氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理

doi:10.15541/jim20250019

无机材料学报

• •

氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理

范雨竹¹, 王媛¹, 王林燕¹, 向美玲¹, 鄢雨婷¹, 黎本慧¹, 李敏¹, 文志东^2,3, 王海超^2,4, 陈永福⁵, 邱会东¹, 赵波⁶, 周成裕¹

1.重庆科技大学化学化工学院, 重庆 401331;
2.烟台新旧动能转换研究院, 烟台 264004;
3.哈尔滨工程大学烟台研究院, 烟台 264000;
4.鲁东大学资源与环境工程学院, 烟台 264025;
5.中国兵器装备集团西南技术工程研究所, 重庆 400039;
6.中华人民共和国上海海关, 上海 200002

收稿日期:2025-01-14 修回日期:2025-04-14
通讯作者: 范雨竹, 副教授. E-mail: fanyuzhu1010@foxmail.com; 周成裕, 教授. E-mail: zhoucy0130@cqust.edu.cn
作者简介:范雨竹(1990-), 女, 副教授. E-mail: fanyuzhu1010@foxmail.com
基金资助:
重庆市教育委员会科学技术研究项目(KJQN202301545); 重庆市自然科学基金面上项目(CSTB2024NSCQ-MSX0796); 重庆市教委科学技术研究重点项目(KJZD-K202201504); 重庆科技大学大学生科技创新训练计划项目(S2024115001015, 202411551009); 重庆科技大学研究生创新计划项目(YKJCX2420501); 烟台市科技创新发展计划(2023JCYJ081); 烟台市精细化工废水处理与资源化重点实验室开放课题(JXHGSYS-2023-01)

Progress of Graphene Oxide-based Adsorbents for Pb(II) Removing in Water: Synthesis, Performance and Mechanism

FAN Yuzhu¹, WANG Yuan¹, WANG Linyan¹, XIANG Meiling¹, YAN Yuting¹, LI Benhui¹, LI Min¹, WEN Zhidong^2,3, WANG Haichao^2,4, CHEN Yongfu⁵, QIU Huidong¹, ZHAO Bo⁶, ZHOU Chengyu¹

1. School of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, China;
2. Yantai Institute of New and Old Kinetic Energy Conversion, Yantai 264004, China;
3. Yantai Research Institute of Harbin Engineering University, Yantai 264000, China;
4. School of Resources and Environmental Engineering, Ludong University, Yantai 264025, China;
5. Southwest Technology and Engineering Research Institute of China Ordnance Equipment Group Corporation, Chongqing 400039, China;
6. Shanghai Customs District P.R. China, Shanghai 200002, China

Received:2025-01-14 Revised:2025-04-14
Contact: FAN Yuzhu, associate professor. E-mail: fanyuzhu1010@foxmail.com; ZHOU Chengyu, professor. E-mail: zhoucy0130@cqust.edu.cn
About author:FAN Yuzhu (1990–), female, associate professor. E-mail: fanyuzhu1010@foxmail.com
Supported by:
Science and Technology Research Program of Chongqing Municipal Education Commission (KJQN202301545); General Program of Natural Science Foundation of Chongqing (CSTB2024NSCQ-MSX0796); Scientific and Technological Key Research Program of Chongqing Municipal Education Commission (KJZD-K202201504); College Students' Science and Technology Innovation Training Program of Chongqing University of Science and Technology (S2024115001015, 202411551009); Postgraduate Innovation Program of Chongqing University of Science and Technology (YKJCX2420501); Yantai Science and Technology Innovation Development Plan (2023JCYJ081); Open Topic of Yantai Key Laboratory of Fine Chemical Wastewater Treatment and Resource Utilization (JXHGSYS-2023-01)

摘要/Abstract

摘要： 水体Pb(II)污染严重危害生态环境与人类健康,吸附法是一种简单环保的Pb(II)处理技术。氧化石墨烯（GO）被认为是一种潜在的理想吸附材料,但其表面官能团种类有限、吸附选择性差、吸附后难分离等缺点制约了其实际应用。发展各种改性策略提高GO吸附性能,已成为目前研究热点。本文针对如何提高GO对水中Pb(II)的吸附效率,重点总结了N/S官能团改性、形貌改性、磁化改性三类改性策略;综述了GO基吸附剂的吸附性能,涵盖吸附容量、吸附选择性、再生性以及其他性能;详细讨论了Pb(II)吸附的四种机理,包括物理吸附、静电吸引、离子交换合表面络合;最后对GO基吸附剂去除Pb(II)进行了展望,以期为GO改性材料在Pb(II)处理方面的研究和应用提供参考依据。

