Effect of ZrO2 on Crystallization and Phase Transformation in Low-temperature Processed BaO-Al2O3-SiO2 Glass-ceramics

doi:10.3724/SP.J.1077.2008.00159

Abstract

Abstract: BaO-Al₂O₃-SiO₂ (BAS) glass-ceramics with stoichiometric and off-stoichiometric celsian composition were fabricated, doped with B₂O₃ for melting and sintering. Crystallization and phase transformation characters of two groups of BAS glass-ceramics with and without ZrO₂ were investigated by differential scanning calorimetry (DSC), X-ray diffraction (XRD) and dilatometry. Results show that for both BAS glasses, the sintering temperature is lower than 850℃ and crystallization peak temperature is lower than 900℃. The crystallization characteristic of hexacelsian in each sample is bulk nucleation and three-dimensional growth because Avrami exponent is 2.8--3.9. The crystallization characteristic of monocelsian in the sample doped with ZrO₂ is surface nucleation and one-dimensional growth because Avrami exponent is 0.95, while it is bulk nucleation and three-dimensional growth because Avrami exponent is about 3.0 in the sample without nucleation agent. It reveals that crystallization peak temperature and activation energy get lower in stoichiometric BAS glass-ceramics doped with ZrO₂, while the crystallization peak temperature get higher in off-stoichiometric BAS glass-ceramics doped with ZrO₂. Stoichiometric BAS glass-ceramics doped with ZrO₂ crystallized at 850℃ for 12h is completely transformed into monocelsian. Monocelsian will not be detected in off-stoichiometric BAS doped with ZrO₂crystallized at 850℃ for 100h.

Key words: glass-ceramics, celsian, low temperature sintering, crystallization, phase transformation

CLC Number:

TG171

LU Yu-Feng,DU Yong-Guo,XIAO Jia-Yu,ZHANG Wei-Jun,WU Jian-Feng,YANG Guang,WANG Yue-Ran. Effect of ZrO₂ on Crystallization and Phase Transformation in Low-temperature Processed BaO-Al₂O₃-SiO₂ Glass-ceramics[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2008.00159.

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Effect of ZrO₂ on Crystallization and Phase Transformation in Low-temperature Processed BaO-Al₂O₃-SiO₂ Glass-ceramics

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