Microstructure and Properties of ZrO2-AlN Composite Ceramics by Microwave Sintering

doi:10.15541/jim20210150

Abstract

Abstract:

Zirconia (ZrO₂) ceramics have excellent mechanical properties, but its application is limited by ZrO₂-AlN low thermal conductivity (TC). Zirconia-aluminum nitride (AlN) composite ceramics ZrO₂-AlN with high TC were designed and successfully fabricated by microwave sintering. After optimization of preparation conditions, the reaction between two substances was inhibited and the dense composite (relative density>99%) was obtained. The microstructure evolution, thermal behavior and mechanical properties were investigated in detail. The room temperature thermal conductivity, thermal diffusion coefficient and thermal capacity of ZrO₂-AlN composites increase with AlN content increasing, reaching 41.3 W/(m·K), 15.2 mm²/s and 0.6 J/(g·K), respectively. Such ZrO₂-AlN composites with high thermal conductivity and improved thermal shock resistance have broad application prospects in the field of high temperature heat exchange materials of energy systems.

Key words: zirconia, aluminum nitride, composite ceramic, microwave sintering, thermal conductivity

CLC Number:

TQ174

MU Tinghai, XU Wentao, LING Junrong, DONG Tianwen, QIN Zixuan, ZHOU Youfu. Microstructure and Properties of ZrO₂-AlN Composite Ceramics by Microwave Sintering[J]. Journal of Inorganic Materials, 2021, 36(11): 1231-1236.

Figures/Tables 9

References 23

[1]	LI J, PENG J, GUO S, et al. Thermodynamic calculations of t to m martenstic transformation of ZrO₂-CaO binary system. Ceramics International, 2012, 38(4):2743-2747. DOI URL
[2]	LI K, WANG D, CHEN H, et al. Normalized evaluation of thermal shock resistance for ceramic materials. Journal of Advanced Ceramics, 2014, 3(3):250-258. DOI URL
[3]	YOSHINAGA M, SASAKI T, KOBAYASHI N. Effect of microwave irradiation for crystallization behavior of yttria-stabilized zirconia system. Journal of the Ceramic Society of Japan, 2019, 127(10):767-772. DOI URL
[4]	MALYI O I, WU P, KULISH V V, et al. Formation and migration of oxygen and zirconium vacancies in cubic zirconia and zirconium oxysulfide. Solid State Ionics, 2012, 212:117-122. DOI URL
[5]	WANG L, LIANG T. Ceramics for high level radioactive waste solidification. Journal of Advanced Ceramics, 2012, 1(3):194-203. DOI URL
[6]	LI B, YANG, CHU M, et al. Ti₃SiC₂/UO₂ composite pellets with superior high-temperature thermal conductivity. Ceramics International, 2018, 44(16):19846-19850. DOI URL
[7]	HOLGATE C S, SEWARD G G E, ERICKS A R, et al. Dissolution and diffusion kinetics of yttria-stabilized zirconia into molten silicates. Journal of the European Ceramic Society, 2021, 41(3):1984-1994. DOI URL
[8]	MEBRAHITOM ASMELASH G, MAMAT O, AHMAD F, et al. Thermal shock and fatigue behavior of pressureless sintered Al₂O₃- SiO₂-ZrO₂ composites. Journal of Advanced Ceramics, 2015, 4(3):190-198. DOI URL