关键词: 氧化石墨烯, 改性, 吸附, 铅离子, 机理, 综述

Abstract: Pb(II) pollution in water constitutes a serious form of heavy metal pollution that endangers both the ecological environment and human health. As an effective sewage treatment technology, adsorption has been considered an economic and common method because of low cost, environmental friendliness and simple operation. Graphene oxide (GO), an innovative material with superior properties, has garnered extensive research as an ideal adsorbent. Nonetheless, GO faces many challenges in practical applications due to limited surface functional groups, suboptimal adsorption selectivity, and poor regenerative properties. Current research focuses on developing various modification strategies to enhance the adsorption performance of GO. In this paper, the modification methods of GO and adsorption mechanisms are reviewed. Firstly, three strategies for improving Pb(II) adsorption properties of GO-based materials are discussed, including N/S functionalization, morphological alteration and magnetization. The adsorption properties of GO-based adsorbents are evaluated, covering adsorption capacity, adsorption selectivity, regeneration, and other performance metrics. Subsequently, the adsorption mechanisms of Pb(Ⅱ) by GO-based adsorbents such as physical adsorption, electrostatic attraction, ion exchange, and surface complexation are summarized, which are essential for the development of highly efficient GO-modified materials. Finally, the future development of adsorption of GO-based materials for Pb(II) is prospected. This review provides novel insights for rational design of emerging GO-based adsorbents and serve as a reference foundation for research and application of GO-modified materials in Pb(II) treatment.

Key words: graphene oxide, modification, adsorption, Pb(Ⅱ), mechanism, review

中图分类号:

TB383

范雨竹, 王媛, 王林燕, 向美玲, 鄢雨婷, 黎本慧, 李敏, 文志东, 王海超, 陈永福, 邱会东, 赵波, 周成裕. 氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理[J]. 无机材料学报, DOI: 10.15541/jim20250019.

FAN Yuzhu, WANG Yuan, WANG Linyan, XIANG Meiling, YAN Yuting, LI Benhui, LI Min, WEN Zhidong, WANG Haichao, CHEN Yongfu, QIU Huidong, ZHAO Bo, ZHOU Chengyu. Progress of Graphene Oxide-based Adsorbents for Pb(II) Removing in Water: Synthesis, Performance and Mechanism[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20250019.

