Study on Isothermal Crystallization Kinetics of Mica Glass Ceramics

Abstract

Abstract: The isothermal crystallization kinetics of mica-containing glass ceramics with addition of TiO2 asnucleation agent was investigated by XRD, SEM and DTA. Two distinct crystallization exotherm peaksin the DTA curve were observed and resolved corresponding to the initial formation of MgTi₂O₅,followed by the formation of KMg₃AlSi₃O₁₀F₂, confirmed by X-ray diffeaction analysis (XRD). By usingJohnson-Mehl-Avrami equation, the activation energics for precipitation of MgTi₂O₅ and mica crystalswere enaluated and the crystallization mechanism of mica was analyzed. The results indicated that the growth of KMg₃AlSi₃O₁₀F₂isa two-dimensional process, controlled by the crystal-glass in terface reaction. The average values of activation energies are 242kJ/mol and 265kJ/mol corresponding to that of MgTi₂O₅ and mica crystalized out of the glass, respectively.

Key words: mica, glass, crystalization, kinetics, phase separation, growth mechanism

CHENG Kangguo,WAN Julin,LIANG Kaiming. Study on Isothermal Crystallization Kinetics of Mica Glass Ceramics[J]. Journal of Inorganic Materials.

References

1 Unuma H, Mlura K, Nakajima K. J. Am. Ceram. Soc., 1992, 75: 2300.

2 Grossman d G. J. Am. Ceram. Soc., 1972, 559: 446.

3 Uno T, Kasuga T, Nakajima K. 1991, 74: 3139.

4 Danlels W H, Moor R E. J. Am. Ceram. Soc., 1975, 58: 217.

5 Cai H, Kalceff M A, Lawn B R. J. Mater. Res., 1994, 9: 762.

6 Bednarik J F, Richter O W. Glass Technol., 1986, 27: 60.

7 Lawn B R, Padure N P, Cai H, et al. Science, 1994, 263, 1114.

8 Uno T, Kasnga T, Nakayama S, et al. J. Am. Ceram. Soc., 1995, 76: 539.

9 Hattori t, Yahata A, Mohri J, et ak. J. Mater. Sci. Lett., 1984, 3: 57.

10 Lihua L, Haihu Yu. J. Non-Crystal. solids, 1989, 112: 156.

11 Baik D S, No K S, Chun J S. J. Am. Ceram. Soc., 1995, 78: 1217.

12 Hockin H, Xu K, Jahanmir S. J. Am. Ceram. Soc., 1995, 78: 497.

13 Hamasaki T, Eguchi K, Koyanati Y, et al. J. Am. Ceram. Soc., 1988, 71: 1120.

14 Holand W, Naumann K, Seiferth H-G, et al. Z. Chem., 1981, 21: 108.

15 Elasen J, King G S D, Holand W, et al. J. Chem. Res. (S), 1989, 160.

16 McMillan P W. J. Mater. Sci., 1995, 39: 904.

18 Matusita K, Komatsu T, Yokota R. J. Mater. Sci., 1984, 19: 291.

19 Marotta A, Saiello S, Buri A. J. Non-Cryst. solids, 1983, 57: 473.

20 Abdel-Rahim M A, Ibrahim M M, dongol M, et al. J. Mater. Sci., 1992, 27: 4685.

21 Rysava N, spasov T, Tichy L. J. Thermal Anal., 1987, 32: 1015.

22 Branda F, Marotta A, Buri A. J. Non-Cryst. Solids, 1991, 134: 123.

23 Johnson W A, Mehl R F. Trans. Am. Inst. Min. Metall. Pet. Eng., 1939, 135: 416.

24 Avrami M. J. Chem. Phys., 1940, 8: 212.

25 Avrami M. J. Chem. Phys., 1941, 9: 177.

26 Yinnon H, Uhlmann D R. J. Non-Cryst. Solids, 1983, 54: 253.

27 Bansal N P, doremus R H. J. thermal. Anal., 1984, 29: 115.

28 Mashadevan S, Giridhar A, Singh AK. J. Non-Cryst. Solids, 1986, 88: 11.

29 Colenenero J, Barandiaran J M. J. Non-Cryst. Solids, 1978, 30: 262.

30 Shelestak L J, Charez R A, Machenaic J D. ibid., 1978, 27: 263.

31 Duhai P, Barancok D, Ondreika A. ibid., 1976, 21: 411.

32 Burton J J, Ray R P. ibid., 1971, 6: 393.

33 胡丽丽, 姜中宏. 硅酸盐学报, 1990, 4: 315.

34 Holand W, Alateva K, Vogel W, et al. Z. Chem., 1982, 22: 197.

35 包永千. 金属学基础. 北京: 冶金工业出版社, 1986.

