Journal of Inorganic Materials

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Comparison of LSGM and LSGMC8.5 Synthesized by Advanced Pechini Method

XU Guo-Yue, CAO Min, LIU Bo, CHENG Xin, ZHOU Jian   

  1. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
  • Received:2005-06-24 Revised:2005-09-05 Published:2006-05-20 Online:2006-05-20

Abstract: The perovskite-type LSGM(La0.9Sr0.1Ga0.85Mg0.15O2.875) and Co-doped
LSGMC8.5 (La0.9Sr0.1(Ga0.9Co0.1)Mg0.15O3-δ) were synthesized by the advanced Pechini method. Their properties were compared by the analysis of XRD, DTA-TG, impedance spectra, conductivity and density. It showed that Co doping decreased the forming temperature of cubic perovskite structure from 1400℃ to 1300℃, and increased the fractional density from 95% to 99%. The conductivity of the LSGMC8.5 sintered at 1400℃ for 6h is 5.38×10-2S/cm. So the Co-doped LSGMC8.5 is more suitable for IT-SOFC.

Key words: advanced pechini method, fuel cell, Co-doped, LSGM

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