参考文献

[1] ABDELWAHEB M, JEBALI K, DHAOUADI H,et al. Adsorption of nitrate, phosphate, nickel and lead on soils: risk of groundwater contamination. Ecotoxicology and Environmental Safety, 2019, 179: 182.
[2] YAO X, STEVEN XU X, YANG Y N,et al. Stratification of population in NHANES 2009-2014 based on exposure pattern of lead, cadmium, mercury, and arsenic and their association with cardiovascular, renal and respiratory outcomes. Environment International, 2021, 149: 106410.
[3] SALL M L, DIAW A K D, GNINGUE-SALL D,et al. Toxic heavy metals: impact on the environment and human health, and treatment with conducting organic polymers, a review. Environmental Science and Pollution Research International, 2020, 27(24): 29927.
[4] JOSHI N C, GURURANI P.Advances of graphene oxide based nanocomposite materials in the treatment of wastewater containing heavy metal ions and dyes.Current Research in Green and Sustainable Chemistry, 2022, 5: 100306.
[5] CHOUDHARI U, RAMGIR N, VAGHELA C,et al. Sensitive and selective electrochemical lead sensor: a synergistic effect of nanobiocomposite. Microchemical Journal, 2024, 202: 110763.
[6] KAUR S, ROY A.Bioremediation of heavy metals from wastewater using nanomaterials.Environment, Development and Sustainability, 2021, 23(7): 9617.
[7] 张海虎, 呙润华, 刘喜杰. 改性氧化石墨烯的制备及应用研究进展. 化工新型材料, 2022, 50(12): 12.
[8] 张笑娟, 魏琦峰, 任秀莲. 氧化石墨烯的制备方法、结构、性质及应用研究进展. 应用化工, 2022, 51(7): 2106.
[9] GAIDUKEVIC J, AUKSTAKOJYTE R, NAVICKAS T,et al. A novel approach to prepare highly oxidized graphene oxide: structural and electrochemical investigations. Applied Surface Science, 2021, 567: 150883.
[10] AZIZ K H H, MUSTAFA F S, OMER K M,et al. Heavy metal pollution in the aquatic environment: efficient and low-cost removal approaches to eliminate their toxicity: a review. RSC Advances, 2023, 13(26): 17595.
[11] 陈玥琪, 张震斌, 单凤君. 氧化石墨烯及其复合材料对重金属离子的吸附研究进展. 辽宁工业大学学报: 自然科学版, 2022, 42(5): 325.
[12] ZHANG L, ZHANG Z, WANG L,et al. Mechanism and application of sulfhydryl-modified chitosan derivative for decontamination of Pb(II) and Cd(II) in water bodies. International Journal of Biological Macromolecules, 2025, 306: 141535.
[13] ARYEE A A, MPATANI F M, HAN R P,et al. A review on adsorbents for the remediation of wastewater: antibacterial and adsorption study. Journal of Environmental Chemical Engineering, 2021, 9(6): 106907.
[14] YAN H, HU W H, CHENG S,et al. Microwave-assisted preparation of manganese dioxide modified activated carbon for adsorption of lead ions. Water Science and Technology, 2020, 82(1): 170.
[15] NEOLAKA Y A B, RIWU A A P, AIGBE U O,et al. Potential of activated carbon from various sources as a low-cost adsorbent to remove heavy metals and synthetic dyes. Results in Chemistry, 2023, 5: 100711.
[16] BESSA R A, FRANÇA A M M, PEREIRA A L S,et al. Hierarchical zeolite based on multiporous zeolite A and bacterial cellulose: an efficient adsorbent of Pb²+. Microporous and Mesoporous Materials, 2021, 312: 110752.
[17] NEOLAKA Y A B, SUPRIYANTO G, KUSUMA H S. Adsorption performance of Cr(VI)-imprinted poly(4-VP-co-MMA) supported on activated Indonesia (Ende-Flores) natural zeolite structure for Cr(VI) removal from aqueous solution.Journal of Environmental Chemical Engineering, 2018, 6(2): 3436.
[18] WANG S F, LI X, LIU Y G,et al. Nitrogen-containing amino compounds functionalized graphene oxide: synthesis, characterization and application for the removal of pollutants from wastewater: a review. Journal of Hazardous Materials, 2018, 342: 177.
[19] YANG X D, WAN Y S, ZHENG Y L,et al. Surface functional groups of carbon-based adsorbents and their roles in the removal of heavy metals from aqueous solutions: a critical review. Chemical Engineering Journal, 2019, 366: 608.
[20] TIWARI S K, SAHOO S, WANG N,et al. Graphene research and their outputs: status and prospect. Journal of Science: Advanced Materials and Devices, 2020, 5(1): 10.
[21] JIANG X, RUAN G, HUANG Y,et al. Assembly and application advancement of organic-functionalized graphene-based materials: a review. Journal of separation science, 2020, 43(8): 1544.
[22] FEIST B, PILCH M, NYCZ J.Graphene oxide chemically modified with 5-amino-1, 10-phenanthroline as sorbent for separation and preconcentration of trace amount of lead(II).Microchimica Acta, 2019, 186(2): 91.
