Journal of Inorganic Materials ›› 2020, Vol. 35 ›› Issue (12): 1295-1306.DOI: 10.15541/jim20200134
Special Issue: 能源材料论文精选(一)：锂离子电池(2020)
ZHENG Shiyou(
),DONG Fei,PANG Yuepeng,HAN Pan,YANG Junhe
Received:2020-03-16
Revised:2020-04-22
Published:2020-12-20
Online:2020-05-10
About author:ZHENG Shiyou(1974–), male, professor. E-mail: syzheng@usst.edu.cn
Supported by:CLC Number:
ZHENG Shiyou, DONG Fei, PANG Yuepeng, HAN Pan, YANG Junhe. Research Progress on Nanostructured Metal Oxides as Anode Materials for Li-ion Battery[J]. Journal of Inorganic Materials, 2020, 35(12): 1295-1306.
Fig. 1 (a, b) SEM images of SnO2/C-NTs; (c) Cycling performance at 500 mA/g, and (d) rate capabilities of SnO2-NTs and SnO2/C-NTs[23]
Fig. 2 (a) Illustration of the synthesis principles of ultrafine SnO2 NPs immobilized in the mesopore channels of mesoporous carbon; (b) Cycle performance at 200 mA/g between 0.005 and 3 V, and (c) rate performance of electrodes based on different SnO2 content[31]
Fig. 3 (a) SEM image, and (b) cycle performance at 100 mA/g of CuO NRAs[42]
Fig. 4 (a) Schematic illustration of the synthesis of hollow CuO@NCS composites; (b) Cycle performance of CuO@NCS at 100 mA/g[46]
Fig. 5 TEM images of (a) Fe2O3-graphene particle-on-sheet composite, and (b-d) Fe2O3-graphene sheet-on-sheet composite[57]
Fig. 6 (a) Illustration for the synthetic procedure, (b) TEM image, and (c) rate capabilities of Fe3O4@N-HPCNs[63]
Fig. 7 (a) Structure diagrams of the amorphous porous CoSnO3/Au composite nanocubes; Cycle performance of the amorphous porous CoSnO3/Au composite nanocubes at (b) 0.2 and (c) 5 A/g[65]
Fig. 8 (a) Schematic illustration for the synthetic procedure, (b) TEM image, and (c) rate capabilities of spinel ZnxCo3-xO4 hollow polyhedron[79]
| Materials structure | First cyclic capacity/(mAh?g-1) (Current density/(A?g-1)) | Coulombic efficiency | Cycling performance/ (mAh?g-1) (Current density/ (A?g-1), cycle number) | Rate performance/(mAh?g-1) (Current density/(A?g-1)) | Ref. |
|---|---|---|---|---|---|
| SnO2 NPs (5~20 nm) | 1310 (0.1) | 69% | 800 (0.1, 100) | 850 (1); 800 (2) | [ |
| SnO2/C-NT (15 nm) | 483 (0.5) | 51% | 596 (0.5, 200) | 683 (1); 550 (2) | [ |
| SnO2 nanosheets (7.4 nm) | 1338 (0.1) | 55% | 763 (0.1, 300) | 460 (1); 280 (2) | [ |
| SnO2 HS (50 nm) | 736 (0.1) | 47% | 540 (0.1, 50) | 550 (1); 422 (2) | [ |