[9]	DONG K F, MO W Q, JIN F, et al. Effect of TiN-ZrO₂ intermediate layer on the microstructure and magnetic properties of FePt and FePt-SiO₂-C thin films. Journal of Magnetism and Magnetic Materials, 2017, 432:323-329. DOI URL
[10]	JI Y, FU R, LV J, et al. Enhanced bonding strength of Al₂O₃/AlN ceramics joined via glass frit with gradient thermal expansion coefficient. Ceramics International, 2020, 46(8):12806-12811. DOI URL
[11]	LAZAR A, KOSMAC T, ZAVASNIK J, et al. TiN-nanoparticulate- reinforced ZrO₂ for electrical discharge machining. Materials (Basel), 2019, 12(17):2788-2802. DOI URL
[12]	ESMAEILZAEI A, SAJJADI S A, MOLLAZADEH BEIDOKHTI S, et al. Rapid consolidation of Al₂O₃-TiO₂-Co nanocermets via spark plasma sintering of Co-coated ceramic particles. Journal of Alloys and Compounds, 2019, 771:79-88. DOI URL
[13]	OKAZAKI H, KOBAYASHI R, HASHIMOTO R, et al. Thermal conductivity and mechanical strength of low-temperature-sintered aluminum nitride ceramics containing aluminum nitride whiskers. Journal of the Ceramic Society of Japan, 2020, 128(11):991-994. DOI URL
[14]	YEH CT, TUAN W H. Oxidation mechanism of aluminum nitride revisited. Journal of Advanced Ceramics, 2017, 6(1):27-32. DOI URL
[15]	MIYAZAKI H, YOSHIZAWA YI. Correlation of the indentation fracture resistance measured using high-resolution optics and the fracture toughness obtained by the single edge-notched beam (SEPB) method for typical structural ceramics with various microstructures. Ceramics International, 2016, 42(6):7873-7876. DOI URL
[16]	TANAKA I. Impacts of first principles calculations in engineering ceramics. Journal of the Ceramic Society of Japan, 2016, 124(8):791-795. DOI URL
[17]	LU Y, YUAN Z, SHEN H, et al. High-temperature phase relations of ZrN-ZrO₂-Y₂O₃ ternary system. Journal of Advanced Ceramics, 2018, 7(4):388-391. DOI URL
[18]	CALLAWAY J. Model for lattice thermal conductivity at low temperatures. Physical Review, 1959, 113(4):1046-1051. DOI URL
[19]	TAO Y, LIU C, CHEN W, et al. Mean free path dependent phonon contributions to interfacial thermal conductance. Physics Letters A, 2017, 381(22):1899-1904. DOI URL
[20]	SLACK G A. Nonmetallic crystals with high thermal conductivity. J. Phys. Chem. Solids, 1972, 34:321-335. DOI URL
[21]	HONG H, KIM J, KIM T I. Effective assembly of nano-ceramic materials for high and anisotropic thermal conductivity in a polymer composite. Polymers, 2017, 9(9):413. DOI URL
[22]	CHEN H, WEI J, CHEN Y, et al. Theoretical investigation of the mechanical and thermodynamic properties of titanium pernitride under high temperature and high pressure. Journal of Alloys and Compounds, 2017, 726:1179-1185. DOI URL
[23]	NOVIKOV V V. Debye-Einstein model and anomalies of heat capacity temperature dependences of solid solutions at low temperatures. Journal of Thermal Analysis and Calorimetry, 2019, 138(1):265-272. DOI URL