[23] ARCHANA S, RADHIKA D, JAYANNA B K,et al. Functionalization and partial grafting of the reduced graphene oxide with p-phenylenediamine: an adsorption and photodegradation studies. FlatChem, 2021, 26: 100210.
[24] ZHENG B, CHU X X, LI H,et al. Layered graphene oxide membranes functioned by amino acids for efficient separation of metal ions. Applied Surface Science, 2021, 546: 149145.
[25] HUANG R J, SHAO N, HOU L,et al. Fabrication of an efficient surface ion-imprinted polymer based on sandwich-like graphene oxide composite materials for fast and selective removal of lead ions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 566: 218.
[26] SAHU P S, VERMA R P, DABHADE A H,et al. A novel, efficient and economical alternative for the removal of toxic organic, inorganic and pathogenic water pollutants using GO-modified PU granular composite. Environmental Pollution, 2023, 328: 121201.
[27] ZARENEZHAD M, ZAREI M, EBRATKHAHAN M,et al. Synthesis and study of functionalized magnetic graphene oxide for Pb²+ removal from wastewater. Environmental Technology & Innovation, 2021, 22: 101384.
[28] PIRVEYSIAN M, GHIACI M.Synthesis and characterization of sulfur functionalized graphene oxide nanosheets as efficient sorbent for removal of Pb²+, Cd²+, Ni²+ and Zn²+ ions from aqueous solution: a combined thermodynamic and kinetic studies.Applied Surface Science, 2018, 428: 98.
[29] LIAN Q Y, AHMAD Z U, GANG D D,et al. The effects of carbon disulfide driven functionalization on graphene oxide for enhanced Pb(II) adsorption: investigation of adsorption mechanism. Chemosphere, 2020, 248: 126078.
[30] YAP P L, AUYOONG Y L, HASSAN K,et al. Multithiol functionalized graphene bio-sponge via photoinitiated thiol-ene click chemistry for efficient heavy metal ions adsorption. Chemical Engineering Journal, 2020, 395: 124965.
[31] REZANIA S, MOJIRI A, PARK J,et al. Removal of lead ions from wastewater using lanthanum sulfide nanoparticle decorated over magnetic graphene oxide. Environmental Research, 2022, 204: 111959.
[32] DIAGBOYA P N, MMAKO H K, DIKIO E D,et al. Synthesis of amine and thiol dual functionalized graphene oxide for aqueous sequestration of lead. Journal of Environmental Chemical Engineering, 2019, 7(6): 103461.
[33] HUANG H Y, WANG Y, ZHANG Y B, et al. Amino-functionalized graphene oxide for Cr(VI), Cu(II), Pb(II) and Cd(II) removal from industrial wastewater. Open Chemistry, 202018(1): 97.
[34] BAKRY A M, AMRI N, ADLY M S,et al. Remediation of water containing lead(II) using (3-iminodiacetic acid) propyltriethoxysilane graphene oxide. Scientific Reports, 2024, 14: 18848.
[35] ZOU L, SHANG W, MIN T T,et al. Efficient removal of Pb(II) and Cd(II) ions from wastewater using amidoxime functionalized graphene oxide. The Canadian Journal of Chemical Engineering, 2025, 103(2): 799.
[36] LOH N Y L, TEE W T, HANSON S,et al. Enhanced removal of lead and zinc by a 3D aluminium sulphate-functionalised graphene aerogel as an effective adsorption system. Chemosphere, 2024, 362: 142537.
[37] XING C J, XIA A Q, YU L,et al. Enhanced removal of Pb(II) from aqueous solution using EDTA-modified magnetic graphene oxide. CLEAN - Soil, Air, Water, 2021, 49(4): 2000272.
[38] MANZOOR Q, FARRUKH M A, SAJID A.Optimization of lead (II) and chromium (VI) adsorption using graphene oxide/ZnO/chitosan nanocomposite by response surface methodology.Applied Surface Science, 2024, 655: 159544.
[39] KONG L, LI Z C, HUANG X Q,et al. Efficient removal of Pb(II) from water using magnetic Fe3S4/reduced graphene oxide composites. Journal of Materials Chemistry A, 2017, 5(36): 19333.
[40] ZHANG H N, LIU X M, TIAN L H,et al. Preparation of functionalized graphene oxide composite spheres and removal of Cu²+ and Pb²+ from wastewater. Water, Air, & Soil Pollution, 2022, 233(12): 512.
[41] TENG J, ZENG X, XU X,et al. Assembly of a novel porous 3D graphene oxide-starch architecture by a facile hydrothermal method and its adsorption properties toward metal ions. Materials Letters, 2018, 214: 31.
[42] LI Z S, LI B L, DU L J,et al. Three-dimensional oxygen-doped porous graphene: sodium chloride-template preparation, structural characterization and supercapacitor performances. Chinese Journal of Chemical Engineering, 2021, 40: 304.