| SnO2/C (50~100 nm) | 998 (0.1) | 69% | 750 (0.1, 100) | 413 (1); 325 (2) | [ |
| C-SnO2/CNT (7 nm) | 1373 (1) | 52% | 950 (1, 100) | 1100 (1); 950 (2) | [ |
| SnO2@G-SWCNT (7 nm) | 1007 (0.1) | 53% | 785 (0.1, 100) | 510 (1); 426 (2) | [ |
| SnO2@CMK-5 (4~5 nm) | 694 (0.2) | 71% | 1039 (0.1, 100) | 770 (1) | [ |
| SnO2/C (2.8 nm) | 899 (1.4) | 44% | 560 (1.4, 100) | 700 (1.4); 538 (2.8) | [ |
| CuO spheres (400 nm) | 590 (0.45) | 66% | 400 (0.45, 50) | - | [ |
| CuO octahedra (5 nm) | 506 (0.5) | 70% | 785 (0.5, 50) | 488 (1); 370 (2) | [ |
| CuO labyrinths (20 nm) | 645 (0.1) | 66% | 330 (1, 100) | 340 (1.3); 255 (3.4) | [ |
| CuO NRAs (2~3 μm) | 751 (0.1) | 56% | 671 (0.1, 150) | 367 (1); 300 (2) | [ |
| CuO spheres (10 nm) | 552 (0.67) | 55% | 750 (0.67, 350) | 650 (1.3); 600 (3.4) | [ |
| CuO/MWCNT (10 nm) | 462 (0.07) | 69% | 650 (0.07, 100) | 590 (1.3); 590 (2) | [ |
| Cu2O/CuO/rGO (500 nm) | 375 (0.3) | 75% | 570 (0.3, 100) | 350 (1.3); 250 (2.7) | [ |
| Cu@NCSs (45 nm) | 909 (0.5) | 62% | 602 (0.5, 200) | 760 (1); 570 (2) | [ |
| Graphene/Fe2O3 (40 nm) | 1074 (0.1) | 65% | 800 (0.1, 50) | - | [ |
| Fe2O3/CA (5~50 nm) | 836 (0.1) | 55% | 635 (0.1, 100) | 652 (0.4); 546 (0.8) | [ |
| RG-O/Fe2O3 (60 nm) | 1219 (0.1) | 72% | 1027 (0.1, 50) | 970 (0.4); 760 (0.8) | [ |
| Fe3O4@PCFs (10~60 nm) | 1014 (0.2) | 72% | 920 (0.2, 80) | 677 (1); 523 (2) | [ |
| Fe3O4/PPy (200 nm) | 493 (1) | 89% | 554 (1, 100) | 500 (1); 330 (2) | [ |
| Fe3O4-CNTs (50~100 nm) | 845 (0.05) | 77% | 702 (0.05, 50) | - | [ |
| Fe3O4@N-HPCNs (6 nm) | 521 (0.1) | 54% | 1240 (0.1, 100) | 700 (1); 600 (2) | [ |
| CoMoO4 NPs (2~10 nm) | 1051 (0.2) | 72% | 1185 (0.2, 100) | 900 (1); 850 (2) | [ |
| CoSnO3/Au cube (70 nm) | 1693 (0.2) | 68% | 1615 (0.2, 100) | 1425 (1); 1289 (2) | [ |
| NiFe2O4 NPs (20 nm) | 1177 (0.1) | 79% | 1390 (0.1, 20) | 823 (1); 725 (3) | [ |
| ZnxCo3-xO4 (10 nm) | 967 (0.1) | 76% | 990 (0.1, 50) | 1020 (0.9); 988 (2.7) | [ |
| NixCo3-xO4 (40 nm) | 1133 (0.1) | 70% | 1109 (0.1, 100) | 864 (1); 728 (2) | [ |
Table 1 Structures and comprehensive electrochemical performances of different metal oxide anode materials
| Materials structure | First cyclic capacity/(mAh?g-1) (Current density/(A?g-1)) | Coulombic efficiency | Cycling performance/ (mAh?g-1) (Current density/ (A?g-1), cycle number) | Rate performance/(mAh?g-1) (Current density/(A?g-1)) | Ref. |
|---|---|---|---|---|---|
