Journal of Inorganic Materials ›› 2020, Vol. 35 ›› Issue (8): 939-946.DOI: 10.15541/jim20190469
Special Issue: 结构陶瓷论文精选(2020); 功能材料论文精选(2020); 【虚拟专辑】分离膜,复相陶瓷(2020~2021)
• RESEARCH PAPER • Previous Articles Next Articles
ZHANG Bo1(),ZHANG Ning1,YANG Jianhua2,LAN Jiancheng2,WANG Jinqu1,2
Received:
2019-09-10
Revised:
2019-11-01
Published:
2020-08-20
Online:
2020-01-20
Supported by:
CLC Number:
ZHANG Bo,ZHANG Ning,YANG Jianhua,LAN Jiancheng,WANG Jinqu. High Performance a&b Oriented T Zeolite Membrane by a Two-stage Crystallization Synthesis[J]. Journal of Inorganic Materials, 2020, 35(8): 939-946.
Fig. 1 SEM images of α-Al2O3 support photographed from surface (a) and cross section (b), large seeds (c), small seeds (d), modified by large seeds photographed from surface (e) and cross section (f), and the small seed layer photographed from surface (g) and cross section (h)
Fig. 3 SEM images of T-type zeolite membranes after first-step crystallization prepared at different first-step crystallization temperatures (a, b) M1-1, 110 ℃; (c, d) M2-1, 120 ℃; (e, f) M3-1, 130 ℃; (g, h) M4-1, 135 ℃; (i, j) M5-1, 150 ℃
Fig. 4 SEM images of T-type zeolite membranes after two-step crystallizations prepared at different first-step crystallization temperature (a, b) M1, 110 ℃; (c, d) M2, 120 ℃; (e, f) M3, 130 ℃; (g, h) M4, 135 ℃; (i, j) M5, 150 ℃
No. | First-step crystallization | Second-step crystallization | J/ (kg·m-2·h-1) | α | ||
---|---|---|---|---|---|---|
Temp./℃ | Time/h | Temp./℃ | Time/h | |||
M1 | 110 | 4 | 110 | 6 | - | - |
M2 | 120 | 4 | 110 | 6 | 4.19 | 968 |
M3 | 130 | 4 | 110 | 6 | 3.87 | 5219 |
M4 | 135 | 4 | 110 | 6 | 3.84 | >10000 |
M5 | 150 | 4 | 110 | 6 | 3.53 | 2918 |
Table 1 Pervaporation performance of T zeolite membranes prepared under different first-step crystallization temperatures
No. | First-step crystallization | Second-step crystallization | J/ (kg·m-2·h-1) | α | ||
---|---|---|---|---|---|---|
Temp./℃ | Time/h | Temp./℃ | Time/h | |||
M1 | 110 | 4 | 110 | 6 | - | - |
M2 | 120 | 4 | 110 | 6 | 4.19 | 968 |
M3 | 130 | 4 | 110 | 6 | 3.87 | 5219 |
M4 | 135 | 4 | 110 | 6 | 3.84 | >10000 |
M5 | 150 | 4 | 110 | 6 | 3.53 | 2918 |
Fig. 6 SEM images of T-type zeolite membranes after first-step crystallization prepared with varying first-step crystallization time (a, b) M6-1, 2 h; (c, d) M7-1, 3 h; (e, f) M8-1, 5 h; (g, h) M9-1, 6 h
Fig. 7 SEM images of T-type zeolite membranes after two-step crystallizations prepared with different first-step crystallization time (a, b) M6, 2 h; (c, d) M7, 3 h; (e, f) M8, 5 h; (g, h) M9, 6 h
No. | First-step crystallization | Second-step crystallization | J/ (kg ·m-2·h-1) | α | ||
---|---|---|---|---|---|---|