[43] LIU Z J, ZHANG W H, YIN M J,et al. Tailored GO nanosheets for porous framework to high CO₂ adsorption. Chemical Engineering Journal, 2024, 498: 155127.
[44] OLEJNICZAK A, RYMZHANOV R A.From nanohole to ultralong straight nanochannel fabrication in graphene oxide with swift heavy ions.Nature Communications, 2023, 14: 889.
[45] LI B L, LI Z S, PANG Q,et al. Synthesis and characterization of activated 3D graphene via catalytic growth and chemical activation for electrochemical energy storage in supercapacitors. Electrochimica Acta, 2019, 324: 134878.
[46] WU T R, MOGHADAM F, LI K.High-performance porous graphene oxide hollow fiber membranes with tailored pore sizes for water purification.Journal of Membrane Science, 2022, 645: 120216.
[47] KONG F X, YOU L, CAO J M,et al. Effect of etching and reduction time on the structure, performance, and stability of GO-based membrane for water purification. Journal of Environmental Chemical Engineering, 2023, 11(1): 109215.
[48] LI Y, ZHAO W, WEYLAND M,et al. Thermally reduced nanoporous graphene oxide membrane for desalination. Environmental Science & Technology, 2019, 53(14): 8314.
[49] CHENG J H, GAO M L, YANG L,et al. Coral-inspired “nanotentaclization” porous composite gel for efficient removal of lead(II) from aqueous solution. Materials & Design, 2020, 195: 109072.
[50] MOHARRAM M A K, TOHAMI K, EL HOTABY W M,et al. Graphene oxide porous crosslinked cellulose nanocomposite microspheres for lead removal: kinetic study. Reactive and Functional Polymers, 2016, 101: 9.
[51] ZHANG X X, XU J, ZHANG Z J,et al. Pb(II) adsorption properties of a three-dimensional porous bacterial cellulose/graphene oxide composite hydrogel subjected to ultrasonic treatment. Materials, 2024, 17(13): 3053.
[52] PACHIYAPPAN J, GNANASUNDARAM N.Using graphene oxide-silica [GO-Si] nano composite adsorbent, removal of heavy metal ions (lead and mercury) from industrial wastewater and analysing its performance.Rasayan Journal of Chemistry, 2020, 13(3): 2027.
[53] HE Y Q, ZHANG N N, WANG X D.Adsorption of graphene oxide/chitosan porous materials for metal ions.Chinese Chemical Letters, 2011, 22(7): 859.
[54] GUO T, BULIN C K, LI C N,et al. Experimental and statistical physics illumination of Pb(II) adsorption on magnetic chitosan-graphene oxide surface. Separation and Purification Technology, 2025, 354: 128867.
[55] KIREETI K V M K, CHANDRAKANTH G, KADAM M M,et al. A sodium modified reduced graphene oxide-Fe₃O₄ nanocomposite for efficient lead(II) adsorption. RSC Advances, 2016, 6(88): 84825.
[56] AHMAD S Z N, SALLEH W N W, YUSOF N,et al. Efficiency of magnetic zeolitic imidazolate framework-8 (ZIF-8) modified graphene oxide for lead adsorption. Environmental Science and Pollution Research, DOI: 10.1007/s11356-024-33322-w.
[57] LIU Z M, GAO Z M, XU L C,et al. Polypyrrole modified magnetic reduced graphene oxide composites: synthesis, characterization and application for selective lead adsorption. RSC Advances, 2020, 10(30): 17524.
[58] WANG Y, LIN K, LIU Y,et al. Nanocomposites of functionalized metal-organic frameworks and magnetic graphene oxide for selective adsorption and efficient determination of lead(II). Journal of Solid State Chemistry, 2022, 313: 123300.
[59] HOU L, QIN G J, QU Y Q,et al. Fabrication of recoverable magnetic composite material based on graphene oxide for fast removal of lead and cadmium ions from aqueous solution. Journal of Chemical Technology & Biotechnology, 2021, 96(5): 1345.
[60] KAUR M, KAUR M, SINGH D,et al. Magnesium ferrite-nitrogen-doped graphene oxide nanocomposite: effective adsorptive removal of lead(II) and arsenic(III). Environmental Science and Pollution Research, 2022, 29(32): 48260.
[61] JAVANMIRPOURSHIRZADI Z, HARGALANI F Z, ROBATI M,et al. Removal of lead (II) from aqueous solutions using β-cyclodextrin functionalized magnetic graphene oxide nanocomposite, performance, and optimization with response surface methodology. Journal of Nanoparticle Research, 2023, 25(7): 131.
[62] TANG T T, CAO S R, XI C X,et al. Chitosan functionalized magnetic graphene oxide nanocomposite for the sensitive and effective determination of alkaloids in hotpot. International Journal of Biological Macromolecules, 2020, 146: 343.
