Journal of Inorganic Materials ›› 2023, Vol. 38 ›› Issue (2): 137-147.DOI: 10.15541/jim20220343
Special Issue: 【信息功能】电介质储能材料(202506)； 【信息功能】介电、铁电、压电材料（202506）
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XIE Bing1(
), CAI Jinxia1, WANG Tongtong1, LIU Zhiyong1, JIANG Shenglin2, ZHANG Haibo3
Received:2022-06-19
Revised:2022-09-21
Published:2023-02-20
Online:2022-10-28
About author:XIE Bing (1983-), male, PhD, associate professor. E-mail: xieb@nchu.edu.cn
Supported by:CLC Number:
XIE Bing, CAI Jinxia, WANG Tongtong, LIU Zhiyong, JIANG Shenglin, ZHANG Haibo. Research Progress of Polymer-based Multilayer Composite Dielectrics with High Energy Storage Density[J]. Journal of Inorganic Materials, 2023, 38(2): 137-147.
Fig. 1 PVDF-based composites and sandwich-structured BT/PVDF composites[28] (a) Electric field distribution simulation diagram; (b) Breakdown field strength; (c) COMSOL multi-physics field simulation; (d, e) Energy density
Fig. 2 BT@HPC/PVDF composite[27] (a, b1) Schematic diagram of preparation and space charge polarization distribution of BT@HPC/PVDF composites; (b2) Microcapacitor networks constructed by BT@HPC; (b3) Generated space charge region (SCR) surrounding BT@HPC in the PVDF matrix; (b4) Space charge regions in single-layer structural composites; (b5) Three-layer structural composites; (c) Weibull breakdown distribution; (d) Discharged energy density Colorful figures are available on website
Fig. 3 Schematic preparation of all-organic PMMA/P(VDF-HFP) films, cross-sectional SEM image, discharged energy density, and charge-discharge efficiency[35] (a) Schematic illustration of PMMA/P(VDF-HFP) films; (b) SEM cross-sectional image; (c) Discharged energy density; (d) Charge-discharge efficiency
Fig. 4 Three-layer composite film with PVDF/BNNS as the outer layer and PVDF/BST as the middle layer[26] (a) Structure schematic; (b) Weibull plots for the trilayer-structured nanocomposites indicating the failure distribution; (c) The development of electrical trees in the trilayer-structured nanocomposites with different BST NW contents at 550 MV·m−1; (d) Weibull breakdown strength and maximum electrical displacement; (e) Discharged energy density
Fig. 5 Dielectric energy storage properties of multilayer composites with asymmetric LTN structure[45] (a) Dielectric energy storage properties of multilayer composites with asymmetric LTN structure; (b) Weibull breakdown distribution; (c) Derived breakdown strength; (d) Discharged energy density; (e) Charge-discharge efficiency (b, d, e) E/F in volume fraction
Fig. 6 Gradient-structured BaTiO3/PVDF nanocomposites (GLN)[46] (a) Electric field distribution and growth of breakdown channels; (b) Average electric field in each layer of GLNs; (c) Electric field gap at different interfaces and average electric field in the GLN sample; (d, e) Discharged energy density and charge-discharge efficiency
Fig. 7 P(VDF-HFP)/BT nanocomposites and P(VDF-HFP)-P(VDF-HFP)/BT multilayer nanocomposites[48] (a) Schematic illustration of the preparation; (b) SEM image of P(VDF-HFP)-10% BTO; (c, d) Polarization interface ions and induced depolarization and phase field simulation of multilayer nanocomposites; (e) Breakdown strength of multilayer composites and control group; (f) Discharged energy density of different types of composites
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