Specimen	Composition
ZAN-0	100%ZrO₂
ZAN-1	95wt%ZrO₂+5wt%AlN
ZAN-2	90wt%ZrO₂+10wt%AlN
ZAN-3	85wt%ZrO₂+15wt%AlN
ZAN-4	80wt%ZrO₂+20wt%AlN

Specimen	Composition
ZAN-0	100%ZrO₂
ZAN-1	95wt%ZrO₂+5wt%AlN
ZAN-2	90wt%ZrO₂+10wt%AlN
ZAN-3	85wt%ZrO₂+15wt%AlN
ZAN-4	80wt%ZrO₂+20wt%AlN

Sample	Rotating speed/(r·min^-1)	Rotating time/h	Pressure/MPa	Relative density/%
1#	250	24	200	99.3
2#	250	12	200	98.5
3#	200	24	200	98.9
4#	250	24	100	98.1

Sample	Rotating speed/(r·min^-1)	Rotating time/h	Pressure/MPa	Relative density/%
1#	250	24	200	99.3
2#	250	12	200	98.5
3#	200	24	200	98.9
4#	250	24	100	98.1

Microstructure and Properties of ZrO₂-AlN Composite Ceramics by Microwave Sintering

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 23

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Weide, CHEN Huanbei, LI Shishuai, YAO Dongxu, ZUO Kaihui, ZENG Yuping. Preparation of Silicon Nitride with High Thermal Conductivity and High Flexural Strength Using YbH₂-MgO as Sintering Additive [J]. Journal of Inorganic Materials, 2021, 36(9): 959-966.
[2]	WANG Haoxuan, LIU Qiaomu, WANG Yiguang. Research Progress of High Entropy Transition Metal Carbide Ceramics [J]. Journal of Inorganic Materials, 2021, 36(4): 355-364.
[3]	SANG Weiwei, ZHANG Hongsong, CHEN Huahui, WEN Bin, LI Xinchun. Preparation and Thermophysical Properties of (Sm_0.2Gd_0.2Dy_0.2Y_0.2Yb_0.2)₃TaO₇High-entropy Ceramic [J]. Journal of Inorganic Materials, 2021, 36(4): 405-410.
[4]	ZHANG Li, YANG Xianfeng, XU Xiewen, GUO Jinyu, ZHOU Zhe, LIU Peng, XIE Zhipeng. 3D Printed Zirconia Ceramics via Fused Deposit Modeling and Its Mechanical Properties [J]. Journal of Inorganic Materials, 2021, 36(4): 436-442.
[5]	GAO Jiming, YANG Yang, LEI Ting, WANG Jin, LIU Jie, ZHANG Limin. Synthesis and Characterization of SiC@SiO₂/BN/PI Composites by in-situ Polymerization [J]. Journal of Inorganic Materials, 2021, 36(1): 36-42.
[6]	QIU Xiaoxiao,ZHOU Xiying,FU Yuntian,SUN Xiaomeng,WANG Lianjun,JIANG Wan. Influence of Ge_1-_xIn_xTe Microstructure on Thermoelectric Properties [J]. Journal of Inorganic Materials, 2020, 35(8): 916-922.
[7]	ZHANG Xiaoxu,ZHU Dongbin,LIANG Jinsheng. Progress on Hydrothermal Stability of Dental Zirconia Ceramics [J]. Journal of Inorganic Materials, 2020, 35(7): 759-768.
[8]	JI Xiaojuan,YU Yueguang,LU Xiaoliang. Effects of Impurities on Properties of YSZ Thermal Barrier Coatings [J]. Journal of Inorganic Materials, 2020, 35(6): 669-674.
[9]	LI Xing-Bang,ZHONG He,ZHANG Jing-Xian,DUAN Yu-Sen,JIANG Dong-Liang. Powder Characteristics on the Rheological Performance of Resin-based Zirconia Suspension for Stereolithography [J]. Journal of Inorganic Materials, 2020, 35(2): 231-235.
[10]	DAI Zhao,WANG Ming,WANG Shuang,LI Jing,CHEN Xiang,WANG Da-Lin,ZHU Ying-Chun. Zirconia Reinforced Trace Element Co-doped Hydroxyapatite Coating [J]. Journal of Inorganic Materials, 2020, 35(2): 179-186.
[11]	ZHOU Xingyuan, LIU Wei, ZHANG Cheng, HUA Fuqiang, ZHANG Min, SU Xianli, TANG Xinfeng. Optimization of Thermoelectric Transport Properties of Nb-doped Mo_1-_xW_xSeTe Solid Solutions [J]. Journal of Inorganic Materials, 2020, 35(12): 1373-1379.
[12]	LIU Fengqi, FENG Jian, JIANG Yonggang, LI Liangjun. Preparation and Application of Boron Nitride Aerogels [J]. Journal of Inorganic Materials, 2020, 35(11): 1193-1202.
[13]	HE Duan-Peng,GAO Hong,ZHANG Jing-Jing,WU Jie,LIU Bo-Tian,WANG Xiang-Ke. Simulation and Experimental Verification of Thermal Property for Aluminum Nitrides and Copper Clad Laminates under Space Thermal Environment [J]. Journal of Inorganic Materials, 2019, 34(9): 947-952.
[14]	Bo-Le MA, Wen MA, Wei HUANG, Yu BAI, Rui-Ling JIA, Hong-Ying DONG. Thermophysical Property of Single-phase Strontium Zirconate Co-doped with Double Rare-earth Oxides as a Thermal Barrier Coating Material [J]. Journal of Inorganic Materials, 2019, 34(4): 394-400.
[15]	Ren-Jie GENG, Song-Feng E, Chao-Wei LI, Tao-Tao LI, Jun WU, Ya-Gang YAO. High Crystallinity Boron Nitride Nanosheets: Preparation and the Property of BNNSs/Polyvinyl Alcohol Composite Film [J]. Journal of Inorganic Materials, 2019, 34(4): 401-406.