[63] CHAI D, CHEN Y, JIANG Z,et al. Insight on magnetic nitrogen-doped graphene oxide composite electrode constructing heterogeneous electro-Fenton system for treating organophosphorus pesticide wastewater. Separation and Purification Technology, 2024, 345: 127419.
[64] HE Y, YI C, ZHANG X L,et al. Magnetic graphene oxide: synthesis approaches, physicochemical characteristics, and biomedical applications. TrAC Trends in Analytical Chemistry, 2021, 136: 116191.
[65] LI S, JI J, SHAN S,et al. Efficient adsorption removal of tetrabromobisphenol A from water by using a magnetic composite Fe₃O₄/GO/ZIF-67. Crystals, 2024, 14(6): 508.
[66] BERTRAN A, SANDOVAL S, ORÓ-SOLÉ J,et al. Particle size determination from magnetization curves in reduced graphene oxide decorated with monodispersed superparamagnetic iron oxide nanoparticles. Journal of Colloid and Interface Science, 2020, 566: 107.
[67] YANG W J, ZHONG Y C, HE C X,et al. Electrostatic self-assembly of pFe₃O₄ nanoparticles on graphene oxide: a co-dispersed nanosystem reinforces PLLA scaffolds. Journal of Advanced Research, 2020, 24: 191.
[68] DE ANDRADE M B, GUERRA A C S, DOS SANTOS T R T,et al. Simplified synthesis of new GO-α-γ-Fe₂O₃-Sh adsorbent material composed of graphene oxide decorated with iron oxide nanoparticles applied for removing diuron from aqueous medium. Journal of Environmental Chemical Engineering, 2020, 8(4): 103903.
[69] WU Z G, DENG W J, ZHOU W,et al. Novel magnetic polysaccharide/graphene oxide @Fe₃O₄ gel beads for adsorbing heavy metal ions. Carbohydrate Polymers, 2019, 216: 119.
[70] AZAM M G, KABIR M H, SHAIKH M A A,et al. A rapid and efficient adsorptive removal of lead from water using graphene oxide prepared from waste dry cell battery. Journal of Water Process Engineering, 2022, 46: 102597.
[71] WANG N, SONG F X, NIU Y X,et al. Three-dimensional-printed calcium alginate/graphene oxide porous adsorbent with super-high lead ion adsorption ability in aqueous solution. Separation and Purification Technology, 2023, 326: 124757.
[72] ZHANG C Z, JIN R H, SHEN Q Q,et al. Synthesis of graphene oxide grafted by diazanyl groups and its application in recovery of lead from lead-acid wastewater. Environmental Science and Pollution Research International, 2023, 30(11): 29844.
[73] ALBOGHBEISH M, LARKI A, SAGHANEZHAD S J.Effective removal of Pb(II) ions using piperazine-modified magnetic graphene oxide nanocomposite; optimization by response surface methodology.Scientific Reports, 2022, 12(1): 9658.
[74] RAKHYM A B, SEILKHANOVA G A, KURMANBAYEVA T S.Adsorption of lead (II) ions from water solutions with natural zeolite and chamotte clay.Materials Today: Proceedings, 2020, 31: 482.
[75] WEI H, SONG B, HUAN Q,et al. Preparation of iron tailings-based porous ceramsite and its application to lead adsorption: characteristic and mechanism. Separation and Purification Technology, 2024, 342: 126839.
[76] TRAN C V, QUANG D V, THI H P N,et al. Effective removal of Pb(II) from aqueous media by a new design of Cu-Mg binary ferrite. ACS Omega, 2020, 5(13): 7298.
[77] HASHEM H M, EL-MAGHRABEY M, EL-SHAHENY R.Inclusive study of peanut shells derived activated carbon as an adsorbent for removal of lead and methylene blue from water.Scientific Reports, 2024, 14(1): 13515.
[78] CHEN Z H, YU C, DONG H F,et al. Sorption-desorption characteristics and internal mechanism of lead ions on polycarboxylic ion exchange resin. Journal of Polymer Research, 2022, 29(12): 512.
[79] KAUR M, KUMARI S, SHARMA P.Removal of Pb (II) from aqueous solution using nanoadsorbent ofOryza sativa husk: isotherm, kinetic and thermodynamic studies. Biotechnology Reports, 2020, 25: e00410.
[80] PUTZ A M, IVANKOV O I, KUKLIN A I,et al. Ordered mesoporous silica prepared in different solvent conditions: application for Cu(II) and Pb(II) adsorption. Gels, 2022, 8(7): 443.
[81] YAZEED E W S A, MANSOUR B N H, IBRAHIM A A,et al. Activated carbon encapsulated aluminum metal-organic frameworks as an active and recyclable adsorbent for removal of different dyes and lead from aqueous solution. Inorganic Chemistry Communications, 2025, 171: 113558.
[82] MOSLEH N, AHRANJANI P J, PARANDI E,et al. Titanium lanthanum three oxides decorated magnetic graphene oxide for adsorption of lead ions from aqueous media. Environmental Research, 2022, 214: 113831.