[1]	WEI Jianwen, ZHANG Lijuan, GENG Linlin, LI Yu, LIAO Lei, WANG Dunqiu. Novel CO₂ Adsorbent Prepared with ZSM-5/MCM-48 as Support: High Adsorption Property and Its Mechanism [J]. Journal of Inorganic Materials, 2025, 40(7): 833-839.
[2]	HUANG Zipeng, JIA Wenxiao, LI Lingxia. Crystal Structure and Terahertz Dielectric Properties of (Ti_0.5W_0.5)⁵⁺ Doped MgNb₂O₆ Ceramics [J]. Journal of Inorganic Materials, 2025, 40(6): 647-655.
[3]	GUO Ziyu, ZHU Yunzhou, WANG Li, CHEN Jian, LI Hong, HUANG Zhengren. Effect of Zn²⁺ Catalyst on Microporous Structure of Porous Carbon Prepared from Phenolic Resin/Ethylene Glycol [J]. Journal of Inorganic Materials, 2025, 40(5): 466-472.
[4]	WAN Junchi, DU Lulu, ZHANG Yongshang, LI Lin, LIU Jiande, ZHANG Linsen. Structural Evolution and Electrochemical Performance of Na₄Fe_xP₄O₁₂₊_x/C Cathode Materials for Sodium-ion Batteries [J]. Journal of Inorganic Materials, 2025, 40(5): 497-503.
[5]	XUE Ke, CAI Changkun, XIE Manyi, LI Shuting, AN Shengli. Pr₁₊_xBa_1-_xFe₂O₅₊_δ Cathode Materials for Solid Oxide Fuel Cells: Preparation and Electrochemical Performance [J]. Journal of Inorganic Materials, 2025, 40(4): 363-371.
[6]	HONG Peiping, LIANG Long, WU Lian, MA Yingkang, PANG Hao. Structure Regulation of ZIF-67 and Adsorption Properties for Chlortetracycline Hydrochloride [J]. Journal of Inorganic Materials, 2025, 40(4): 388-396.
[7]	FAN Xiaobo, ZU Mei, YANG Xiangfei, SONG Ce, CHEN Chen, WANG Zi, LUO Wenhua, CHENG Haifeng. Research Progress on Proton-regulated Electrochemical Ionic Synapses [J]. Journal of Inorganic Materials, 2025, 40(3): 256-270.
[8]	SHI Tong, GAN Qiaowei, LIU Dong, ZHANG Ying, FENG Hao, LI Qiang. Boost Electrochemical Reduction of CO₂ to Formate Using a Self-supporting Bi@Cu Nanotree Electrode [J]. Journal of Inorganic Materials, 2024, 39(7): 810-818.
[9]	LI Liuyuan, HUANG Kaiming, ZHAO Xiuyi, LIU Huichao, WANG Chao. Influence of RE-Si-Al-O Glass Phase on Microstructure and CMAS Corrosion Resistance of High Entropy Rare Earth Disilicates [J]. Journal of Inorganic Materials, 2024, 39(7): 793-802.
[10]	JING Xinxin, CHEN Biqing, ZHAI Jiaxin, YUAN Meiling. Ni-Co-B-RE (Sm, Dy, Tb) Composite Electrodes: Preparation by Chemical Deposition Method and Electrocatalytic Hydrogen Evolution Performance [J]. Journal of Inorganic Materials, 2024, 39(5): 467-476.
[11]	YUE Zihao, YANG Xiaotu, ZHANG Zhengliang, DENG Ruixiang, ZHANG Tao, SONG Lixin. Effect of Pb²⁺ on the Luminescent Performance of Borosilicate Glass Coated CsPbBr₃ Perovskite Quantum Dots [J]. Journal of Inorganic Materials, 2024, 39(4): 449-456.
[12]	BAO Ke, LI Xijun. Chemical Vapor Deposition of Vanadium Dioxide for Thermochromic Smart Window Applications [J]. Journal of Inorganic Materials, 2024, 39(3): 233-258.
[13]	CHEN Zhengpeng, JIN Fangjun, LI Mingfei, DONG Jiangbo, XU Renci, XU Hanzhao, XIONG Kai, RAO Muming, CHEN Chuangting, LI Xiaowei, LING Yihan. Double Perovskite Sr₂CoFeO₅₊_δ: Preparation and Performance as Cathode Material for Intermediate-temperature Solid Oxide Fuel Cells [J]. Journal of Inorganic Materials, 2024, 39(3): 337-344.
[14]	DING Haoming, CHEN Ke, LI Mian, LI Youbing, CHAI Zhifang, HUANG Qing. Chemical Scissor-mediated Structural Editing of Inorganic Materials [J]. Journal of Inorganic Materials, 2024, 39(2): 115-128.
[15]	GUO Xiaoyang, ZHANG Xiaolin, JIANG Yan, TIAN Yuan, GENG Zhi. Ti-doped Hf(Zr)B₂-SiC Anti-ablation Coatings: Preparation and Ablation Resistance Mechanism [J]. Journal of Inorganic Materials, 2024, 39(12): 1357-1366.