Temp./℃ | Time/h | Temp./℃ | Time/h | |||
M6 | 135 | 2 | 110 | 6 | - | - |
M7 | 135 | 3 | 110 | 6 | 4.04 | 915 |
M4 | 135 | 4 | 110 | 6 | 3.84 | >10000 |
M8 | 135 | 5 | 110 | 6 | 4.2 | 2371 |
M9 | 135 | 6 | 110 | 6 | 4.97 | 697 |
Table 2 Pervaporation performance of T zeolite membranes prepared with different first-step crystallization time
No. | First-step crystallization | Second-step crystallization | J/ (kg ·m-2·h-1) | α | ||
---|---|---|---|---|---|---|
Temp./℃ | Time/h | Temp./℃ | Time/h | |||
M6 | 135 | 2 | 110 | 6 | - | - |
M7 | 135 | 3 | 110 | 6 | 4.04 | 915 |
M4 | 135 | 4 | 110 | 6 | 3.84 | >10000 |
M8 | 135 | 5 | 110 | 6 | 4.2 | 2371 |
M9 | 135 | 6 | 110 | 6 | 4.97 | 697 |
Fig. 8 SEM images of T-type zeolite membranes after two-step crystallizations prepared at different second-step crystallization temperatures (a, b) M10, 90 ℃; (c, d) M11, 100 ℃; (e, f) M12, 120 ℃; (g, h) M13, 130 ℃
No | First-step crystallization | Second-step crystallization | J/ (kg·m-2·h-1) | α | ||
---|---|---|---|---|---|---|
Temp./℃ | Time/h | Temp./℃ | Time/h | |||
M10 | 135 | 4 | 90 | 6 | - | - |
M11 | 135 | 4 | 100 | 6 | 3.94 | 2646 |
M4 | 135 | 4 | 110 | 6 | 3.84 | >10000 |
M12 | 135 | 4 | 120 | 6 | 3.97 | 5867 |
M13 | 135 | 4 | 130 | 6 | 3.41 | 5594 |
Table 3 Pervaporation performance of T zeolite membranes prepared under different second-step crystallization temperatures
No | First-step crystallization | Second-step crystallization | J/ (kg·m-2·h-1) | α | ||
---|---|---|---|---|---|---|
Temp./℃ | Time/h | Temp./℃ | Time/h | |||
M10 | 135 | 4 | 90 | 6 | - | - |
M11 | 135 | 4 | 100 | 6 | 3.94 | 2646 |
M4 | 135 | 4 | 110 | 6 | 3.84 | >10000 |
M12 | 135 | 4 | 120 | 6 | 3.97 | 5867 |
M13 | 135 | 4 | 130 | 6 | 3.41 | 5594 |
Support | Temp./ ℃ | Time/ h | J/ (kg·m-2·h-1) | α | Ref. |
---|---|---|---|---|---|
α-Al2O3 disc | 120 | 24 | 2.24 | 10000 | [29] |
α-Al2O3 tube | 100 | 30 | 2.52 | 10000 | [21] |
α-Al2O3 tube | 120 | 16 | 2.96 | 6400 | [23] |
α-Al2O3 tube | 100+140a | 8+1a | 2.15 | 10000 | [19] |
α-Al2O3 tube | 150+120b | 4+8b | 2.04 | 2874 | [30] |
α-Al2O3 tube | 135+110c | 4+6c | 3.84 | >10000 | This work |
Table 4 Pervaporation performance of zeolite T membranes for 90wt% isopropanol/water mixture at 75 ℃
Support | Temp./ ℃ | Time/ h | J/ (kg·m-2·h-1) | α | Ref. |
---|---|---|---|---|---|
α-Al2O3 disc | 120 | 24 | 2.24 | 10000 | [29] |
α-Al2O3 tube | 100 | 30 | 2.52 | 10000 | [21] |
α-Al2O3 tube | 120 | 16 | 2.96 | 6400 | [23] |
α-Al2O3 tube | 100+140a | 8+1a | 2.15 | 10000 | [19] |
α-Al2O3 tube | 150+120b | 4+8b | 2.04 | 2874 | [30] |
α-Al2O3 tube | 135+110c | 4+6c | 3.84 | >10000 | This work |
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