[83] LIU M, WANG Y, WU Y J,et al. Preparation of graphene oxide hydrogels and their adsorption applications toward various heavy metal ions in aqueous media. Applied Sciences, 2023, 13(21): 11948.
[84] VO L Q, VU A T, LE T D,et al. Fe₃O₄/graphene oxide/chitosan nanocomposite: a smart nanosorbent for lead(II) ion removal from contaminated water. ACS Omega, 2024, 9(15): 17506.
[85] BAKHTIARI S, SALARI M, SHAHRASHOUB M,et al. A comprehensive review on green and eco-friendly nano-adsorbents for the removal of heavy metal ions: synthesis, adsorption mechanisms, and applications. Current Pollution Reports, 2024, 10: 1.
[86] NICOLA R, COSTIŞOR O, CIOPEC M,et al. Silica-coated magnetic nanocomposites for Pb²+ removal from aqueous solution. Applied Sciences, 2020, 10(8): 2726.
[87] BHARDWAJ M, TEWARI S, KUMARI N,et al. Adsorption of Pb(II) and Cd(II) by functionalized graphene oxide (GO-MBT): mechanisms, antibacterial activity, and DFT studies. Inorganic Chemistry Communications, 2024, 164: 112464.
[88] WU W P, GE H C.Preparation of amino-silane and thiosemicarbazide modified graphene oxide composite for high uptake adsorption of Hg(II) and Pb(II).Journal of Dispersion Science and Technology, DOI: 10.1080/01932691.2024.2312839.
[89] ZHOU C Y, LI B H, LI Y F,et al. A review of graphene oxide-based adsorbents for removing lead ions in water. Journal of Environmental Chemical Engineering, 2024, 12(1): 111839.
[90] WU B L, WAN J, ZHANG Y Y,et al. Selective phosphate removal from water and wastewater using sorption: process fundamentals and removal mechanisms. Environmental Science & Technology, 2020, 54(1): 50.
[91] GONZÁLEZ-HERRERO H, RÍO E C, MALLET P,et al. Hydrogen physisorption channel on graphene: a highway for atomic H diffusion. 2D Materials, 2019, 6(2): 021004.
[92] SHARMA P, SINGH A K, SHAHI V K.Selective adsorption of Pb(II) from aqueous medium by cross-linked chitosan-functionalized graphene oxide adsorbent.ACS Sustainable Chemistry & Engineering, 2019, 7(1): 1427.
[93] WEI M P, CHAI H, CAO Y L,et al. Sulfonated graphene oxide as an adsorbent for removal of Pb²+ and methylene blue. Journal of Colloid and Interface Science, 2018, 524: 297.
[94] FAN Y Z, DONG J X, ZHANG Y,et al. A smartphone-coalesced nanoprobe for high selective ammonia sensing based on the pH-responsive biomass carbon nanodots and headspace single drop microextraction. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 219: 382.
[95] FAN Y Z, TANG Q, LIU S G,et al. A smartphone-integrated dual-mode nanosensor based on novel green-fluorescent carbon quantum dots for rapid and highly selective detection of 2, 4, 6-trinitrophenol and pH. Applied Surface Science, 2019, 492: 550.
[96] DONG X Y, GAO X, SONG J Q,et al. A novel dispersive magnetic solid phase microextraction using ionic liquid-coated amino silanized magnetic graphene oxide nanocomposite for high efficient separation/preconcentration of toxic ions from shellfish samples. Food Chemistry, 2021, 360: 130023.
[97] CAO Z F, WEN X, WANG J,et al. In situ nano-Fe₃O₄/triisopropanolamine functionalized graphene oxide composites to enhance Pb²+ ions removal. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 561: 209.
[98] HUSEIN D Z, HASSANIEN R, KHAMIS M.Cadmium oxide nanoparticles/graphene composite: synthesis, theoretical insights into reactivity and adsorption study.RSC Advances, 2021, 11(43): 27027.
[99] LALMI A, BOUHIDEL K E, SAHRAOUI B,et al. Removal of lead from polluted waters using ion exchange resin with Ca(NO₃)₂ for elution. Hydrometallurgy, 2018, 178: 287.
[100] FAN Y Z, HAN L, LIU S G,et al. A ratiometric optical strategy for bromide and iodide ion sensing based on target-induced competitive coordination of a metal-organic nanosystem. Journal of Materials Chemistry C, 2020, 8(33): 11517.
[101] FAN Y Z, HAN L, YANG Y Z,et al. Multifunctional binding strategy on nonconjugated polymer nanoparticles for ratiometric detection and effective removal of mercury ions. Environmental Science & Technology, 2020, 54(16): 10270.
[102] LEMMA L, KIFLIE Z, KASSAHUN S K.Adsorption of Pb²+ and Cd²+ on the l-cysteine-functionalized graphene oxide/chitosan/polyvinyl alcohol hydrogel: kinetic, isotherm, and thermodynamic study.Remediation Journal, 2023, 33(3): 233.
[103] 周博秋, 李慧强, 廖维, 等. GO-LDH复合材料对水中铅离子的吸附性能. 中国给水排水, 2019, 35(17): 105.

