, 显微组织, 性能, 综述

Abstract:

High-entropy ceramics, a novel class of single-phase ceramic solid solutions consisting of near-equimolar multielement species, are recently attracting tremendous attentions. Especially, the transition metal non-oxide high-entropy ceramics, such as transition metal carbide and boride high-entropy ceramics, have been proposed for potential applications in aerospace, nuclear energy, high-speed machining and many other extreme environments, owing to their excellent physical and chemical properties including super-high hardness, low thermal conductivity, good oxidation resistance and corrosion/erosion resistance. Recently, the research of high-entropy ceramics is only focused on composition design, fabrication methods, single-phase stability and mechanical properties, but the design criterion and theoretical analysis are rarely reported. Based on the researches of high-entropy alloy, the fabrication, characterization and theoretical study of several transition metal non-oxide high-entropy ceramics are summarized, along with some related results of high-entropy film. The prospects for the future developments of high-entropy ceramics are also discussed.

Key words: high-entropy ceramic, non-oxide ceramic, fabrication process, microstructure, performance, review

中图分类号:

TB332

陈磊,王恺,苏文韬,张文,徐晨光,王玉金,周玉. 过渡金属非氧化物高熵陶瓷的研究进展[J]. 无机材料学报, 2020, 35(7): 748-758.

CHEN Lei,WANG Kai,SU Wentao,ZHANG Wen,XU Chenguang,WANG Yujin,ZHOU Yu. Research Progress of Transition Metal Non-oxide High-entropy Ceramics[J]. Journal of Inorganic Materials, 2020, 35(7): 748-758.

图/表 7

图1 NbTaMoW高熵合金的电阻率比较[19]

Fig. 1 Comparison of electrical resistivity between NbTaMoW high-entropy alloy and other single alloys[19]

表1 部分碳化物高熵陶瓷的EFA值大小排序[29]

Table 1 Ranking of some high-entropy carbides based on the EFA values[29]

Ranking	HEC	EFA/(eV·atom)^-1^a	Ranking	HEC	EFA/(eV·atom)^-1^a
(1)	(VNbTaMoW)C	125	(23)	(TiZrNbTaW)C	59
(2)	(TiZrHfNbTa)C	100	(29)	(ZrVNbTaW)C	56
(3)	(TiHfVNbTa)C	100	(33)	(TiZrHfNbW)C	53
(4)	(TiVNbTaMo)C	100	(36)	(TiZrHfTaW)C	50
(5)	(TiZrNbTaV)C	83	(44)	(TiZrTaMoW)C	48
(7)	(TiVNbTaW)C	77	(52)	(ZrHfTaMoW)C	45
(10)	(TiZrNbTaMo)C	71	(55)	(TiZrHfMoW)C	38
(17)	(TiHfNbTaW)C	67	(56)	(ZrHfVMoW)C	37

图2 不同原料制备的(TiZrNbTaW)C高熵陶瓷的((a)单质为原料、(b)碳化物为原料和(c)氧化物和碳为原料)断口、表面SEM照片和EDS元素分布, 以(d)单质、(e)碳化物和(f)氧化物和碳为原料制备陶瓷的背散射图像[43]

Fig. 2 SEM images of the fracture surfaces, polished surfaces and their corresponding EDS element mappings of (TiZrNbTaW)C using (a) metallic powders and graphite, (b) metal carbides and (c) metal oxides and graphite as raw materials, as well as the back scattered electron images of (TiZrNbTaW)C using (d) metallic powders and graphite,(e) metal carbides and (f) metal oxides and graphite as raw materials[43]

图3 (HfTaZrNb)C高熵陶瓷与一元碳化物、二元碳化物固溶体之间的硬度-深度变化曲线[37]

Fig. 3 Comparison of hardness depth-profiles of the mono, binary and (HfTaZrNb)C high-entropy transition metal carbides[37]

图4 五组元高熵陶瓷的硬度对比[25,27-29,31,34,46]

Fig. 4 Comparison of hardness for different series of quinary high-entropy ceramics[25,27-29,31,34,46]

图5 (TiZrHfNbTa)C高熵陶瓷及其相关(TiZrNbTa)C、(TiZrNb)C和ZrC陶瓷材料随时间的增重变化对比[52]

Fig. 5 Comparison of weight gain per unit area as a function of exposure time for (TiZrHfNbTa)C high-entropy ceramic and related (TiZrHNbTa)C, (TiZrNb)C, ZrC ceramic[52]

图6 不同温度烧结制备的(TiZrHfNbTa)B2的EDS元素分布图[57]

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过渡金属非氧化物高熵陶瓷的研究进展

Research Progress of Transition Metal Non-oxide High-entropy Ceramics

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