| SnO2 NPs (5~20 nm) | 1310 (0.1) | 69% | 800 (0.1, 100) | 850 (1); 800 (2) | [ |
| SnO2/C-NT (15 nm) | 483 (0.5) | 51% | 596 (0.5, 200) | 683 (1); 550 (2) | [ |
| SnO2 nanosheets (7.4 nm) | 1338 (0.1) | 55% | 763 (0.1, 300) | 460 (1); 280 (2) | [ |
| SnO2 HS (50 nm) | 736 (0.1) | 47% | 540 (0.1, 50) | 550 (1); 422 (2) | [ |
| SnO2/C (50~100 nm) | 998 (0.1) | 69% | 750 (0.1, 100) | 413 (1); 325 (2) | [ |
| C-SnO2/CNT (7 nm) | 1373 (1) | 52% | 950 (1, 100) | 1100 (1); 950 (2) | [ |
| SnO2@G-SWCNT (7 nm) | 1007 (0.1) | 53% | 785 (0.1, 100) | 510 (1); 426 (2) | [ |
| SnO2@CMK-5 (4~5 nm) | 694 (0.2) | 71% | 1039 (0.1, 100) | 770 (1) | [ |
| SnO2/C (2.8 nm) | 899 (1.4) | 44% | 560 (1.4, 100) | 700 (1.4); 538 (2.8) | [ |
| CuO spheres (400 nm) | 590 (0.45) | 66% | 400 (0.45, 50) | - | [ |
| CuO octahedra (5 nm) | 506 (0.5) | 70% | 785 (0.5, 50) | 488 (1); 370 (2) | [ |
| CuO labyrinths (20 nm) | 645 (0.1) | 66% | 330 (1, 100) | 340 (1.3); 255 (3.4) | [ |
| CuO NRAs (2~3 μm) | 751 (0.1) | 56% | 671 (0.1, 150) | 367 (1); 300 (2) | [ |
| CuO spheres (10 nm) | 552 (0.67) | 55% | 750 (0.67, 350) | 650 (1.3); 600 (3.4) | [ |
| CuO/MWCNT (10 nm) | 462 (0.07) | 69% | 650 (0.07, 100) | 590 (1.3); 590 (2) | [ |
| Cu2O/CuO/rGO (500 nm) | 375 (0.3) | 75% | 570 (0.3, 100) | 350 (1.3); 250 (2.7) | [ |
| Cu@NCSs (45 nm) | 909 (0.5) | 62% | 602 (0.5, 200) | 760 (1); 570 (2) | [ |
| Graphene/Fe2O3 (40 nm) | 1074 (0.1) | 65% | 800 (0.1, 50) | - | [ |
| Fe2O3/CA (5~50 nm) | 836 (0.1) | 55% | 635 (0.1, 100) | 652 (0.4); 546 (0.8) | [ |
| RG-O/Fe2O3 (60 nm) | 1219 (0.1) | 72% | 1027 (0.1, 50) | 970 (0.4); 760 (0.8) | [ |
| Fe3O4@PCFs (10~60 nm) | 1014 (0.2) | 72% | 920 (0.2, 80) | 677 (1); 523 (2) | [ |
| Fe3O4/PPy (200 nm) | 493 (1) | 89% | 554 (1, 100) | 500 (1); 330 (2) | [ |
| Fe3O4-CNTs (50~100 nm) | 845 (0.05) | 77% | 702 (0.05, 50) | - | [ |
| Fe3O4@N-HPCNs (6 nm) | 521 (0.1) | 54% | 1240 (0.1, 100) | 700 (1); 600 (2) | [ |
| CoMoO4 NPs (2~10 nm) | 1051 (0.2) | 72% | 1185 (0.2, 100) | 900 (1); 850 (2) | [ |
| CoSnO3/Au cube (70 nm) | 1693 (0.2) | 68% | 1615 (0.2, 100) | 1425 (1); 1289 (2) | [ |
| NiFe2O4 NPs (20 nm) | 1177 (0.1) | 79% | 1390 (0.1, 20) | 823 (1); 725 (3) | [ |
| ZnxCo3-xO4 (10 nm) | 967 (0.1) | 76% | 990 (0.1, 50) | 1020 (0.9); 988 (2.7) | [ |
| NixCo3-xO4 (40 nm) | 1133 (0.1) | 70% | 1109 (0.1, 100) | 864 (1); 728 (2) | [ |
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