氧化石墨烯基吸附材料去除水体中Pb(II)：制备、性能及机理

Progress of Graphene Oxide-based Adsorbents for Pb(II) Removing in Water: Synthesis, Performance and Mechanism

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	梁锐辉, 钟鑫, 洪督, 黄利平, 牛亚然, 郑学斌. Yb₂O₃改性硅黏结层的环境障涂层体系耐高温水氧腐蚀行为研究[J]. 无机材料学报, 2025, 40(4): 425-432.
[2]	田睿智, 兰正义, 殷杰, 郝南京, 陈航榕, 马明. 基于微流控技术的纳米无机生物材料制备: 原理及其研究进展[J]. 无机材料学报, 2025, 40(4): 337-347.
[3]	张继国, 吴田, 赵旭, 杨钒, 夏天, 孙士恩. 钠离子电池正极材料循环稳定性提升策略及产业化进程[J]. 无机材料学报, 2025, 40(4): 348-362.
[4]	洪培萍, 梁龙, 吴炼, 马颖康, 庞浩. ZIF-67结构调控及其对盐酸金霉素的吸附性能研究[J]. 无机材料学报, 2025, 40(4): 388-396.
[5]	穆爽, 马沁, 张禹, 沈旭, 杨金山, 董绍明. Yb₂Si₂O₇改性SiC/SiC复合材料的氧化行为研究[J]. 无机材料学报, 2025, 40(3): 323-328.
[6]	殷杰, 耿佳毅, 王康龙, 陈忠明, 刘学建, 黄政仁. SiC陶瓷的3D打印成形与致密化新进展[J]. 无机材料学报, 2025, 40(3): 245-255.
[7]	谌广昌, 段小明, 朱金荣, 龚情, 蔡德龙, 李宇航, 杨东雷, 陈彪, 李新民, 邓旭东, 余瑾, 刘博雅, 何培刚, 贾德昌, 周玉. 直升机特定结构先进陶瓷材料研究进展与应用展望[J]. 无机材料学报, 2025, 40(3): 225-244.
[8]	王悦, 王欣, 于显利. 室温铁磁性还原氧化石墨烯基全碳膜[J]. 无机材料学报, 2025, 40(3): 305-313.
[9]	范晓波, 祖梅, 杨向飞, 宋策, 陈晨, 王子, 罗文华, 程海峰. 质子调控型电化学离子突触研究进展[J]. 无机材料学报, 2025, 40(3): 256-270.
[10]	海热古·吐逊, 郭乐, 丁嘉仪, 周嘉琪, 张学良, 努尔尼沙·阿力甫. 上转换荧光探针辅助的光学成像技术在肿瘤显影中的应用研究进展[J]. 无机材料学报, 2025, 40(2): 145-158.
[11]	孙树娟, 郑南南, 潘昊坤, 马猛, 陈俊, 黄秀兵. 单原子催化剂制备方法的研究进展[J]. 无机材料学报, 2025, 40(2): 113-127.
[12]	陶桂龙, 支国伟, 罗添友, 欧阳佩东, 衣新燕, 李国强. 空腔型薄膜体声波滤波器的关键技术进展[J]. 无机材料学报, 2025, 40(2): 128-144.
[13]	冯关正, 杨健, 周渡, 陈啟明, 许文涛, 周有福. 水热-碳热合成AlN纳米粉体的机理[J]. 无机材料学报, 2025, 40(1): 104-110.
[14]	周帆, 田志林, 李斌. 热防护系统用碳化物超高温陶瓷抗烧蚀涂层研究进展[J]. 无机材料学报, 2025, 40(1): 1-16.
[15]	王文婷, 徐敬军, 马科, 李美栓, 李兴超, 李同起. 原位反应/热压合成Ti₂AlC-20TiB₂复合材料在1000~1300 ℃空气中的高温氧化行为[J]. 无机材料学报, 2025, 40(1): 31-38.