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无机材料学报

无机材料学报

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一种新型改性PbTiO3压电陶瓷材料研究

周桃生; 何云斌; 尚勋忠; 张源伟; 邝安祥   

  1. 湖北大学压电陶瓷技术研究所; 武汉430062
  • 收稿日期:1997-07-16 修回日期:1997-10-07 出版日期:1998-08-10 网络出版日期:1998-08-10

A New Modified PbTiO3 Piezoelectric Ceramic Material

ZHOU Tao-Sheng; HE Yun-Bin; SHANG Xun-Zhong; ZHANG Yuan-Wei; KUANG An-Xiang   

  1. Institute of Piezoelectric Ceramic Technology Hubei University Wuhan 430062 China
  • Received:1997-07-16 Revised:1997-10-07 Published:1998-08-10 Online:1998-08-10

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摘要： 研制了一种新型的添加Pb（Mn1／3Sb2／3）O3、碱土金属CaCO3、Bi2O3、NiO的改性钛酸铅压电陶瓷材料．该材料具有高压电活性、大压电各向异性、低介电常数及小的机械品质因素．实验确定其典型配方为Pb0．80Ca0．20［（Mn1／3Sb2／3）0．05Ti0．95］O3＋0．5wt％NiO＋1wt％Bi2O3；在优化后的制备工艺条件下，其主要性能参数为：εT33/ε0＝160, d33＝70×10-12C·N-1；Kt＝60．0；Hp≈0，Qm＝43，Nt＝2004Hz·m．

关键词: 钛酸铅压电陶瓷, 锑锰B位取代, 改性, 高Kt, 大各向异性

Abstract: A new modified PbTiO3 piezoelectric ceramic material added with Pb(Mn1/3Sn2/3)O3 , CaCO3,Bi2O3, NiO was prepared. The modified material has high piezeoelectric activities, large piezoelectric anisotropy as well as low dielectric constant, and low mechanical quality factors. The typical composition of this material obtained from experiments is Pb0.80Ca0.20[(Mn1/3Sb2/3)0.05Ti0.95]O3+0.5wt% NiO+1wt%Bi2O3. Under the optimized preparation technique, its main performance are as follows. εT33/ε0＝160, d33=70×10-12C·N-1；Kt＝60．0；Hp≈0，Qm＝43，Nt＝2004Hz·m．

Key words: PbTiO3 piezoelectric ceramic, B-site substitution of [Mn1/3Sb2/3]4+, modification, high Kt, large anisotropy

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