Nd3+/Yb3+共掺La2O3-TiO2-ZrO2微晶玻璃的制备及上转换发光研究

doi:10.3724/SP.J.1077.2013.13196

无机材料学报 ›› 2013, Vol. 28 ›› Issue (8): 896-900.DOI: 10.3724/SP.J.1077.2013.13196 CSTR: 32189.14.SP.J.1077.2013.13196

Nd³⁺/Yb³⁺共掺La₂O₃-TiO₂-ZrO₂微晶玻璃的制备及上转换发光研究

张明辉^1,2，余建定¹，潘秀红¹，程愉悻^1,2，刘岩¹

(1. 中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，上海 200050；2. 中国科学院大学，北京 100039)

收稿日期:2013-04-08 修回日期:2013-04-28 出版日期:2013-08-20 网络出版日期:2013-07-15
作者简介:张明辉. E-mail: mhzh1987@student.sic.ac.cn
基金资助:
National Natural Science Foundation of China(51072209); Program of Scientific Equipment Development of Chinese Academy of Sciences(YZ201142); Innovation Fund of Shanghai Institute of Ceramics, CAS(Y17ZC11601G)

Preparation and Upconversion Luminescence of Nd³⁺/Yb³⁺ Co-doped La₂O₃-TiO₂-ZrO₂ Glass-ceramics

ZHANG Ming-Hui^{1, 2}, YU Jian-Ding¹, PAN Xiu-Hong¹, CHENG Yu-Xing^{1, 2}, LIU Yan¹

(1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; 2. University of Chinese Academy of Sciences, Beijing 100039, China)

Received:2013-04-08 Revised:2013-04-28 Published:2013-08-20 Online:2013-07-15
About author:ZHANG Ming-Hui (1987-), male, candidate of PhD. E-mail: mhzh1987@student.sic.ac.cn
Supported by:
National Natural Science Foundation of China(51072209); Program of Scientific Equipment Development of Chinese Academy of Sciences(YZ201142); Innovation Fund of Shanghai Institute of Ceramics, CAS(Y17ZC11601G)

摘要/Abstract

摘要： 利用气悬浮方法制备了Nd³⁺/Yb³⁺共掺La₂O₃-TiO₂-ZrO₂前驱体玻璃, 通过热处理获得了微晶玻璃。通过DTA对前驱体玻璃的热稳定性进行了研究。利用光致发光谱, TEM和EDS对微晶玻璃进行了表征分析, 并研究了热处理对上转换发光的影响。结果表明: 玻璃转变温度和析晶起始温度分别为799℃和880℃. 在980 nm激光激发下, 样品发射出中心位于497, 523, 545, 603和657 nm处的五条发光带。热处理后样品上转换发光强度提高, 经过880℃保温50 min热处理的微晶玻璃显示了最强的上转换发光, 在545 nm处的发光强度是前驱体玻璃的11倍, 这是由于在微晶玻璃基质中存在致密柱状晶和Nd³⁺离子在晶体中富集造成的。

关键词: 微晶玻璃, 气悬浮方法, 热处理, 上转换发光

Abstract: Nd³⁺/Yb³⁺ co-doped La₂O₃-TiO₂-ZrO₂ glass-ceramic samples were prepared by heat treatment of precursor glasses fabricated via aerodynamic levitation method. The thermal stability of the precursor glass was studied by DTA. The glass-ceramic samples were characterized by photoluminescence spectra, TEM and EDS. The effects of heat treatment on the upconversion luminescence were studied. The DTA curve shows that the glass transition temperature and the onset temperature of crystallization are 799℃ and 880℃, respectively. Five emission bands centered at 497, 523, 545, 603 and 657 nm are obtained at the excitation of 980 nm laser. The emission intensity can be increased by heat treatment. The glass-ceramic samples heat-treated at 880℃ for 50 min perform the strongest upconversion luminescence with intensity (at 545 nm) as 11 times high as that of the precursor glasses, which can be ascribed to the dense columnar crystals embedded in the glass matrix and the enrichment of Nd³⁺ ions in the crystals.

Key words: glass-ceramics, aerodynamic levitation method, heat treatment, upconversion luminescence

中图分类号:

TQ171

张明辉，余建定，潘秀红，程愉悻，刘岩. Nd³⁺/Yb³⁺共掺La₂O₃-TiO₂-ZrO₂微晶玻璃的制备及上转换发光研究[J]. 无机材料学报, 2013, 28(8): 896-900.

ZHANG Ming-Hui, YU Jian-Ding, PAN Xiu-Hong, CHENG Yu-Xing, LIU Yan. Preparation and Upconversion Luminescence of Nd³⁺/Yb³⁺ Co-doped La₂O₃-TiO₂-ZrO₂ Glass-ceramics[J]. Journal of Inorganic Materials, 2013, 28(8): 896-900.

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Nd³⁺/Yb³⁺共掺La₂O₃-TiO₂-ZrO₂微晶玻璃的制备及上转换发光研究

Preparation and Upconversion Luminescence of Nd³⁺/Yb³⁺ Co-doped La₂O₃-TiO₂-ZrO₂ Glass-ceramics

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