氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理

doi:10.15541/jim20250019

无机材料学报

• •

氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理

范雨竹¹, 王媛¹, 王林燕¹, 向美玲¹, 鄢雨婷¹, 黎本慧¹, 李敏¹, 文志东^2,3, 王海超^2,4, 陈永福⁵, 邱会东¹, 赵波⁶, 周成裕¹

1.重庆科技大学化学化工学院, 重庆 401331;
2.烟台新旧动能转换研究院, 烟台 264004;
3.哈尔滨工程大学烟台研究院, 烟台 264000;
4.鲁东大学资源与环境工程学院, 烟台 264025;
5.中国兵器装备集团西南技术工程研究所, 重庆 400039;
6.中华人民共和国上海海关, 上海 200002

收稿日期:2025-01-14 修回日期:2025-04-14
通讯作者: 范雨竹, 副教授. E-mail: fanyuzhu1010@foxmail.com; 周成裕, 教授. E-mail: zhoucy0130@cqust.edu.cn
作者简介:范雨竹(1990-), 女, 副教授. E-mail: fanyuzhu1010@foxmail.com
基金资助:
重庆市教育委员会科学技术研究项目(KJQN202301545); 重庆市自然科学基金面上项目(CSTB2024NSCQ-MSX0796); 重庆市教委科学技术研究重点项目(KJZD-K202201504); 重庆科技大学大学生科技创新训练计划项目(S2024115001015, 202411551009); 重庆科技大学研究生创新计划项目(YKJCX2420501); 烟台市科技创新发展计划(2023JCYJ081); 烟台市精细化工废水处理与资源化重点实验室开放课题(JXHGSYS-2023-01)

Progress of Graphene Oxide-based Adsorbents for Pb(II) Removing in Water: Synthesis, Performance and Mechanism

FAN Yuzhu¹, WANG Yuan¹, WANG Linyan¹, XIANG Meiling¹, YAN Yuting¹, LI Benhui¹, LI Min¹, WEN Zhidong^2,3, WANG Haichao^2,4, CHEN Yongfu⁵, QIU Huidong¹, ZHAO Bo⁶, ZHOU Chengyu¹

1. School of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, China;
2. Yantai Institute of New and Old Kinetic Energy Conversion, Yantai 264004, China;
3. Yantai Research Institute of Harbin Engineering University, Yantai 264000, China;
4. School of Resources and Environmental Engineering, Ludong University, Yantai 264025, China;
5. Southwest Technology and Engineering Research Institute of China Ordnance Equipment Group Corporation, Chongqing 400039, China;
6. Shanghai Customs District P.R. China, Shanghai 200002, China

Received:2025-01-14 Revised:2025-04-14
Contact: FAN Yuzhu, associate professor. E-mail: fanyuzhu1010@foxmail.com; ZHOU Chengyu, professor. E-mail: zhoucy0130@cqust.edu.cn
About author:FAN Yuzhu (1990–), female, associate professor. E-mail: fanyuzhu1010@foxmail.com
Supported by:
Science and Technology Research Program of Chongqing Municipal Education Commission (KJQN202301545); General Program of Natural Science Foundation of Chongqing (CSTB2024NSCQ-MSX0796); Scientific and Technological Key Research Program of Chongqing Municipal Education Commission (KJZD-K202201504); College Students' Science and Technology Innovation Training Program of Chongqing University of Science and Technology (S2024115001015, 202411551009); Postgraduate Innovation Program of Chongqing University of Science and Technology (YKJCX2420501); Yantai Science and Technology Innovation Development Plan (2023JCYJ081); Open Topic of Yantai Key Laboratory of Fine Chemical Wastewater Treatment and Resource Utilization (JXHGSYS-2023-01)

摘要/Abstract

摘要： 水体Pb(II)污染严重危害生态环境与人类健康,吸附法是一种简单环保的Pb(II)处理技术。氧化石墨烯（GO）被认为是一种潜在的理想吸附材料,但其表面官能团种类有限、吸附选择性差、吸附后难分离等缺点制约了其实际应用。发展各种改性策略提高GO吸附性能,已成为目前研究热点。本文针对如何提高GO对水中Pb(II)的吸附效率,重点总结了N/S官能团改性、形貌改性、磁化改性三类改性策略;综述了GO基吸附剂的吸附性能,涵盖吸附容量、吸附选择性、再生性以及其他性能;详细讨论了Pb(II)吸附的四种机理,包括物理吸附、静电吸引、离子交换合表面络合;最后对GO基吸附剂去除Pb(II)进行了展望,以期为GO改性材料在Pb(II)处理方面的研究和应用提供参考依据。

关键词: 氧化石墨烯, 改性, 吸附, 铅离子, 机理, 综述

Abstract: Pb(II) pollution in water constitutes a serious form of heavy metal pollution that endangers both the ecological environment and human health. As an effective sewage treatment technology, adsorption has been considered an economic and common method because of low cost, environmental friendliness and simple operation. Graphene oxide (GO), an innovative material with superior properties, has garnered extensive research as an ideal adsorbent. Nonetheless, GO faces many challenges in practical applications due to limited surface functional groups, suboptimal adsorption selectivity, and poor regenerative properties. Current research focuses on developing various modification strategies to enhance the adsorption performance of GO. In this paper, the modification methods of GO and adsorption mechanisms are reviewed. Firstly, three strategies for improving Pb(II) adsorption properties of GO-based materials are discussed, including N/S functionalization, morphological alteration and magnetization. The adsorption properties of GO-based adsorbents are evaluated, covering adsorption capacity, adsorption selectivity, regeneration, and other performance metrics. Subsequently, the adsorption mechanisms of Pb(Ⅱ) by GO-based adsorbents such as physical adsorption, electrostatic attraction, ion exchange, and surface complexation are summarized, which are essential for the development of highly efficient GO-modified materials. Finally, the future development of adsorption of GO-based materials for Pb(II) is prospected. This review provides novel insights for rational design of emerging GO-based adsorbents and serve as a reference foundation for research and application of GO-modified materials in Pb(II) treatment.

Key words: graphene oxide, modification, adsorption, Pb(Ⅱ), mechanism, review

中图分类号:

TB383

范雨竹, 王媛, 王林燕, 向美玲, 鄢雨婷, 黎本慧, 李敏, 文志东, 王海超, 陈永福, 邱会东, 赵波, 周成裕. 氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理[J]. 无机材料学报, DOI: 10.15541/jim20250019.

FAN Yuzhu, WANG Yuan, WANG Linyan, XIANG Meiling, YAN Yuting, LI Benhui, LI Min, WEN Zhidong, WANG Haichao, CHEN Yongfu, QIU Huidong, ZHAO Bo, ZHOU Chengyu. Progress of Graphene Oxide-based Adsorbents for Pb(II) Removing in Water: Synthesis, Performance and Mechanism[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20250019.

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氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理

Progress of Graphene Oxide-based Adsorbents for Pb(II) Removing in Water: Synthesis, Performance and Mechanism

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